TOXICOLOGICAL PROFILE FOR HYDROGEN SULFIDE

3,51
MB

253
stron

3467
ID Agency for Toxic Substances and Disease Registry

2006
rok

CONTENTS

DISCLAIMER ii

UPDATE STATEMENT ..iii

FOREWORD ..v

QUICK REFERENCE FOR HEALTH CARE PROVIDERS..vii

CONTRIBUTORS..ix

PEER REVIEW xi

CONTENTS.xiii

LIST OF FIGURES xvii

LIST OF TABLESxix

1. PUBLIC HEALTH STATEMENT.1

1.1 WHAT IS HYDROGEN SULFIDE?1

1.2 WHAT HAPPENS TO HYDROGEN SULFIDE WHEN IT ENTERS THE ENVIRONMENT? .2

1.3 HOW MIGHT I BE EXPOSED TO HYDROGEN SULFIDE? .2

1.4 HOW CAN HYDROGEN SULFIDE ENTER AND LEAVE MY BODY? 3

1.5 HOW CAN HYDROGEN SULFIDE AFFECT MY HEALTH? ..4

1.6 HOW CAN HYDROGEN SULFIDE AFFECT CHILDREN?5

1.7 HOW CAN FAMILIES REDUCE THE RISK OF EXPOSURE TO HYDROGEN SULFIDE?.6

1.8 IS THERE A MEDICAL TEST TO DETERMINE WHETHER I HAVE BEEN EXPOSED TO

HYDROGEN SULFIDE? .6

1.9 WHAT RECOMMENDATIONS HAS THE FEDERAL GOVERNMENT MADE TO PROTECT

HUMAN HEALTH?.7

1.10 WHERE CAN I GET MORE INFORMATION? ..8

2. RELEVANCE TO PUBLIC HEALTH 9

2.1 BACKGROUND AND ENVIRONMENTAL EXPOSURES TO HYDROGEN SULFIDE IN THE

UNITED STATES 9

2.2 SUMMARY OF HEALTH EFFECTS..10

2.3 MINIMAL RISK LEVELS (MRLs) ..14

3. HEALTH EFFECTS..21

3.1 INTRODUCTION..21

3.2 DISCUSSION OF HEALTH EFFECTS BY ROUTE OF EXPOSURE .21

3.2.1 Inhalation Exposure ..22

3.2.1.1 Death .22

3.2.1.2 Systemic Effects ..26

3.2.1.3 Immunological and Lymphoreticular Effects61

3.2.1.4 Neurological Effects..62

3.2.1.5 Reproductive Effects .68

3.2.1.6 Developmental Effects .70

3.2.1.7 Cancer..71

3.2.2 Oral Exposure..72

3.2.2.1 Death .72

3.2.2.2 Systemic Effects ..72

3.2.2.3 Immunological and Lymphoreticular Effects73

3.2.2.4 Neurological Effects..73

3.2.2.5 Reproductive Effects .73

3.2.2.6 Developmental Effects .73

3.2.2.7 Cancer..73

3.2.3 Dermal Exposure.73

3.2.3.1 Death .73

3.2.3.2 Systemic Effects ..74

3.2.3.3 Immunological and Lymphoreticular Effects74

3.2.3.4 Neurological Effects..74

3.2.3.5 Reproductive Effects .75

3.2.3.6 Developmental Effects .75

3.2.3.7 Cancer..75

3.3 GENOTOXICITY 75

3.4 TOXICOKINETICS..75

3.4.1 Absorption.76

3.4.1.1 Inhalation Exposure76

3.4.1.2 Oral Exposure76

3.4.1.3 Dermal Exposure .77

3.4.2 Distribution 77

3.4.2.1 Inhalation Exposure77

3.4.2.2 Oral Exposure79

3.4.2.3 Dermal Exposure .79

3.4.2.4 Other Routes of Exposure ..79

3.4.3 Metabolism79

3.4.4 Elimination and Excretion..82

3.4.4.1 Inhalation Exposure82

3.4.4.2 Oral Exposure82

3.4.4.3 Dermal Exposure .83

3.4.5 Physiologically Based Pharmacokinetic (PBPK)/Pharmacodynamic (PD) Models .83

3.5 MECHANISMS OF ACTION ..84

3.5.1 Pharmacokinetic Mechanisms..84

3.5.2 Mechanisms of Toxicity..86

3.5.3 Animal-to-Human Extrapolations ..88

3.6 TOXICITIES MEDIATED THROUGH THE NEUROENDOCRINE AXIS..88

3.7 CHILDREN’S SUSCEPTIBILITY.89

3.8 BIOMARKERS OF EXPOSURE AND EFFECT ..91

3.8.1 Biomarkers Used to Identify or Quantify Exposure to Hydrogen Sulfide .92

3.8.2 Biomarkers Used to Characterize Effects Caused by Hydrogen Sulfide 93

3.9 INTERACTIONS WITH OTHER CHEMICALS ..93

3.10 POPULATIONS THAT ARE UNUSUALLY SUSCEPTIBLE..95

3.11 METHODS FOR REDUCING TOXIC EFFECTS.95

3.11.1 Reducing Peak Absorption Following Exposure ..96

3.11.2 Reducing Body Burden..97

3.11.3 Interfering with the Mechanism of Action for Toxic Effects .97

3.12 ADEQUACY OF THE DATABASE.98

3.12.1 Existing Information on Health Effects of Hydrogen Sulfide 98

3.12.2 Identification of Data Needs .100

3.12.3 Ongoing Studies..107

4. CHEMICAL AND PHYSICAL INFORMATION109

4.1 CHEMICAL IDENTITY109

4.2 PHYSICAL AND CHEMICAL PROPERTIES.109

5. PRODUCTION, IMPORT/EXPORT, USE, AND DISPOSAL.113

5.1 PRODUCTION ..113

5.2 IMPORT/EXPORT ..113

5.3 USE..114

5.4 DISPOSAL..114

6. POTENTIAL FOR HUMAN EXPOSURE ..115

6.1 OVERVIEW115

6.2 RELEASES TO THE ENVIRONMENT..118

6.2.1 Air ..118

6.2.2 Water.119

6.2.3 Soil .120

6.3 ENVIRONMENTAL FATE.121

6.3.1 Transport and Partitioning121

6.3.2 Transformation and Degradation .122

6.3.2.1 Air122

6.3.2.2 Water ..122

6.3.2.3 Sediment and Soil.123

6.4 LEVELS MONITORED OR ESTIMATED IN THE ENVIRONMENT.123

6.4.1 Air ..124

6.4.2 Water.127

6.4.3 Sediment and Soil 127

6.4.4 Other Environmental Media128

6.5 GENERAL POPULATION AND OCCUPATIONAL EXPOSURE .129

6.6 EXPOSURES OF CHILDREN..131

6.7 POPULATIONS WITH POTENTIALLY HIGH EXPOSURES .132

6.8 ADEQUACY OF THE DATABASE..132

6.8.1 Identification of Data Needs ..133

6.8.2 Ongoing Studies 135

7. ANALYTICAL METHODS 137

7.1 BIOLOGICAL MATERIALS.137

7.2 ENVIRONMENTAL SAMPLES..143

7.3 ADEQUACY OF THE DATABASE..151

7.3.1 Identification of Data Needs ..151

7.3.2 Ongoing Studies 152

8. REGULATIONS AND ADVISORIES ..153

9. REFERENCES ..159

10. GLOSSARY .201

APPENDICES

A. ATSDR MINIMAL RISK LEVELS AND WORKSHEETS .A-1

B. USER’S GUIDE... B-1

C. ACRONYMS, ABBREVIATIONS, AND SYMBOLS. C-1

D. INDEX .