Benchmarking Metal Finishing

9,59
MB

154
stron

4277
ID National Center for Manufacturing Sciences

2002
rok

Table of Contents

Section

What You Will Find in This Report . iii

List of Tables . ix

Background and Acknowledgments . xiii

What Is the Benchmarking Survey? . xiii

What We Did xiii

Why We Did It xiii

Who We Are . xiii

Acronyms and Abbreviations . xv

Chapter 1 . The Benchmarking Survey . 1-1

1.1 What We Asked in Phases 1 and 2 1-2

1.2 Who Responded: a Profile of Survey Participants 1-2

1.2.1 Processes . 1-2

1.2.2 Multi-Process Operations .1-3

1.2.3 Rack and Barrel Plating 1-3

1.2.4 Comparison Between Survey Respondents and General Population . 1-4

1.2.5 Other Descriptive Statistics 1-5

1.3 What We Learned 1-7

1.3.1 Overview of Our Approach 1-7

1.3.2 Regression Results: Environmental Performance Versus Process Type 1-10

1.3.3 Regression Results: Environmental Performance Versus Other Company Characteristics 1-

12

1.3.4 Adjustment Formulas . 1-14

Appendix 1A: Phase 1 and Phase 2 Survey Forms 1A-1

Appendix 1B : Compilation of Survey Data . 1B- 1

Appendix 1C: Additional Details on Survey Methods and Analytical Approach 1C-1

Chapter 2 . Using the Survey Results 2-1

2.1 Analysis of Phase 1 Data-Ranking Environmental Performance 2-1

2.1.1 Wastewater Discharge Rate 2-2

2.1.2 Sludge Generation Rate and RecycleDisposal Method . 2-2

2.1.3 Electricity Use . 2-3

2.1.4 Organic Emissions 2-3

2.1.5 Finding the Rank . 2-4

2.2 Analysis of Phase 2 Data . 2-8

2.2.1 Production and Environment-Related Practices . 2-8

2.2.2 Pollution Control Costs 2-13

Appendix 2A: Descriptive Data for Ranked Companies . 2A-1

Use arid dissemination of the information contained in this document are subject to restrictions on

the Wright page 1 I

Chapter 3 . Guide to Best Practices . 3.1

3.1 Alkaline Cleaning 3-2

3.1.1 Alternatives to Solvent Cleaning 3-2

3.1.2 Process Characteristics . 3-3

3.1.3 Water Use Reduction 3-3

3.1.4 Bath Maintenance . 3-4

3.2.1 Water Use Reduction 3-5

3.2 Acid Dipping and Pickling 3-5

3.2.2 Bath Maintenance . 3-6

3.2.3 Process Conditions . 3-6

3.2.6 Uses for Spent Baths . 3.7

3.3.1 Water Use Reduction 3-7

3.3.2 Anode Use 3-8

3.3.3 Bath Maintenance . 3-8

3.3.5 Special Practices for Chromic Acid 3.9

3.4.2 Bath Maintenance . 3-11

3.2.4 Inhibitors . 3-7

3.2.5 Chemical Substitution . 3-7

3.3 Anodizing . 3-7 .

3.3.4 Energy Use Reduction 3-9

3.4 Cadmium Plating . 3-9

3.4.1 Water Use Reduction 3-10

3.4.3 Chemical Recovery . 3-11

3.5.1 Water Use Reduction 3-11

3.5 Copper Plating . 3-11

3.5.2 Bath Maintenance . 3-12

3.5.3 Chemical Recovery . 3-12

3.6 Decorative Chromium Plating 3-12

3.6.3 Air Quality 3-14

3.7 Electroless Nickel Plating . 3-15

3.7.1 Bath Maintenance . 3-15

3.7.2 Disposal of Spent Baths 3.16

3.8 Hard Chromium Plating 3-16

3.8.1 Drag-out Recovery 3.16

3.8.3 Air Quality 3-18

3.9 Nickel Plating 3-18

3.6.1 Water Use Reduction 3-13

3.6.2 Bath Maintenance . 3-14

3.7.3 Water Use Reduction 3-16

3.7.4 Air Quality 3-16

3.8.2 Bath Maintenance . 3-17

3.9.1 Water Use Reduction 3-18

3.9.2 Chemical Recovery . 3-19

3.9.3 Additives . 3-20

3.9.4 Bath Maintenance . 3-20

3.9.5 Additional Methods 3 -21

3.9.6 Air Quality 3-21

3.10 Tin and Tin-Lead Plating . 3-21

3.10.1 Alternative Processes . 3-21

3.10.2 Water Use Reduction . 3-22

3.10.3 Bath Maintenance . 3-22

3.10.4 Chemical Recovery 3-22

3.10.5 Disposal of Spent Baths and Sludge 3-22

3.1 1 Zinc Plating . 3-22

3.1 1.1 Bath Maintenance . 3-23

3.1 1.2 Water Use Reduction . 3-24

3.1 1.3 .Chemical Recovery 3-24

3.12 Other Processes . 3-24

3.12.1 Phosphating 3-25

3.12.2 Passivation 3-25

3.12.3 Black Oxide 3-26

3.12.5 Painting . 3-26

3.12.4 Electropolish . 3-26

3.12.6 Polishing and Buffing . 3-26

3.13 Additional Comments . 3-26

3.13.1 General . 3-27

3.13.2 Energy 3-28

3.13.3 TreatmentDisposaVOff-site Recycling 3-28

Appendix 3A: Glossary 3A-1

Chapter 4 . Roadmap 4. 1

4.1 Method Outline 4-1

4.1.1 Starting Point 4.2

4.1.2 Destination 4-3

4.1.3 Factors Affecting “How Far” 4-4

4.1.4 Factors Affecting “How Steep” 4-5

4.2 Specific Process Benchmarks 4-7

4.2.1 Zinc Plating . 4-7

4.2.2 Nickel Plating . 4. 10

4.2.3 Decorative Chromium Plating 4-11

4.2.4 Electroless Nickel Plating . 4. 12

4.2.5 . Anodizing . 4. 13

4.2.6 Hard Chromium Plating 4-15