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global renewable energy
wind energy
solar power
hydroelectricity
geothermal energy
bioenergetics
waste disposal
conclusions

biomass and energy

Analysis of Energy

economies of bioenergetics
terminology
direct impact
indirect impact

thermodynamic data for bioenergetics
formula
symbols
units
heat of combustion

EXPLANATIONS

references

Bioenergetics

The confusion surrounding the "greenhouse effect" is slowly being transformed into a debate about the potential human populations’ interference with the processes that determine the conditions of life on Earth. Global effort to reduce CO2 emissions will be the first attempt to verify this hypothesis. In the background of this hypothesis there is also a question about the possible creation of a global economic policy in line with the real circumstances existing on Earth. Greenhouse gas emission is the only significant consequence of technological processes required for energy creation. Ability to create energy is the foundation of our civilization, so you can not simultaneously reduce its output/production and at the same time expect to maintain living standards. It is important that the direction of energy development is consistent with the intent to maintain its current capacity for a period greater than the time horizon of current policies.

Sustainable development is a recipe for economic policy formulation such that the resources available to our generation will be preserved for all generations after us. It is some kind of utopia, because you can not eat cakes from the box and have them there all the time. Nevertheless, one should not be discouraged and discard any attempts to stick to the principles of sustainable development in strategic planning. This is because sustainability expresses the fundamental law of ecology for all species. Mankind is not exempted from the rule. It can not grow the population by reducing exploration of resources on which its existence depends. Particularly energy resources are subjected to pressure from humans. Energy resources are necessary precondition for the existence of civilization. We need to look how to secure the energy needs that will be available for hundreds of generations after us.

The debate related to "greenhouse effect" revolves around dispute between the realists and ecologists. Realists opt for perfecting the techniques currently used for fossil fuel, and environmentalists promote renewable energy. Realists are supported by large capital, whose total volume exceeds 20% of the global financial market. Ecologists can rely on societal support, which often expresses itself in the policy of the state authorities rather than in the form of real investment funds. The result of this debate creates attempts and action that are quite often deprived of rational arguments. For example: environmentalists are watching with amazement when their colleagues support nuclear energy technology. This technology possess the highest level of risk by exploring radioactive fossil fuels without the proper waste management. On the opposite side, those holding shares of oil corporations listen with horror to the experts - experts who promote expensive recovery and dumping of CO2 at the bottom of the oceans.

Realistically, the only inexhaustible source of energy is the radiation from the Sun. This unequivocally points at the solar technologies as a target among the whole energy options. It has to be mentioned, that all carbon fossil fuels owe their energy capacity thanks to solar energy accumulated in them over millions of years. Combustion of fossil fuels reverses the process of CO2 assimilation by plants and other organisms from the atmosphere. Process of photosynthesis is the only one operating on a global scale - it permanently absorbs a small part of the solar radiation and traps this energy within the biomass. In the past, this trapped energy reserves in the form of fossil hydrocarbons and coal could have been released only in volcanic processes. However production and increasing demand for energy are responsible for release of both: the accumulated solar energy in the biomass, and the carbon dioxide gas. The latter is, of course, able to create the excess of solar heat in the atmosphere.

As we mentioned, modern civilizations extract , then burn fossil fuels (coal, oil, natural gas) and release stored in it solar energy. This solar energy was accumulated in Earth's crust, millions of years ago. On top of it we combust biofuels accumulated recently. What makes the difference between the combustion of recent biofuels and fossil fuels, is the period of time needed to replenish the fuel. Recently accumulated biomass arise in the process of binding solar energy as well. This energy when released during combustion, does not affect the carbon balance of the biosphere. It is estimated that 4.2x1017J/year of solar energy is “trapped” (due to photosynthesis) in the form of biomass containing 1010 tons of carbon. We could extract back the same energy by burning this whole amount of mentioned “recent” biomass. As a result, theoretically, atmospheric heat energy balance would increase. Or, explaining it more accurate: such approach balances amount of CO2 in the atmosphere, but at the same time eliminates cooling of the biosphere. Cooling takes place because of plants’ photosynthesis. Without cooling of the biosphere, total amount of energy within the Earth's environment will increase. Considering this, one cannot assume that such energy policy, based on burning recent biomass, fills the condition of sustainable development.

We can conclude: criterion of energy balance within the Earth’s biosphere must be preserved. Therefore development of bioenergy should not eliminate existing capacity for photosynthesis. This can be achieved quickly by assigning segments of bioenergy to land areas that are marginal with regard to agricultural industry today. At the same time, natural areas of considerable potential for the assimilation of CO2 and absorption of solar energy will be excluded from the process of generating bioenergy. Energy plantations must be developed in the areas of deserts, degraded areas, and even in cities and industrialized areas. Maintaining the energy balance within the biosphere can be helped by creation of analytical tools for quantitative presentation of life cycle for each form of energy and agronomic systems. It is important to eliminate and reduce energy technologies that affect negatively photosynthesis. This should be achieved by strategic planning that will keep in check any adverse economic impact on climate change.

“Criterion for Energy Balance within Biosphere” evaluates life cycle of energy forms such electricity, heat, fuel for transport and agriculture. This approach provides an objective presentation of results and helps to establish numerical priorities for the development of individual technologies. Analytical methodology will be based on the eco-toxicological studies and thermodynamic data. This in turn will establish objectives for protecting ability to maintain potential of photosynthesis. Today the euphemistic impact of energy on biodiversity will be quantified and included in the cost of producing energy forms. Such economic formula of dematerialization when utilized for scrutinizing damages to the environment, will help to make rational investment decisions. At the same time this formula will determine importance of each energy technology and categorize each technology that appears on the list of economic expansions. Therefore, planning for sustainable development of eco-growth will be equipped with the helpful tools for investment analysts. These tools will allow to exchange understandable and clear information about priorities.

Investors’ decisions will ultimately determine need to mitigate the climate change. Decisions will be based on assessing the impact of uncertainties such as: 1) climate change on the economy; 2) the stability/effectiveness of the policy regulating appropriate changes. All factors arising from inaccuracies are taken into consideration for investment risk. These factors are: 1) operation cost’s valuation related to selected technology; 2) vulnerability of selected technology for variability of financing. In short: investment analysts will dictate direction for technology development. Consideration will be given to technology that:

- enjoys political support, which ensures stability of the regulatory processes;
- is economically competitive in the market for existing alternatives, which provide a stable funding;
- is the best among existing alternatives when it comes to criterion for sustainable development. This would insure steady political support.

Bioenergy has the potential to meet all of the conditions set by the analysis of investment risk. It is estimated that current fossil fuels provide 3.9x1017J of primary energy consumed in the global economy. This is the amount comparable to the entire global product of photosynthesis, so in theory it can be expected that bioenergy will be able to fully replace fossil fuels. However, the existing energy generating technologies that use biofuels, have the potential of not more than 0.4x1017J. This calls for radical technological progress, that will: 1) increase access to bioenergy, while preserving natural resources capable of photosynthesis; 2) not diminish the potential of agriculture and preserve capacity for food production.

Competitive to the bioenergetics technology is the direct conversion of solar energy into electricity and heat. Photovoltaics do not require any additional technical operations and provide at least 4-fold higher efficiency than photosynthesis. Conversion of biomass to fuel and energy takes place in complex installations including network of electricity carriers while the user of solar cells obtains energy directly after connecting to the grid. Similarly, it is easy and cheap to operate thermoelectric power plants and solar heating installations. However, methods for making this kind of plant are closely linked to the most devastating types of elecromechanical industries. Environmental degradation in the industrialized countries is a reason to eliminate a substantial part of the solar energy potential. Why? - because if progress towards cleaner production schemes in the industry fails to reduce emissions of toxins produced in the manufacture of photovoltaic and solar thermal plants, direct solar energy will not represent the ultimate model of sustainable energy.

The nuclear technology, as well as many advanced techniques generating renewable energy are fraught with serious reservations regarding their impact on the environment. None of them, except bioenergy, is able to meet sufficient capacity for growing energy needs. Construction of wind and water turbines requires non-renewable materials. Consequently development of these technologies will be thwarted by material shortages. Before we proceed to review the future potentials of bioenergy, we must bear in mind, that nowadays all traditional forms of biomass energy usage are in place. Burning wood is the first energy technique, which man mastered at least 100 thousand years ago. Manufacture of alcohol from cereals represents almost the same example; invention of fermentation being loosely attributed to the biblical Noah. Survey of energy sources in the third world countries, as well as in the world's leading economies, will show that these oldest techniques are still a huge part of bioenergetics and occupy a significant share of global energy generation. The graph below represents global energy consumption from various sources (where Mtoe/a = millions of tons of oil equivalent per annum).

We conclude that the current bioenergy is still in the very initial stage of development and has reached its limits. Most of this form of energy is acquired from the combustion of biomass by using variety of simple and uneffective installations. This causes destruction of natural forest in poor southern countries. In the industrialized countries growing biomass for combustion competes with agricultural land use. At the beginning of the third millennium bioenergetics remains at a primitive technological level: biomass designated for combustion is classified as biofuel of base-generation.

0. Base-generation bio-fuels are generated by mechanical processes.
This class consist of :
0.1. waste from forestry, wood industry and agriculture; for example it can be small tree branches, low quality wood, bark, straw that are useless for manufacturing industry .
0.2. peat (decayed vegetation matter formed in wetland bogs and swamp forests).
0.3. chips, pellets and briquettes made from the dried cellulosic biomass.
0.4. untreated municipal and industrial waste.

It is important to realize, that fossil fuel utilization cannot be completely replaced by base-generation of bio-fuels. Yet new generations of bio-fuels, and only when implemented on a full scale, may have such capacity and be able to replace base-generated biofuels.

1. First-generation bio-fuels are utilized on a large scale. Examples include:
1.1.  bio-ethanol produced by hydrolysis and fermentation from sugar cane and cereals.
1.2. vegetable oil (pure plant oil or in short: PPO) obtained by cold-pressing or extraction from oilseed plants such as rape.
1.3. bio-diesel, that is methyl ester of rapeseed oil (in short: RME) synthesized from PPO by chemical reaction of transestrification.
1.4. methyl or ethyl esters of fatty oils (in short: FAME or FAEE) derived by transestrification from degraded waste oils.
1.5. biogas produced from wet biomass by fermentation process.

2. Examples of the second generation bio-fuels, that are under development, are as follows:
2.1. bio-ethanol (wood alcohol) obtained by advanced hydrolysis and fermentation of cellulosic materials.
2.2. synthetic biofuels, such as Fischer-Tropsch (FT) diesel, bio-methanol, mixed higher alcohols and bio-dimethyl ether (Bio-DME) derived by chemical processes of gasification and synthesis (FT method).
2.3. biodiesel produced from hydrogenated vegetable oils and animal fats using selective hydrogenation
2.4. synthetic bio-natural gas (SNG) produced from cellulosic biomass by gasification and synthesis.
2.5. biohydrogen obtained from cellulosic biomass by biological method or by gasification/ synthesis.

3. The third generation of biofuels is in the research and implementation phase. Examples include:
3.1. biodiesel produced from algae by selective hydrogenation.
3.2. synthetic biofuels derived from gasification of algae biomass.

A separate category of biofuels is energy carriers generated as by-products of industrial processes or household waste. Discussions are still ongoing whether this substances can be categorized as biofuels. Fact is, that this group of fuels is undoubtedly of a biological source. So far, the overwhelming bulk of this type of waste is stored without any long term planning for recycling. Thus we encounter the enormous environmental pollution associated with landfills emissions. This calls for intensive work to eliminate landfill waste disposal. Technological advances in the field of incineration has already allowed the use of waste for energy production on an industrial scale.

4. Biofuels produced from waste include:
4.1. alternative fuel (RDF refuse derived fuel) produced from municipal and industrial waste by mechanical alteration in order to adapt the mass to the needs of power plants.
4.2. biogas generated by landfills and biogas obtained by fermentation of wastewater and sewage sludge.
4.3. the synthetic biogas produced by pyrolysis of waste and sewage sludge.

Hundreds of innovative bioenergy technologies have been launched so far. Each technology or its sequence possesses three steps/stages. Initially living organisms are used to absorb solar energy and CO2. In the second stage biomass is converted to fuel. The third stage is a fuel burning, so the energy is released as well as the CO2 (the latter absorbed in the first stage). Thus bioenergetics allows for storing and managing solar energy, and use of solar energy in proper place and in desired time. Additional secondary expenses occur of course. They are expressed both in the price of equipment needed for the particular technology operation, as well as in price for energy and raw materials consumed by this operation. In addition, biofuels are a normal industrial product, so like any other energy industry, bioenergy industry is under scrutiny that measures its impact on environment. Indeed such impact exists - it is a necessity to acquire vast areas of farmland for biomass production.

The expansion of bioenergy must be preceded by an analysis of the life cycle of all energy products derived from biomass; otherwise we will enter the rapid development of bioethanol production from energy crops. This means large scale deforestation and reduced access to food and feed crops. Large scale energy plantations will lead to loss of biodiversity, displacement of indigenous populations, growing poverty and crime. Such scenario and related to it cost, calls for a critical review of such approach, its location and scale of operations. To put it simply - bioenergetics cannot be the next plague falling on the third world countries. Before jumping on an industrial scale, there has to be analysis of social and environmental consequences in order to maintain sustainable development. This is the most important aspect of bioenergy technologies reviewed in this study.

   
   

 

 global renewable energy

In 2001, global energy consumption was 418 EJ, of which over 10%, or 45 EJ, coincided with biomass. It is expected that by 2030 energy consumption would be 50% higher. Since the use of biomass for heating in households stands now at about 39 EJ, maintaining more than 10% share of biomass in total energy consumption will require significant progress in the industrial production of biofuels. This conclusion comes from the observation, that the energy needs of households remain almost constant thanks to growing changes in developing countries. The diagram below shows the share of renewable energy in global energy consumption. [3]

 

During the last ten years spending on renewable energy development increased at a unprecedented rate in the history of the industry. New investments in this sector in 2008 reached the sum of over US$120bln. The leading position is held by United States, where investment amounted to US$24bln. China, Spain and Germany made a significant contribution to the development of renewable energies at the level of US$15-19bln. Brazil has invested more than US$5bln into biofuels. Renewable energy has proved to be the most crisis resistant industrial sector. Even after September 2008 crisis, spending on aid to developing countries reached a record high of US$2bln. [9]

The following diagram presents the main indicators of the development of renewable energy:

Almost all industrialized countries and many developing countries subsidize investment in renewable energy. Also, the purchase of renewable energy grid carriers and network facilities are subsidized. Mandatory subsidizing for all consumers of electricity exists in the forms of: 1) preferential tariffs, 2) limits for bioenergy participation in total generated electricity, 3) quotas related to the distribution of biofuels in transportation fuels. Both: direct funding, as well as the legal obligations imposed on participants in the energy market are to compensate the economic differences between bioenergetics and the total energy in the country.

Main fields of investment are wind energy (42%), photovoltaic cells (32%) and biofuels (13%). These are the most capital-intensive forms of renewable energy, which without government subsides would have little chance of confrontation with the classical energy. Investments in energy derived from biomass, geothermal energy, solar generators and small hydropower plants have a share of about 6% of the total investment effort. These sectors of renewable energy are particularly beneficial to local communities at relatively low cost. Widely criticized in 2008 big hydro projects also received considerable funding at US$45bln.

In addition to great efforts to improve the capacity of renewable energy, we observe a very intensive development of production infrastructure and research facilities. It is estimated that in 2008 investments in new technology exceeded US$15bln. Companies and funds investment in research and development increased up to US$13.5bln. Also, banks keep lending at a high level for renewable energy projects. The largest creditor is the European Investment Bank, whose involvement increased in 2008 to US$2.6bln. Technology transfer and direct investment to developing countries exceeded the sum of US$bln in 2008. The World Bank earmarked US$1.2bln for the development of clean energy in Third World countries.

Despite the financial crisis in 2008/2009, further development continues.. The crisis affected some of the investments in renewable energy, however this sector receives major financial support from governments. Renewable energy and clean technologies have become an important element in stimulating activity of many industries threatened with collapse. By such economical stimulation authorities hope for creation of much needed "green jobs." USA launched a 10 years support program valued at US$150bln, Japan established a five years long development plan worth US$12.2bln, South Korea will invest US$36bln within next 4 years. In addition, many countries have established special tax incentives for investors financing renewable energy development programs. In the USA these credits were US$1.6bln in 2008, and in China US$15bln. In Mexico, a new energy law will be funded at the level of US$0.8bln, and Morocco claims its program valued at US$1bln.

The renewable energy industry experienced an unprecedented boom in 2008. In September, the stock market listed more than 160 companies producing this type of energy with the total capital in excess of US$100bln. Global capital commitment for the industry was estimated at US$240bln, and the level of employment at more than 2.4 million people. The crisis at the end of  2008 caused significant difficulties for many of newly launched enterprises, but giants, for example like BP and Shell, have closed some plants and laid of workers as well. Changes in the location of newly constructed facilities became to be noticeable. China became a significant and growing producer of solar and wind generated energy. Production of this type of energy has been launched in India and Southeast Asia.
 

Wind Energy

Wind energy utilization represents the largest progress. The graphs below relate to its state at the end of 2008.

growing output of energy obtained in wind power plants

The largest increase is observed in the USA, about 8.4 GW. In China, installed capacity had doubled by the year 2008. There are also African and Asian countries investing in wind energy. The increase is also observed in plants built on the seas. At the end of 2008 the installed capacity reached 1.5 GW, mainly in Europe, where Britain is the leader. Denmark obtains more than 30% of the energy from wind power installations.

10 countries with the highest share of wind energy

The success of wind energy stems from both: its economic attractiveness, as well as the decline in the industries that can be easily switched to the production of windmills. 10 firms covering more than 85% of demand for wind turbines are listed from the largest: Vestas (Denmark), GE Wind (USA), Gamesa (Spain), Enercon (Germany), Suzlon (India), Siemens (Denmark), Sinovel ( China), Acciona (Spain), Goldwind (China), Nordex (Germany). The most commonly used are turbines of 2 MW. Recently even bigger - 3 MW turbines are being used. In 2010 the generating industrial capacity for wind turbines reached 20 GW.

 

Solar Power

Evidence suggests that energy from the solar installations grows at the fastest pace.

installed electric capacity of photovoltaic cells

WIn 2008, global installed capacity of solar cells grew by 70% compared to the previously measured total solar power; about 13 GW was connected to electricity networks. The leader is Spain, where 0.55 GW in 2007 grew to 3.2 GW in 2008. Non-grid connected local installations grow even faster. The total power generated by photovoltaic cells reached a level of 16 GW in 2008. There is a new trend in the construction of photovoltaic installations:

- Cells integrated into the buildings,
- Thin-film cells with greater efficiency,
- Solar photovoltaic power plants exceeding 200 kW.

The world's largest solar power plant of 60 MW is located in Spain. Even greater plants of this type are built in the U.S. , China, India and Japan. The largest producers of solar cells are China ( 1.8 GW of potential capacity/ year), Germany (1.3 GW) and Japan (1.2 GW). The fastest growing is thin-film cell production, with USA in forefront - manufacturing thin-calls able to deliver about 270 MW in 2008.

In addition to the production/research of photovoltaic cells, solar power plants are being built and upgraded extensively. This type of plants convert directly solar energy into heat, and then generate electricity in a conventional steam turbines. Concentrating Solar Power (CSP) is a system promising a great future if it will be integrated with complementary natural gas-powered installations. In 2008 we observed construction of such systems having 50MW or more. Total installed capacity exceeded 8GW. Even bigger installations are under construction, having a total summarized power of 6GW. CSP technology is one of the most technologically advanced. It uses a very diverse systems. A significant number of new global producers surfaced in 2008. The largest are: Ausra, Bright Source Energy, eSolar, FPL Energy, Infinia, Sopergy and Stirling Energy Systems in the USA: Abengoa Solar, Acciona, Iberdrola Renovables, and Sener in Spain, and Solar Millennium in Germany.

total global producers of solar energy and their share

Solar heating systems have found wide application in all countries that support and are involved in developing renewable energy. At the end of  2008 the total output of these systems exceeded 145GWt, where “t" refers to thermal power output. This means doubling the capacity when compared to 2004. Nearly 70% of global installed capacity comes from China, where the pace of development of these solar installations is fastest. In general, the extraction of heat from solar radiation is the most efficient and utilizes the simplest technologies. Spectrum of applications for solar energy has a greatest range (one example is the market for small devices for local use). Back to heating: in Germany  200 000 solar heating systems were installed having total power of  1.5GWt. At the same time, China reached 14GWt. This technology has contributed to expansion of “green” constructions and buildings in Europe, while in developing countries is likely to play the role of a primary source of heat.

Solar energy plays an important part of the rural electrification programs in developing countries. Charitable grants, government and international support help to erect cheap and easy to use photo-and thermoelectric systems providing electricity to the most remote settlements. This applies particularly to places where classic electrification is uneconomic or impossible to achieve. In India, so called Remote Village Electrification Program supplied the photoelectric power to 5400 villages and settlements, provided 435000 houses with light , installed 700 000 street and aerial lights, 7000 water pumps and delivered 637000 solar ovens/cookers (2009 data). This Program should provide solar energy for 600000 villages by 2032. In Bangladesh, the World Bank funded the electrification of 400 000 households, and ultimately this project will provide energy for 1.3 million households. Danish-German program, known as "Energizing Development" (EnDev), provided modern energy for 5 million people, and by 2015 plans predict to extend the program to supply 10 million people.

 

Hydroelectricity

Large hydroelectric plants are still being built - scale of construction growing, despite the protests of environmental organizations. Just in 2008 China launched more than 25GW of power, and India more than 5GW. Much greater support is behind small hydropower installations, currently estimated at 85GW. China is a leader in this field, increasing the installed capacity in small hydro plants with 4 - 6GW per year.

Geothermal Energy

The installed capacity of geothermal systems reached level of 10GW (2008 data). Most progress has been made in the USA where 120 projects delivered a total capacity of 5GW. About 40 countries are engaged in building and using geothermal energy installations of more than total 3GW output. In 2008, geothermal heating plants equipped with heat pumps reached a total power of about 30GWt. Total municipal and industrial direct geothermal heating (greenhouses, drying systems, etc.) reached 15GWt.

Bioenergetics

Power plants using biomass as a primary or secondary fuel, reached around 52GW of power. The biggest increase was recorded in the European Union and in China, estimated at 2GW. The largest share of biofuels consumed in power plants consists of waste from agriculture and forestry. Working installations are able to use biogas from the fermentation of waste from animal farms and sludge from sewage treatment plants. In Brazil, and Philippines, new installations consume residues from bioalcohol. Biofuel sector is growing at an accelerating pace. Compared with the year 2004 production of bioethanol doubled, and biodiesel production observed six-fold increase. In 2008, the amount of bioethanol used as a transport fuel, reached 67bln liters. More than half of this amount is produced in the United States from corn and other cereals. In 2008 Brazil increased two times the supply of bioethanol from sugar cane; amounting to 27bln liters. Biodiesel production reached a level of 16bln liters, of which nearly 70% is produced and consumed in Europe.

The possibility of producing energy from biomass is limited by photosynthesis potential. It is estimated that the total energy on the land converted into biomass is currently 4.560 EJ/year (GPP - Gross Primary Production). Half of it is consumed in the process of autotrophic respiration, so the quantity of energy available in the form of biomass is only 2.280 EJ (NPP - Net Primary Production). Many studies during last 20 years have been devoted to assess and increase global bioenergy output. The criterion limiting this output (or potential) is formed as a forecast for food needs of growing populations. Considering this factor and assuming unchanged advancement in bioenergy technologies - total potential can be estimated between 200 and 500 EJ per year. However complete halt of expansion of energy crops (meaning waste biomass consumption only) will reduce the global potential of bioenergy to about only 100 EJ.

Multiplication of bioenergy/area can and will be obtained by: improved agrotechnology, effective logistics of harvesting, efficient technologies of converting/connecting biomass energy to electricity grids. In U.S. corn crops may more than double by 2030. Considering the current technological capacity of biofuel production, this will allow to generate 240 mlnT of alcohol and 27 mlnT of biodiesel from the current unexpanded land area. Subsequent changes will bring progress in biotechnology and in genetic engineering. Industrial scale of converting green biomass into ethanol will generate extra inventory of this fuel estimated at 80 mlnT, plus 150 mlnT of feed. The amount of these products will exceed today's demand, so we may expect significant alternations in the market for fuels and agricultural products. [8]

Waste Disposal

Use of domestic and industrial waste for energy production creates controversies mostly due to bad experience with incinerators’ emissions. Since ancient times, incineration has been the choice for neutralization of unnecessary combustible materials. But today's enormous amount of waste contains substances that generate toxic compounds during the combustion. In response to this dilemma, strict and enforced regulations limit amount of toxic substances that can be emitted into environment. Necessity for waste disposal methods other than unlimited storage, combined with limiting regulations drive current incineration technology to the highest technical level.

Landfills in Europe and in the U.S. have increased difficulties with the location and the environmental requirements imposed by protective engineering agencies. To the contrary, production of energy from waste in modern installations brings income. In the European Union and in other industrialized countries, strong economic incentives and legal framework are in place to discourage and eliminate landfills. Directions as to how waste should be disposed, landfill taxation, extended producers’ responsibilities - these are examples of the legal economic policies of the governments. This difference between the waste storage and use of waste energy, still gives economical advantages to landfill operators. The main goal therefore, is to eliminate such difference in order to make production of energy from waste more attractive (if not profitable).

regional rate of waste generation between 1971-2002 in Mt/year [10]

It is estimated that the global domestic waste load exceeds 900 Mt/year. Energy from municipal waste incineration is between 6 to 14 MJ/kg, which is comparable to combustion of peat and brown coal. It follows that the power based on waste, may generate 5 - 13EJ of heat and electricity per annum. The recent global consumption of waste for energy production exceeds 130 Mt/year, that equals around 1 EJ. Biogas that is collected from landfills and sewage sludge fermentation is burned to produce more than 0.2 EJ/year. Significant quantities of biogas are collected by using the mechanical-biological waste transformation. This technology becomes more and more significant and increasingly involved in the waste utilization market. [11]

capacity of waste processing by bio-mechanical method

Issue of greenhouse gas emission becomes noticeable when it comes to waste management industry. This dictates appropriate changes. Waste management industry is responsible for the largest (after agriculture) stream of anthropogenic emissions of methane representing about or more than 5% of the total impact of the human economy on the greenhouse effect. Waste disposal that creates energy, has the least impact on the greenhouse effect, because it eliminates the potential methane emissions from the landfills. In the near term, preference for waste incineration can be expressed in the form of special economic restrictions imposed on methane and other noxious gases being released from the landfills.

greenhouse gas emissions from waste management between 1990-2020, expressed in Mt/year of CO2 equivalent

 

 

Summary and final conclusions:

The total renewable energy production reached 280GW of installed capacity in 2008 (75% increase when compared to 2004). The largest producers are China (76GW), USA (40GW), Germany (34GW), Spain (22GW), India (13GW), and Japan (8GW). In the U.S. and European Union increase of power from renewable energy was greater than from conventional systems (energy from gas, coal, oil and nuclear altogether). However, renewable energy still represents a small fraction of total energy production.

shares of installed capacity of renewable energy for selected countries (large hydro system not included)

When including large hydropower installations, renewable energy production reached 1,140GW. Within the world’s total energy generated by humans, the most primitive households kitchen hearths continue to produce five times more energy than technologies based on renewable energy. If we could improve the efficiency of home heating equipment in third world countries, the consumption of biomass for these purposes would be significantly reduced. Along these lines, the World Bank has implemented a support program, facilitating the purchase of 1 million efficient kitchen stoves for Ethiopia's population. More than 500 manufacturers of such appliances have been trained as experts in energy efficient hearth stoves. However, we are just beginning to probe and utilize advanced renewable energy technologies worldwide. Desired and awaited technical solutions are still at the stage of research and implementation. Without the strong support from governments and international institutions, renewable energy sector will not be able to replace fossil fuels in the global energy market.

biomass and energy

Biomass is a versatile raw material that can be used for production of heat, power, transport fuels, and bioproducts. [12]When produced and used on a sustainable basis, it is a carbon-neutral carrier and can make a large contribution to reducing greenhouse gas emissions. Currently, biomass-driven combined heat and power, co-firing, and combustion plants provide reliable, efficient, and clean power and heat. Production and use of biofuels are growing at a very rapid pace. Sugar cane-based ethanol is already a competitive biofuel in tropical regions. In the medium term, ethanol and high-quality synthetic fuels from woody biomass are expected to be competitive at crude oil prices above US$45 per barrel.

Feedstocks for bioenergy plants can include residues from agriculture, forestry, and the wood processing industry, as well as biomass produced from degraded and marginal lands. Biomass for energy may also be produced on good quality agricultural and pasture lands without jeopardising the world's food and feed supply if agricultural land use efficiency is increased, especially in developing regions. Revenues from biomass and biomass-derived products could provide a key lever for rural development and enhanced agricultural production. Certification schemes are already established to ensure sustainable production of forest biomass and could be adopted to guide residue recovery and energy crop production. Biomass utilisation will be optimised by processing in biorefineries for both products and energy carriers.

Given these possibilities, the potential contribution of bioenergy to the world energy demand of some 467 EJ per year (2004) may be increased considerably compared to the current 45-55 EJ. A range from 200-400 EJ per year in biomass harvested for energy production may be expected during this century. Assuming expected average conversion efficiencies, this would result in 130-260 EJ per year of transport fuels or 100-200 EJ per year of electricity. Most countries have biomass resources available, or could develop such a resource, making biomass a more evenly spread energy supply option across the globe. It is a versatile energy source, which can be used for producing power, heat, liquid and gaseous fuels, and also serves as a feedstock for materials and chemicals.

Current use of biomass for energy

On average, in the industrialised countries biomass contributes less than 10% to the total energy supplies, but in developing countries the proportion is as high as 20-30%. In a number of countries biomass supplies 50-90% of the total energy demand. A considerable part of this biomass use is, however, non-commercial and relates to cooking and space heating, generally by the poorer part of the population. Part of this use is commercial, i.e., the household fuelwood in industrialised countries and charcoal and firewood in urban and industrial areas in developing countries, but there are very limited data on the size of those markets. An estimated 6-9 EJ are included in this category [WEA 2000, WEA 2004].

Modern bioenergy (commercial energy production from biomass for industry, power generation, or transport fuels) makes a lower, but still very significant contribution (some 7 EJ per year in 2000), and this share is growing. It is estimated that by 2000, 40 GW of biomass-based electricity production capacity was installed worldwide (producing 0.6 EJ electricity per year) and 200 GW of heat production capacity (2.5 EJ heat per year) [WEA 2000]. Biomass combustion is responsible for over 90% of the current production of secondary energy carriers from biomass. Combustion for domestic use (heating, cooking), waste incineration, use of process residues in industries, and state-of-the-art furnace and boiler designs for efficient power generation all play their role in specific contexts and markets.

Biofuels, mainly ethanol produced from sugar cane and surpluses of corn and cereals, and to a far lesser extent biodiesel from oilseed crops, represent a modest 1.5 EJ (about 1.5%) of transport fuel use worldwide. Global interest in transport biofuels is growing, particularly in Europe, Brazil, North America, and Asia (most notably Japan, China and India) [WEA 2000, WEA 2004, IEA 2006b]. Global ethanol production has more than doubled since 2000, while production of biodiesel, starting from a much smaller base, has expanded nearly threefold. In contrast, crude oil production has increased by only 7% since 2000 [WorldWatch Institute 2007].

Bioenergy policies and market

Biomass and bioenergy are now a key option in energy policies [Schlamadinger 2006]. Security of supply, an alternative for mineral oil and reduced carbon emissions are key reasons. Targets and expectations for bioenergy in many national policies are ambitious, reaching 20-30% of total energy demand in various countries. Similarly, long-term energy scenarios also contain challenging targets. Sufficient biomass resources and a well-functioning biomass market that can assure reliable, sustainable, and lasting biomass supplies are crucial preconditions to realise such ambitions. To date, various countries have considerable experience with building biomass markets and linking available resources with market demand. Examples are found in Brazil, Sweden, Finland, Canada, and the Netherlands. Relatively recently, international trade in biomass resources has become part of the portfolio of market dealers and volumes traded worldwide have increased at a very rapid pace with an estimated doubling of volumes in several markets over the past few years [Faaij 2005].

Biomass resources

Various biomass resource categories can be considered: residues from forestry and agriculture, various organic waste streams and, most importantly, the possibilities for dedicated biomass production on land of different categories, e.g., grass production on pasture land, wood plantations and sugar cane on arable land, and low productivity afforestation schemes for marginal and degraded lands. The potential for energy crops depends largely on land availability considering that worldwide a growing demand for food has to be met, combined with environmental protection, sustainable management of soils and water reserves, and a variety of other sustainability requirements. Given that a major part of the future biomass resource availability for energy and materials depends on these complex and related factors, it is not possible to present the future biomass potential in one simple figure.

Table provides a synthesis of analyses of the longer term potential of biomass resource availability on a global scale. Also, a number of uncertainties are highlighted that can affect biomass availability. These estimates are sensitive to assumptions about crop yields and the amount of land that could be made available for the production of biomass for energy uses, including biofuels. Critical issues include:

- Competition for water resources: Although the estimates presented in Table 1 generally exclude irrigation for biomass production, it may be necessary in some countries where water is already scarce.
- Use of fertilisers and pest control techniques: Improved farm management and higher productivity depend on the availability of fertilisers and pest control. The environmental effects of heavy use of fertiliser and pesticides could be serious.
- Land-use: More intensive farming to produce energy crops on a large-scale may result in losses of biodiversity. Perennial crops are expected to be less harmful than conventional crops such as cereals and seeds, or even able to achieve positive effects. More intensive cattle-raising would also be necessary to free up grassland currently used for grazing.
- Competition with food and feed production: Increased biomass production for biofuels out of balance with required productivity increases in agriculture could drive up land and food prices.

Table 1: Overview of the global potential of biomass for energy (EJ per year) to 2050 for a number of categories and the main preconditions and assumptions that determine these potentials [Berndes 2003, Smeets 2007, Hoogwijk 2005a].

Biomass category

Main assumptions and remarks

Energy potential in biomass up to 2050

Energy farming on current agricultural land

Potential land surplus: 0-4 Gha (average: 1-2 Gha). A large surplus requires structural adaptation towards more efficient agricultural production systems. When this is not feasible, the bioenergy potential could be reduced to zero. On average higher yields are likely because of better soil quality: 8-12 dry tonne/ha/yr* is assumed.

0 – 700 EJ
(more average development:
100 – 300 EJ)

Biomass production on marginal lands.

On a global scale a maximum land surface of 1.7 Gha could be involved. Low productivity of 2-5 dry tonne/ha/yr.* The net supplies could be low due to poor economics or competition with food production.

<60 – 110 EJ

Residues from agriculture Potential depends on yield/product ratios and the total agricultural land area as well as type of production system. Extensive production systems require re-use of residues for maintaining soil fertility. Intensive systems allow for higher utilisation rates of residues.

15 – 70 EJ

Forest residues The sustainable energy potential of the world’s forests is unclear – some natural forests are protected. Low value: includes limitations with respect to logistics and strict standards for removal of forest material. High value: technical potential. Figures include processing residues 30 - 150 EJ
Dung Use of dried dung. Low estimate based on global current use. High estimate: technical potential. Utilisation (collection) in the longer term is uncertain 5 – 55 EJ
Organic wastes Estimate on basis of literature values. Strongly dependent on economic development, consumption and the use of bio-materials. Figures include the organic fraction of MSW and waste wood. Higher values possible by more intensive use of bio-materials. 5 – 50 EJ
Combined potential Most pessimistic scenario: no land available for energy farming; only utilisation of residues. Most optimistic scenario: intensive agriculture concentrated on the better quality soils. In parentheses: average potential in a world aiming for large-scale deployment of bioenergy. 40 – 1100 EJ

* Heating value: 19 GJ/tonne dry matter.

Focussing on the more average estimates of biomass resource potentials, energy farming on current agricultural (arable and pasture) land could, with projected technological progress, contribute 100 - 300 EJ annually, without jeopardising the world's future food supply. A significant part of this potential (around 200 EJ in 2050) for biomass production may be developed at low production costs in the range of $2/GJ assuming this land is used for perennial crops [Hoogwijk 2005b, WEA 2000]. Another 100 EJ could be produced with lower productivity and higher costs, from biomass on marginal and degraded lands. Regenerating such lands requires more upfront investment, but competition with other land-uses is less of an issue and other benefits (such as soil restoration, improved water retention functions) may be obtained, which could partly compensate for biomass production costs. Combined and using the more average potential estimates, organic wastes and residues could possibly supply another 40-170 EJ, with uncertain contributions from forest residues and potentially a significant role for organic waste, especially when biomaterials are used on a larger scale. In total, the bioenergy potential could amount to 400 EJ per year during this century. This is comparable to the total current fossil energy use of 388 EJ. Key to the introduction of biomass production in the suggested orders of magnitude is the rationalisation of agriculture, especially in developing countries. There is room for considerably higher landuse efficiencies that can more than compensate for the growing demand for food [Smeets 2007]. The development and deployment of perennial crops (in particular in developing countries) is of key importance for bioenergy in the long run. Regional efforts are needed to deploy biomass production and supply systems adapted to local conditions, e.g., for specific agricultural, climatic, and socio-economic conditions.

Conversion

Conversion routes for producing energy carriers from biomass are plentiful. Figure 1 illustrates the main conversion routes that are used or under development for production of heat, power and transport fuels. Key conversion technologies for production of power and heat are combustion and gasification of solid biomass, and digestion of organic material for production of biogas. Main technologies available or developed to produce transportation fuels are fermentation of sugar and starch crops to produce ethanol, gasification of solid biomass to produce syngas and synthetic fuels (like methanol and high quality diesel), and extraction of vegetal oils from oilseed crops, which can be esterified to produce biodiesel. The various technological options are in different stages of deployment and development. Tables 2 and 3 provide a compact overview of the main technology categories and their performance with respect to energy efficiency and energy production costs. The end-use applications of section discusses the likely deployment of various technologies for key markets in the short- and the long-term.

Figure 1: Main conversion options for biomass to secondary energy carriers [WEA 2000].

Table 2: Overview of current and projected performance data for the main conversion routes of biomass to power and heat and summary of technology status and deployment. Due to the variability of technological designs and conditions assumed, all costs are indicative [van Loo 2002, Knoef 2005, USDOE 1998, Dornburg 2001].

Conversion option

Typical capacity

 Net efficiency (LHV basis)

Investment cost ranges ($/kW)

Status and deployment

Biogas production via anaerobic digestion

Up to several  MWe 10-15% electrical (assuming on-site production of electricity)  

Well established technology. Widely applied for homogeneous wet organic waste streams and waste water. To a lesser extent used for heterogeneous wet wastes such as organic domestic wastes.

Landfill gas production Generally several hundred kWe As above. Very attractive GHG mitigation option.   Widely applied and, in general, part of waste treatment policies of many countries.
Combustion for heat Residential:
5-50 kWth
Industrial:
1-5 MWth
Low for classic fireplaces, up to 70-90% for modern furnaces. ~100/kWth for logwood stoves,
300-800/kWth for automatic furnaces,
300-700/kWth for larger furnaces
Classic firewood use still widely deployed, but not growing. Replacement by modern heating systems (i.e., automated, flue gas cleaning, pellet firing) in e.g., Austria, Sweden, Germany ongoing for years.
Combined heat and power 0.1-1 MWe
1-20 MWe
60-90% (overall)
80-100% (overall)
3500 (Stirling)
2700 (ORC)
2500-3000 (Steam turbine)
Stirling engines, steam screw type engines, steam engines, and organic rankine cycle (ORC) processes are in demonstration for small-scale applications between 10 kW and 1 MWe.
Steam turbine based systems 1-10 MWe are widely deployed throughout the world.
Combustion for power generation 20->100 MWe 20-40% (electrical) 2.500 –1600 Well established technology, especially deployed in Scandinavia and North America; various advanced concepts using fluid bed technology giving high efficiency, low costs and high flexibility. Commercially deployed waste to energy (incineration) has higher capital costs and lower (average) efficiency.
Co-combustion of biomass with coal Typically 5-100 MWe at existing coalfired stations. Higher for new multifuel power plants. 30-40% (electrical) 100-1000 + costs of existing power station (depending on biomass fuel + co-firing configuration) Widely deployed in various countries, now mainly using direct combustion in combination with biomass fuels that are relatively clean. Biomass that is more contaminated and/or difficult to grind can be indirectly co-fired, e.g., using gasification processes. Interest in larger biomass co-firing shares and utilisation of more advanced options is increasing.
Gasification for heat production Typically hundreds kWth 80-90% (overall) Several hundred/ kWth, depending on capacity Commercially available and deployed; but total contribution to energy production to date limited.
Gasification/CHP using gas engines 0.1 – 1 MWe 15-30% (electrical)
60-80% (overall)
1.000-3.000 (depends on configuration) Various systems on the market. Deployment limited due to relatively high costs, critical operational demands, and fuel quality.
Gasification using combined cycles for electricity (BIG/CC) 30-200 MWe 40-50% (or higher; electrical) 5.000 – 3.500 (demos)
2.000 – 1.000 (longer term, larger scale)
Demonstration phase at 5-10 MWe range obtained. Rapid development in the nineties has stalled in recent years. First generation concepts prove capital intensive.
Pyrolysis for production of bio-oil 10 tonnes/hr in the shorter term up to 100 tonnes/hr in the longer term. 60-70% biooil/feedstock and 85% for oil + char. Scale and biomass supply dependent; Approx 700/kWth input for a 10 MWth input unit Commercial technology available. Bio-oil is used for power production in gas turbines, gas engines, for chemicals and precursors, direct production of transport fuels, as well as for transporting energy over longer distances.

Table 3: Overview of current and projected performance data for the main conversion routes of biomass to transport fuels. Due to the variability of data in the various references and conditions assumed, all cost figures should be considered as indicative [Hamelinck 2006, IEA 2006b, Ogden 1999, IEA 2004, Lynd 1996].

Concept

Energy efficiency (HHV) + energy inputs

 Estimated production costs (€/GJ fuel)

Short-term

Long-term

Short-term

Long-term

Hydrogen: via biomass gasification and subsequent syngas processing. Combined fuel and power production possible; for production of liquid hydrogen additional electricity use should be taken into account.

60% (fuel only) (+ energy input of 0.19 GJe/GJ H2 for liquid hydrogen) 55% (fuel) 6% (power) (+ 0.19 GJe/GJ H2 for liquid hydrogen)

9 - 12

5 - 8

Methanol: via biomass gasification and subsequent syngas processing. Combined fuel and power production possible 55% (fuel only) 48% (fuel)
12% (power)
10-15 6-8
Fischer-Tropsch liquids: via biomass gasification and subsequent syngas processing. Combined fuel and power production possible 45% (fuel only) 45% (fuel)
10% (power)
12-17 7-9
Ethanol from wood: production takes place via hydrolysis techniques and subsequent fermentation and includes integrated electricity production of unprocessed components. 46% (fuel)
4% (power)
53% (fuel)
8% (power)
12-17 5-7
Ethanol from sugar beet: production via fermentation; some additional energy inputs are needed for distillation. 43% (fuel only)
0.065 GJe +
0.24 GJth/GJ EtOH
25-35 20-30 20-30
Ethanol from sugar cane: production via cane crushing and fermentation and power generation from the bagasse. Mill size, advanced power generation and optimised energy efficiency and distillation can reduce costs further in the longer term. 85 litre EtOH per tonne of wet cane, generally energy neutral with respect to power and heat 95 litre EtOH per tonne of wet cane. Electricity surpluses depend on plant lay-out and power generation technology. 8-12 7-8
Biodiesel RME: takes place via extraction (pressing) and subsequent esterification. Methanol is an energy input. For the total system it is assumed that surpluses of straw are used for power production. 88%; 0.01 GJe + 0.04 GJ MeOH per GJ output.
Efficiency of power generation in the shorter term, 45%; in the longer term, 55%
25-40 20-30

- Assumed biomass price of clean wood: $2/GJ. RME cost figures varied from $20/GJ (short-term) to $12/GJ (longer term), for sugar beet a range of $8 to $12/GJ is assumed. All figures exclude distribution of the fuels to fuelling stations.
- For equipment costs, an interest rate of 10%, economic lifetime of 15 years is assumed. Capacities of conversion unit are normalised on 400 MWth input in the shorter term and >1000 MWth input using advanced technologies and optimised systems in the longer term.
- Diesel and gasoline production costs vary strongly depending on the oil prices, but for indication: recent cost ranges (end 90s till 2010) are between $4 and $9/GJ. Longer term projections give estimates of roughly $6 to $10/GJ. Note that the transportation fuel retail prices are usually dominated by taxation and can vary between $0,50 and $1,30 /litre depending on the country in question.

Short-term represents best available technology or the currently noncommercial systems which could be built around 2010. Long-term represents technology with considerable improvement, large-scale deployment, and incorporation of process innovations that could be realised around 2040. This is also the case for the biomass supplies, assuming biomass production and supply costs around $2/GJ for plants which are close to the biomass production areas

Biomass-based energy carriers are competitive alternatives in situations where cheap, or even "negative-cost", biomass residues or wastes are available. In order to make large-scale bioenergy use competitive with fossil fuels, the conversion technologies, biomass production (especially from dedicated biomass crops), and total bioenergy systems require further development and optimisation. Table 4 gives an overview of the perspectives for bioenergy processes combined with main biomass resources.

Table 4: Generic overview of performance projections for different biomass resource, technology combinations and energy markets on shorter (~5 years) and longer (>20 years) timeframes. [WEA 2004, IEA 2006b, Faaij 2006, IPCC 2007, Knoef 2005, van Loo 2002]

Biomass resource

Heat

Electricity

Transport fuels

 

Short-term;
stabilising market
Longer term Short-term; strong
growth market worldwide
Longer term;
growth may
stabilise due
to competition
of alternative
options

Short-term;
growing market,
but highly policy
driven

Longer term;
potential key
market for
cultivated
biomass.
Organic wastes (i.e., MSW etc.) Undesirable for domestic purposes (emissions); industrial use attractive; in general competitive. Especially attractive in industrial setting and CHP. (advanced combustion and gasification for fuel gas) <$0,03-0,05/kWh for state-of-the-art waste incineration and cocombustion. Economics strongly affected by tipping fees and emission standards. Landfill gas recovery and utilisation is generally a competitive utilisation scheme. Similar range; improvements in efficiency and environmental performance, in particular through IG/CC technology at large-scale. N.A. In particular possible via gasification routes (see below)
Residues:
● Forestry
● Agriculture
Major market in developing countries (<$0,01-0,05 /kWhth); stabilising market in industrialised countries. Especially attractive in industrial setting and CHP. Advanced heating systems (residential) possible but not on global scale. $0,04-0,12 /kWh (see below; major variable is supply costs of biomass); lower costs also in CHP operation and industrial setting depending on heat demand. $0,02-8 /kWh (see below; major variable is supply costs of biomass) N.A. $5-10/GJ; low costs obtainable with lignocellulosic biomass (<US$2/GJ) advanced hydrolysis techniques and large-scale gasification (i.e., <1000 MWth) for MeOH/H2/FT, as well as improved sugar cane production and subsequent ethanol production in optimised distilleries.
Energy crops:
● oil seeds
● sugar/starch
● sugar cane
● perennial crops (i.e., short rotation cropping trees and grasses)
N.A. Unlikely market due to high costs of feedstock for lower value energy carrier; possible niches for pellet or charcoal production in specific contexts. $0,05-0,15 /kWh High costs for smallscale power generation with high-quality feedstock. Lower costs for large-scale (i.e., >100 MWth) stateof- the-art combustion (wood, grasses) and co-combustion. $0,03-8 /kWh Low costs especially possible with advanced cofiring schemes and BIG/CC technology over 100-200 MWe. $8-25 /GJ; lower figures for ethanol from sugar cane; higher for biodiesel (RME) and sugar and starch crops in Europe and North America.

 

Heat and power from biomass

Production of heat and electricity dominate current bioenergy use. At present, the main growth markets for bioenergy are the European Union, North America, Central and Eastern Europe, and Southeast Asia (Thailand, Malaysia, Indonesia), especially with respect to efficient power generation from biomass wastes and residues and for biofuels. Two key industrial sectors for application of state-of-theart biomass combustion (and potentially gasification) technology for power generation are the paper and pulp sector and cane-based sugar industry. Power generation from biomass by advanced combustion technology and co-firing schemes is a growth market worldwide. Mature, efficient, and reliable technology is available to turn biomass into power. In various markets the average scale of biomass combustion schemes rapidly increases due to improved availability of biomass resources and economies of scale of conversion technology. Competitive performance compared to fossil fuels is possible where lower cost residues are available particularly in co-firing schemes, where investment costs can be minimal.

Specific (national) policies such as carbon taxes or renewable energy support can accelerate this development. Gasification technology (integrated with gas turbines/combined cycles) offers even better perspectives for power generation from biomass in the medium term and can make power generation from energy crops competitive in many areas in the world once this technology has been proven on a commercial scale. Gasification, in particular larger scale circulating fluidised bed (CFB) concepts, also offers excellent possibilities for co-firing schemes. With biomass prices of about $2/GJ, state-of-the-art combustion technology at a scale of 40-60 MWe can result in electricity costs of around $0,04 to 0,06/kWh produced. Co-combustion, particularly at efficient coal-fired power plants, can result in similar or lower cost figures, largely depending on the feedstock costs. When Biomass Integrated Gasification/Combined Cycle technology becomes available commercially, electricity costs could drop further to about $0,03 to $0,04/kWh, especially with higher electrical efficiencies. For larger scales (i.e., over 100 MWe) cultivated biomass will be able to compete with fossil fuels in many situations [Knoef 2005, Williams 1996] The benefits of lower specific capital costs and increased efficiency may in many cases outweigh the increase in costs and energy use for transport for considerable distances once a reasonably well-developed infrastructure is in place.

Decentralised power (and heat) production is generally more expensive due to higher capital costs and lower efficiencies than large-scale systems, but could be economical for off-grid applications. The costs that could ultimately be obtained with e.g., gasifier/diesel systems are still unclear and depend strongly on what emissions and fuel quality are considered acceptable. CHP generation is generally attractive when heat is required with high load factors. Traditional use of biomass, in particular, is for production of heat for cooking and space heating. It is not expected that this traditional use will diminish in coming decades. Nevertheless, modernising bioenergy use for poorer populations is an essential component of sustainable development schemes in many countries. This creates opportunities and major markets - for example, for improved stoves, and production of high quality fuels for cooking (e.g., biofuel-based such as ethanol and Fischer-Tropsch liquids) - with considerable efficiency and health advantages. Furthermore, digesters producing biogas on a village level, can prove very effective in various countries (such as China and India) in solving waste treatment problems and supplying high-quality energy carriers (clean gas and power when used in gas engines) along with hygienic bio-fertilisers. For commercial heat production, reliable technology (e.g., boilers, advanced stoves, etc.) is commercially available for many industrial, district and domestic heating applications. Also, combined heat and power generation seems attractive to various markets. The production of heat and process steam from biomass for specific industrial applications is an economically attractive option, as is evident in the paper and pulp and sugar industries worldwide.

Liquid and gaseous fuels from biomass

Generally, the economics of "traditional" fuels like rapeseed methyl esther and ethanol from starch and sugar crops in moderate climate zones are unlikely to reach truly competitive price levels, although trade barriers such as tariffs and quotas can be used to increase the economic performance of these fuels [IEA 2004]. Also, the environmental impacts of growing annual crops are not as good as perennials because per unit of product considerably higher inputs of fertilisers and agrochemicals are needed. In addition, annual crops on average need better quality land than perennials to achieve good productivities. Perennial crops can also be grown on marginal lands, thereby achieving other potential benefits such as soil quality improvement. A key exception under "conventional" biofuels is production of ethanol from sugar cane in tropical regions where good soils are available. For countries where sugar cane production is feasible, commercially available technology allows for production of relatively low-cost ethanol. Brazilian experience shows that ethanol production is competitive with gasoline at oil prices over US$60/barrel [Goldemberg 2004].

Ethanol production capacity based on sugar cane is increasing substantially in African, Latin American, and Asian (e.g., India, Thailand, and China) countries. Furthermore, better use of cane residues (e.g., for power generation or use via hydrolysis processes) can further improve the performance of cane-based ethanol production. The production of methanol (and di-methyl esters or DME), hydrogen, Fischer-Tropsch liquids, and ethanol produced from lignocellulosic biomass offers much better perspectives and competitive fuel prices in the longer term, i.e., between 2010 and 2020. Partly, this is because of the inherently lower feedstock prices and versatility of producing lignocellulosic biomass under varying circumstances. Furthermore, the (advanced) gasification and hydrolysis technologies under development have the potential for efficient and competitive production of fuels, sometimes combined with co-production of electricity [Hamelinck 2006]. Comprehensive research and development strategies for such technologies are required, though. Such strategies should focus not only on development of technologies but also on long-term deployment and building the infrastructure and markets required for those technologies.

Market development and international trade

Biofuel and biomass trade flows are modest compared to total bioenergy production but are growing rapidly. Trade takes place between neighbouring regions or countries, but increasingly trading is occurring over long distances. The possibilities for exporting biomass-derived commodities to the world's energy markets can provide a stable and reliable demand for rural regions in many developing countries, thus creating an important incentive and market access that is much needed. For many rural communities in developing countries such a situation would offer good opportunities for socio-economic development.  Sustainable biomass production may also contribute to the sustainable management of natural resources. Importing countries on the other hand may be able to fulfil cost-effectively their GHG emission reduction targets and diversify their fuel mix. Given that several regions of the world have inherent advantages for producing biomass (including lignocellulosic resources) and biofuels in terms of land availability and production costs, they may gradually develop into net exporters of biomass and biofuels. International transport of biomass (or energy carriers from biomass) is feasible from both the energy and the cost points of view. The import of densified or pre-treated lignocellulosic biomass from various world regions may be preferred, especially for second generation biofuels, where lignocellulosic biomass is the feedstock and large-scale capitalintensive conversion capacity is required to achieve sound economics. This is a situation comparable to that of current oil refineries in major ports which use oil supplies from around the globe.

Very important is the development of a sustainable, international biomass market and trade. Proper standardisation and certification procedures are to be developed and implemented to secure sustainable biomass production, preferably on the global level. Currently, this is a priority for various governments, market players, and international bodies. In particular, competition between production of food, preservation of forests and nature and use of land for biomass production should be avoided. As argued, this is possible by using lignocellulosic biomass resources that can come from residues and wastes, which are grown on non-arable (e.g., degraded) lands, and in The Barra Grande alcohol and sugar production plant in Brazil produces ethanol from sugar cane on a commercial scale particular by increased productivity in agricultural and livestock production. Demonstration of such combined development where sustainable biomass production is developed in conjunction with more efficient agricultural management is a challenge. However, this is how bioenergy could contribute not only to renewable energy supplies and reducing GHG emissions, but also to rural development [Faaij 2006].

Competing markets for biomass

Total primary (the presumed mix of fossil fuels, renewables and nuclear) energy demand in 2050 varies between about 800 EJ and 1,400 EJ. As discussed previously, the total primary biomass supplies in 2050 could amount to 200-400 EJ. This is conservative relative to the increased availability of primary biomass. Assuming conversion to transport fuels with an expected average conversion efficiency of 65%, this would result in 130-260 EJ fuel. This is up to double the current demand and a similar range to the expected demand. Conversion to power with an assumed average efficiency of 50% logically results in 100-200 EJe, also a similar range to the expected future demand. Additional future demand for (new) biomaterials such as bio-plastics could add up to 50 EJ halfway through this century [Hoogwijk 2003]. It is clear, therefore, that biomass can make a very large contribution to the world's future energy supply. This contribution could range from 20% to 50%. The higher value is possible when growth in energy demand is limited; for example, by strongly increased energy efficiency.
Biomass cannot realistically cover the whole world's future energy demand. On the other hand, the versatility of biomass with the diverse portfolio of conversion options, makes it possible to meet the demand for secondary energy carriers, as well as biomaterials. Currently, production of heat and electricity still dominate biomass use for energy. The question is therefore what the most relevant future market for biomass may be.

For avoiding CO2 emissions, replacing coal is at present a very effective way of using biomass. For example, co-firing biomass in coal-fired power stations has a higher avoided emission per unit of biomass than when displacing diesel or gasoline with ethanol or biodiesel. However, replacing natural gas for power generation by biomass, results in levels of CO2 mitigation similar to secondgeneration biofuels. Net avoided GHG emissions therefore depend on the reference system and the efficiency of the biomass production and utilisation chain. In the future, using biomass for transport fuels will gradually become more attractive from a CO2 mitigation perspective because of the lower GHG emissions for producing second-generation biofuels and because electricity production on average is expected to become less carbon-intensive due to increased use of wind energy, PV and other solar-based power generation, carbon capture and storage technology, nuclear energy, and fuel shift from coal to natural gas.  In the shorter term, however, careful strategies and policies are needed to avoid brisk allocation of biomass resources away from efficient and effective utilisation in power and heat production or in other markets, e.g., food. How this is to be done optimally will differ from country to country.

The use of biomass for biomaterials will increase, both in wellestablished markets (such as paper, construction) and for possibly large new markets (such as bio-chemicals and plastics) as well as in the use of charcoal for steel making. This adds to the competition for biomass resources, in particular forest biomass, as well as land for producing woody biomass and other crops. The additional demand for bio-materials could surpass the current global biomass use (which is some 10% of the global energy use) [Hoogwijk 2003]. However, increased use of bio-materials does not prohibit the production of biofuels (and electricity and heat) per se. Construction wood ends up as waste wood, paper (after recycling) as waste paper, and bio-plastics in municipal solid waste [Dornburg 2005]. Such waste streams still qualify as biomass feedstock and are available, often at low or even negative costs. Cascading biomass over time in fact provides an essential strategy to optimise the CO2 mitigation effect of biomass resources. The reports [IPCC 2007] that the largest sustained mitigation benefit will result from a sustainable forest management strategy aimed at maintaining or increasing forest carbon stocks, while producing an annual sustained yield of timber, fibre, or energy from the forest. This could for example involve conventional forests producing material cascades (e.g., solid wood products, reconstituted particle/fibre products, paper products) with wood or fibre that cannot be reused/recycled being used for energy.

Comparison with other energy supply options

Table 5 provides a general overview of the current use, and the technical and theoretical energy potentials of various renewables: biomass, wind energy, solar energy, hydropower, and geothermal energy. Current and potential future energy production costs of electricity, heat, and fuels are given in Table 6.  State-of-the-art scenario studies on energy supply and mitigation of climate change agree that all climate-friendly energy options are needed to meet the future world's energy needs and simultaneously drastically reduce GHG emissions. Intermittent sources such as wind and solar energy have good potential, but their deployment is also constrained by their integration into electricity grids. In addition, electricity production from solar energy is still expensive. Hydropower has a limited potential [IPCC 2007] and commercial deployment of geothermal and ocean energy, despite their large theoretical potentials, has proved to be complex. Biomass in particular can play a major and vital role in production of carbon-neutral transport fuels of high quality as well as providing feedstocks for various industries (including chemical). This is a unique property of biomass compared to other renewables and which makes biomass a prime alternative to the use of mineral oil. Given that oil is the most constrained of the fossil fuel supplies, this implies that biomass is particularly important for improving security of energy supply on the global as well on a national level. In addition, competitive performance is already achieved in many situations using commercial technologies especially for producing heat and power. It is therefore expected that biomass will remain the most important renewable energy carrier for many decades to come.

Table 5: Overview of current use, and the technical and theoretical potentials of different renewable energy options [WEA, 2000].

Resource

 Current use (EJ)

Technical Potential (EJ)

Theoretical potential (EJ)

Biomass energy

50

 200 - 400

2,900

Hydropower 9 50 147
Solar energy 0.1 >1,500 3,900,000
Wind energy 0.12 640 6,000
Geothermal energy 0.6 5,000 140,000,000
Ocean energy NA NA >140,000,000

Total

56

>7,600

>144,000,000

Table 6:  Cost ranges (Euro-cents per unit) for production of electricity, heat, and fuel from various renewable energy options at present and longer term [WEA, 2004].

Technology

Current energy cost

Potential long-term future energy cost (2050)

Biomass energy (based on energy crops as feedstock)
● electricity
● heat
● biofuels

 $0.05-0.15/kWhe
 $0.01-0.05/kWht
 $0.08-0.25/GJf

 $0.04-0.10/kWhe
 $0.01-0.05/kWht
 $0.06-0.10/GJf

Wind electricity

$0.05-0.13/kWhe

$0.03-0.10/kWhe

Solar PV electricity

$0.25-1.25/kWhe

$0.05-0.25/kWhe

Solar thermal electricity

$0.12-0.18/kWhe

$0.04-0.10/kWhe

Low temperature solar heat

$0.03-0.20/kWht

$0.02-0.20/kWht

Hydroelectricity

$0.02-0.10/kWhe

$0.02-0.10/kWhe

Geothermal energy
● electricity
● heat

$0.02-0.10/kWhe
$0.005-0.05/kWhe

$0.01-0.10/kWhe
$0.005-0.05/kWhe

Conclusion

Biomass is the most important renewable energy option at present and is expected to maintain that position during the first half of this century and likely beyond that [IPCC 2007, IEA 2006a]. Currently, combined heat and power (CHP), co-firing and various combustion concepts provide reliable, efficient, and clean conversion routes for converting solid biomass to power and heat. Production and use of biofuels are growing at a very rapid pace. Although the future role of bioenergy will depend on its competitiveness with fossil fuels and on agricultural policies worldwide, it seems realistic to expect that the current contribution of bioenergy of 40-55 EJ per year will increase considerably. A range from 200 to 400 EJ may be expected during this century, making biomass a more important energy supply option than mineral oil today. Large enough to supply one-third of the world's total energy needs.

Bioenergy markets provide major business opportunities, environmental benefits, and rural development on a global scale. If indeed the global bioenergy market is to develop to a size of 300 EJ over this century (which is quite possible given the findings of recent global potential assessments) the value of that market at $4-8/GJ (considering pre-treated biomass such as pellets up to liquid fuels such as ethanol or synfuels) amounts to some $1.2-2.4 trillion per year. Feedstocks can be provided from residues from agriculture, forestry, and the wood industry, from biomass produced from degraded and marginal lands, and from biomass produced on good quality agricultural and pasture lands without jeopardising the world's food and feed supply, forests, and biodiversity. The pre-condition to achieve such a situation is that agricultural land-use efficiency is increased, especially in developing regions.

Considering that about one-third of the above-mentioned 300 EJ could be supplied from residues and wastes, one-quarter by regeneration of degraded and marginal lands, and the remainder from current agricultural and pasture lands, almost 1,000 million hectares worldwide may be involved in biomass production, including some 400 million hectares of arable and pasture land and a larger area of marginal/degraded land. This is some 7% of the global land surface and less than 20% of the land currently in use for agricultural production. There are rapid developments in biofuel markets: increasing production capacity, increasing international trade flows, increased competition with conventional agriculture, increased competition with forest industries, and strong international debate about the sustainability of biofuels production. Biomass is developing into a globalised energy source with advantages (opportunities for producers and exporters, more stability in the market) and concerns (competing land use options, sustainability).

Biomass trading and the potential revenues from biomass and biomass-derived products could provide a key lever for rural development and enhanced agricultural production methods, given the market size for biomass and biofuels. However, safeguards (for example, well-established certification schemes) need to be installed internationally to secure sustainable production of biomass and biofuels. In the period before 2020 substantial experience should be obtained with sustainable biomass production under different conditions as well as with deploying effective and credible certification procedures. Especially promising are the production of electricity via advanced conversion concepts (i.e., gasification, combustion, and co-firing) and biomass-derived fuels such as methanol, hydrogen, and ethanol from lignocellulosic biomass. Ethanol produced from sugar cane is already a competitive biofuel in tropical regions and further improvements are possible. Both hydrolysis-based ethanol production and production of synfuels via advanced gasification from biomass of around E2/GJ can deliver high quality fuels at a competitive price with oil down to US$45/ barrel. Net energy yields per unit of land surface are high and GHG emission reductions of around 90% can be achieved, compared with fossil fuel systems. Flexible energy systems, in which biomass and fossil fuels can be used in combination, could be the backbone for a low risk, low-cost, and low carbon emission energy supply system for large-scale supply of fuels and power, providing a framework for the evolution of large-scale biomass raw material supply systems.

Analysis of Energy

Some writers in the 1970's claimed that energy from biomass would require more energy inputs than would be produced. Energy cost of converting the biomass energy into a useful fuel source must be included. Early calculations pertaining to production of ethanol from maize grain showed, that fermentation, distillation, and drying of the ethanol required more energy than production of the grain. However recently more efficient methods, especially ethanol dehydration, can turn it around making biomass ethanol net positive energy source. In addition, co-products like oil and protein livestock feed come from the maize grain conversion. Ethanol production from maize is currently stable in the US and is a substantial liquid fuel energy source. Production of ethanol from sugar cane continues at a high level in Brazil and most automobiles there run on not totally dehydratet ethanol.

Energy analysis, along with economic and environmental analyses are necessary in order to define the behavior of bioenergetic systems including agricultural production. The goal is clear: to reduce energy inputs or to look for other renewable energy sources in agricultural processes. This goal is combined, if possible, with the reduction of production costs and utilization of environmentally friendlier production methods as part of a better management system. Modern management through precision farming will allow the saving of energy by application of the right quantities of seed, fertilizer, and pesticides according to the local variations of production in each field.

Methodologies and Approaches

The methodologies applied to energy analysis are quite different considering their fundamentals and approaches. Historically, the first approach considers all types of energies, renewable and nonrenewable; stating criteria in relation to energy quality, proposes interconnections between the human made energy and natural energy of ecosystems, considers manpower as a high-quality energy source and evaluates energy flows for the net energy analysis. Recently, the analysis procedure relies on assigning nonrenewable energy amounts to each production factor. Total energy in a process is established by adding partial energies associated with each step, without assigning a quality factor.

In an energy analysis of production systems it is necessary to consider the following steps [Fluck 1992]:

  • Set a limits in the process or system in such a way that all inputs and outputs, in a certain time interval, are evaluated. For example, in crop production, it is necessary to quantify the energy requirements of selected inputs like fuel tractors, farm machinery, pesticides, fertilizer, labor, transportation, etc.

  • Assign energy requirements to all inputs.

  • Multiplication of all inputs by their corresponding assigned energy value and add these values to obtain the total energy in the process.

  • Identify and quantify all outputs, establishing criteria for energy embodied in the main products and by-products.

  • Relate output energy to total energy in order to obtain the energy ratio (relationship between output and input energies) and the energy productivity (units of product obtained per unit of input energy).

  • Apply energy analysis results.

The application of analysis is evident in the production of biofuels, but it can be of interest for any agricultural product to compare production alternatives while complementing economic and environmental analysis. Unifying criteria for assigning amounts of energy to each input presents difficulties.. The lack of reliable data for each country or region forces us, in many cases, to take values from other countries for which circumstances are different. That is the case of fertilizer production: the amount of energy needed per fertilizer unit (e.g., nitrogen) depends to a great degree on the technical level of the manufacturing industry and also on the distance of transportation, which is variable but can be taken as an average value for a region. Another problem is considering different qualities of energy: attached to it contaminations, whether it is renewable, or how much it costs, etc. For example, electricity from a hydroelectric plant (renewable, more efficient in producing mechanical power) is of higher quality than coal (nonrenewable and less efficient). There are also problems with the energy assigned in cases of multiple outputs. Fluck [Fluck 1982] recommended that the energy apportioned to agricultural systems that have multiple outputs should be proportional to the relative values of the products. Let us take cereal production: it is impossible to separate the energy needed to form grain from the one needed to form straw. It has to be assigned according to the use given to the straw and to its corresponding value. When an energy analysis is made, it is important to specify the procedure used for establishing the amount of energy assigned to each item.

Energy Ratio

The energy ratio (ER) is defined as the ratio of the caloric heat of the output products and the total sequestered production energy. This index allows us to know the influence of the inputs (expressed in energy units) in obtaining consumer goods, normally related to the food production, but that can be applied appropriately to the energy balance of biomass or biofuel production. In a strict sense, “the energy ratio can be applied to isolated systems, in which it is important that the output energy is greater than the input, in order to assure their subsistence.” In industrialized agriculture, farming for energy must be energetically sound, but there is no reason why farming for other products should cost less energy than is produced. In short, in developed countries at present, energy to produce human food is not a limiting factor.

Net Energy Gain

Net energy gain (NEG) or net energy production is the difference between the gross energy output produced and the total energy required for obtaining it. In agricultural processes this energy is normally related to the unit of production (square area , e.g., 1 ha).

Energy Productivity

Energy productivity (EP) is the measure of the amount of a product obtained per unit of input energy. Its relationship to the ER is direct: Their ratio is the calorific value of the product. EP is specific for each agricultural product, location, and time. It can serve as an evaluator of how efficiently energy is utilized in different production systems that yield a particular product. Improved EP can be obtained by either reducing the energy sequestered in the inputs or by increasing the yield of product - that is reducing losses.

Energy Inputs

Energy consumption in agricultural systems is associated with all inputs that take part in the production processes. These inputs have to be defined and quantified according to their energetic intensities. The total energy per production unit (e.g., hectare) is established by the addition of the partial energies of each input referred to the unit of production. After the yield produced is obtained, it is possible to calculate the ER, the NEG, and the EP.

In energy analysis, it is necessary to distinguish between inputs that are completely consumed in the period in which they are used (fuels, fertilizers, chemicals, seeds, etc.) and inputs that participate in different processes during a longer period (tractors, farm machinery, irrigation equipment, etc.). In the latter case, the energy of materials, manufacturing and maintenance has to be divided into fractions throughout its useful life. If the duration of the intervention of each factor is known, it is possible to establish the associated energy for a process. Energy inputs can be classified in two main groups: direct-use energy and indirect-use energy.

Direct-use Energy

At present, most of the energy used directly in agriculture comes from a fossil origin such as diesel fuel, gasoline, liquid petroleum gas, coal, and from electricity (all these are not-renewable sources. Tractors and self-propelled farm machinery are powered generally with diesel engines (~60% of total energy use in agriculture industry). Liquid petroleum gas fuel (LPG) is used mainly for heating and drying ,and electricity for irrigation systems. Developing countries also use these fuels, although in a smaller amount. Animal traction is common , for which the real fuel is the caloric value of the animals’ feed. Their needs are covered with crops produced in the same farm or from the surrounding area.

To establish the values of the energy sequestered in these inputs, it is necessary to consider their heating value, adding the energy needed to make their energy available directly to the farmer. For example, a liter of diesel fuel contains 38.7MJ. However, to extract from the ground, refine, and transport a liter of diesel fuel to the farmer, an additional 9.1MJ are needed. Thus the energy cost to consume the liter of fuel totals 47.8MJ (see Table).

Diesel fuel consumption for different farm equipment is given in Table.

Indirect-use Energy

Although approximately one-third of the energy consumed on the farm is for direct use, nearly two-thirds of the energy is consumed indirectly. Indirect use refers to the energy used to produce equipment and other materials that are used on the farm. The major indirect use for energy is for fertilizers and primarily for nitrogen fertilizers. Other important items are farm machinery and biocides. In irrigated areas, irrigation equipment is relevant as well.

a. Farm Machinery.

The production and the repair of farm machinery are important issues in the total energy balance. We consider several steps in calculating this energy:
1) energy used in producing the raw materials (for example: steel, 22 - 60 MJ/kg);
2) quantity of energy required in the machinery manufacturing process; (27-55 MJ/kg)
3) transportation (placement) of the machine at the farm site (estimated ~9 MJ/kg);
4) energy sequestered in maintenance/repairs of machinery.

The total energy sequestered in different types of farm machinery is given in Table:


Mean value per kilogram and year for a group of tractors and agricultural machines is given in Table:

To evaluate the energy input for machinery and equipment per hectare, it is necessary to know the weight of the machinery used in the farm, its working life span, and the average surface on which it is used annually. When we assign the energy values for each and specific machinery used, it is possible to establish the energy input for the farm machinery per hectare, having calculated previously the average weight of machinery utilized per hectare and per year. For example, for mechanized corn production, ~55 kg of equipment is used per hectare and year.

Factors Affecting Tractor Efficiency

Tractors are the most important machines in agriculture, and their performance is of the greatest importance in achieving high efficiency in crop production (meaning a best positive return on energy for the whole particular system including crop production for biofuels).

Engines

The latest developments in the diesel engines of tractors are related to:

- higher pressure of the injection pumps (~1000 bar),
- integrated pump-nozzle units,
- electronic injection control,
- a broad introduction of turbo-charging and inter-cooling.

Unfortunately, the turbocharger heats the air going into the engine. The heat reduces the density of the air. Intercooling reduces the temperature of the air inlet in the combustion chamber, which thereby increases the air density, which in turn increases the power output. In some tractor turbocharged diesel engines, an intercooler with a waterjacket coolant is used. Such an installation limits the aftercooling to ~25oC above the water-jacket temperature. Using air to cool the air from the turbocharger is more effective in lowering the temperature; however, the size of an air-cooled intercooler usually discourages its application for mobile equipment.

The efficiency of internal-combustion engines can be described by engine performance maps. These maps show lines of equal specific fuel consumption and consequently constant engine efficiency, within the diagram of torque/engine speed. They can be used by tractor operators to control engines by use of microcomputers to achieve optimal conditions of operation (power - torque - fuel consumption). For most agricultural tractors, performance maps are available from OECD Tests Reports.

An example of performance map above, shows a tractor that runs at the same speed with 40% of maximum power in two different gears. At point 1 fuel consumption is 225 g/kWh and at point 2, it is 275 g/kWh. If the tractor has a nominal power of 80 kW, the fuel saved working at point 1 in relation to point 2 is

F = 0.4 x 80  x (275 - 225) = 1600 g/h

If we assume for diesel fuel a density of 850 g/L, we find that

F = 1600/850 = 1.88 L/h

Therefore there is a substantial fuel saving, when the proper gear is used to obtain the optimum performance. In the above case, when the engine is run at a high speed (point 2), fuel consumption is greater than that at point 1 and also the life of the engine is reduced.

Transmissions

In modern tractor design there is a change from synchronized to power-shift transmissions. Power shifting means changing from one gear ratio to another without the use of a clutch or any interruption of power. Power-shift transmissions save energy, allowing us to change gears without having to disengage the power coming from the engine. Planetary gears are predominantly used in power-shift transmissions. Recently, reverse gear for all speeds have been also introduced in medium-sized tractors of 60 - 90 kW [Renius 1992].

Hydrostatic transmissions are used in special agricultural equipment, but not so much in standard tractors. In some designs, the hydraulic pump is separated from the propulsion parts of engine. Therefore motors are located directly on the drive wheels. Such arrangement allows for more flexibility in positioning the drive wheels and also eliminates the need for a differential. The efficiency of hydrostatic transmissions is low (50% - 70%) compared with mechanical transmissions (85% - 95%).

Electric transmissions may be found in large engines (machines). Although their efficiency is high (95% - 98%), they do not improve the total effectiveness of the whole internal combustion engine that runs on fossil fuel (such motors have usually a low efficiency of 30% - 35%). The price of electric generators and motors is quite high, and their weight is also considerable. Their advantages are: precise steering and maintenance as well as safe operation.

Tires

The development of radial tires having at a low inflation pressure reduces soil compaction. The slippage is also substantially reduced for a given thrust torque, and consequently less fuel consumption is achieved. To adapt the pressure of radial tires to every work situation, it is necessary for the tractor to have a compressor and a central tire inflation system to change the pressure of the tires when necessary.

A substantial number of evaluations have been made that compare the performance of bias and radial agricultural tires on both two-wheel- and four-wheel-drive tractors. Significant performance improvements (wheel slip reduction of 6% - 7%, torque power increase of 10% - 12%, and fuel savings of up to 20%) have been achieved in both types of tractors when radial tires at low inflation pressures are used instead of bias tires [Stout 1992].

General Considerations in Tractor Operations

Several recommendations to achieve greater efficiency in tractor applications are considered [Kutzbach 1989]:

a. For Heavy Traction Works.
-  The axles of the tractor should be ballasted with different weights and the tires should also filled with water in such a way that the soil is not compacted.
- The tractors should be in the four-wheel traction mode.
- The gear should be chosen in such a way that the real work speed will be as high as possible.
- The depth of plowing should be established in such a way that the wheels slippage ’S’ is within 10% - 15% range.
The slippage is calculated by the formula:

S = 1 - va / vt

where:

- S is the wheel slip,
-
va is the actual travel speed, and
-
vt is the theoretical wheel speed.

b. For Light Traction Works in the Field.
- Reduce the weight of the tractor to avoid formation of tracks in the ground.
- The wheels should be big and wide or use twin wheels.
- Apply low pressure in the tires.
- Maintain ‘S’ not bigger than 10%.

c. For jobs done with mounted machines (fertilizer spreaders, sowing machines, or sprayers):
- The weight of the machine and that of the tractor should be maintained as low as possible to reduce rolling resistance.
- Narrow wheels, if used, should have diameter as big as possible and low pressure.
- Always try to drive in the same track to affect only a small percentage of the soil surface.

d. For transport work:
- Set up high pressure on the tires to reduce rolling resistance (it is advantageous to have a air compressor for tires mounted on the tractor).
- Disconnect the four-wheel drive. Use it only for special heavy traction (as in a big slope).

In general, it is important to attune the combination of tractor and tillage machine/equipment being dragged. When the machine is too small for a tractor, much fuel is unnecessarily wasted.

Energy Saving in Tillage Systems

Tillage may be defined as a modification of soil structure due to the mechanical work of tillage equipment. This work involves large amounts of energy necessary to cut, break down, flap soil layers, reduce clod size, rearrange aggregates, etc. The main objective of tillage is to obtain the best soil conditions for growing crop. These conditions differ from site to site, depending on soil and weather conditions. Any actions on and treatment of soil require direct use of energy, mainly fuel. The energy is conducted from the engine to the tillage equipment through several components of the whole system, in which important losses can be expected.

Overall efficiency (OE) in the use of fuel energy is the result of multiplying partial efficiencies at different steps (engine, transmissions, wheels, and implement):

where

is the engine efficiency (0.3- 0.4),
is the transmission efficiency (0.8 - 0.9),
is the tractive wheel efficiency (0.5 - 0.7), and
is the implement efficiency (0.4 - 0.8).

These values allow calculation of the overall efficiency ranging from 2.5% to 10%, depending on ground properties. In many cases, tillage preparation needs at least two or three steps so that overall efficiency is close to 1%, according to Chancellor [Chancellor 1982].  Overall efficiency in all operations may be stated as a relationship between the energy directly applied on the soil in the laboratory to obtain a desired particle size, and the energy of the fuel required in the field for obtaining the same effect [Hakansson  1995].

Tillage and Soil Compaction

An important objective for tillage is to reduce soil compaction resulting from natural factors (rain, swelling - shrinkage processes, etc.) and human activity like vehicles’ traffic. Severe soil compaction reduces both air and water permeability, root penetration, nutrient uptake, and crop yield; on the other hand, it increases serious environmental problems such as soil degradation and loss of bio-genes. Soil compaction increases energy consumption in tillage operations for two main reasons:

 - The specific draft force increases in the same proportion as the bulk density at the same soil moisture content, and higher tractor slippage can be expected.
- If the soil is cloddy after primary tillage, secondary field passes are necessary to achieve the appropriate size and distribution of the soil aggregates.

There are several ways to reduce these constraints [Hakansson 1995]:

- Carry out tillage operations at the optimum soil moisture content.
- Use high capacity four-wheel-drive tractors and tillage equipment.
- Improve the organization and planning of transport operations taking place across the field;
- Reduce traffic as much as possible.
- Reduce the tire pressure.

Conventional Tillage

Conventional tillage may be defined as traditional practices carried out in seed-bed preparation. In most cases, it is associated with the use of a moldboard plough or a disk plough for primary tillage. Both types invert soil layers to bury crop residues, weeds, fertilizers, and loose soil to increase its porosity. Heavy disk harrows, chisel plough and heavy cultivators also can be considered for primary tillage. Depth of tillage varies according to the tool (machine), soil type, weather conditions, and crop requirements. With moldboard and disk plows, it ranges from 20 to 35 cm and even more; with chiseling plow and cultivating, penetrates are ~20 cm, and with disk harrowing up to 15 cm. Secondary tillage is required for creating optimum soil conditions for sowing and advanced germination. Machines commonly used are light cultivators, vibrating cultivators, light harrows, rollers, etc., and powered one like rotary tillers, oscillating harrows, rotary harrows, etc. In any case, required seed-bed layer should reach depth of 10 or 12 cm on a average.

Two main factors affect energy consumption in tillage practices [Srivastava 1993]:

a. Soil Type andTillage Conditions.

The soil moisture content has a big influence on soil mechanical properties like cohesion, friction, and adhesion. Clayey soils are cohesive, and this variable is strongly conditioned by moisture content. Under dry conditions cohesion can reach values up to ten times higher than that under wet conditions, so that the specific draft force increases in the same proportion. On the other hand, heavy, wet tilth tends to be cloddy; more energy is required for breaking up clods into fine aggregates. Under wet conditions soil is sticky and the adhesion forces are predominant, making the earth work difficult. Sandy soils have low cohesion and high friction, so the moisture content does not have a significant influence on the specific draft force. The optimum moisture content of most soils should be close to its plasticity limit.

b. Implements.

Energy consumption is related to the working action of tools. For primary tillage, moldboard plowing requires more energy than chiseling. Both systems mean two different ways to produce soil breakup. By plowing, soil is cut, lifted, turned, and projected onto a side furrow. The specific draft force depends on the moldboard type, the travel speed, the soil bulk density, and moisture content. By chiseling, soil is pushed forward and laterally to produce its breakup. This machine requires ~30% - 40% of the energy required by the moldboard plow under the same tillage conditions. For secondary tillage, non-powered tools require less energy than powered ones, but also require more field operations for obtaining the same size of aggregates. Powered machines need extra energy to propel their own tools (sometimes more than one implementation) that are dragged behind, but they work more efficiently. One run is often enough for full soil preparation. Table shows specific work for the main tillage implements.

 

Minimum Tillage

Minimum tillage means either the reduction of the depth in tillage or the number of field operations. For primary tillage, chisels, cultivators, and disk harrows are commonly used. Minimum tillage would mean reducing energy consumption by ~50%, if we take into account that deep tillage reaches down to 15 or 20 cm. In some cases of minimum tillage, weeds are not accurately controlled, so a herbicide might be necessary.

Secondary tillage is carried out with the same implements. Seed-bed preparation may be achieved in one or two passes in which a combination of chisel, powered implement, roller and drill, or planter is frequently used, mainly in humid regions when time for sowing is short. Minimum tillage can be included in the conservation tillage systems on the condition that a minimum of 30% of soil surface should stand covered with crop residues after seeding.

Mulch Tillage

For areas where erosion is a problem, mulch tillage is an accurate practice for its prevention; therefore this technique is included in conservation tillage systems [Perdok 1983]. Soil is loosened down to 10 or 13 cm in most cases by chisels, cultivators, harrows, and Vsweep implements. The latter provides good weed control. Other implements also used are rod weeders and stubble treaders. If soil presents compaction problems, a deep loosener (paraplow) is used to increase macroporosity and water infiltration. With mulch tillage, a minimum of 33% of the previous crop residues is left on the soil surface.

Strip Tillage

Strip tillage creates flat or ridged rows, eight to ten inches wide.Crop residues from previous harvesting cover 50% of the undisturbed, weed-suppressed soil surface. This type of tillage, performed with special equipment (sweeps, disc harrow, rotary tiller, can require the farmer to make multiple trips, depending on the strip-till implement used, and field conditions. The disk opener of the planting unit slices the soil and the seed is dropped into the furrow that has been created and then a press wheel closes the furrow.

No Tillage

No tillage is also called direct planting or zero tillage. The soil is disturbed in only a narrow bands ~3–8 cm wide, by the openers of seeders, mainly coulters and disks. Herbicides are applied before seeding. This system saves plenty of energy compared with the other systems mentioned, but it is not possible to apply it in all cases. Good natural soil drainage is the first condition required. On the other hand, weeds and pests, must be controlled as soon as possible; otherwise they will seriously limit the success. Large amounts of crop residues on the soil surface should have been previously accurately treated (chopping, spreading, etc.). Both drills and planters in direct drilling or planting need additional weight because the soil has not been previously loosened by tillage implements. In humid areas, where high rates of crop residues can be expected, soil disk openers are frequently used. In dry regions, with hard soils and low crop residue content, hoe (knife) openers allow a good seeding and are lighter than disk openers. After seeding, ~70%–90% of the soil surface is covered with previous crop residues. Table shows overall energy consumption per hectare for different tillage systems.

b. Fertilizers.

Fertilizers are chemicals being incorporated into the soil or directly on top of the soil, for the nutrition and normal growth of the plants. Crop plants take up nutrients at different rates, so nutrients have to be incorporated into the soil to maintain its productive potential. The process involved is known as fertilization. Plants build their cells using 15 major elements. Oxygen, hydrogen, and carbon form 90% - 92% of the plants' weight. The other elements can be classified into three groups:

  • Primary nutrients (nitrogen, phosphorus, and potassium).

  • Secondary nutrients (calcium, magnesium, and sulfur).

  • Micronutrients (copper, iron, manganese, molybdenum, boron, and zinc).

According to the source, fertilizers are divided into three categories:

  • Chemical: These are manufactured from the air to obtain nitrogen fertilizers and also from geological material to obtain phosphate and potash fertilizers.

  • Organic: These are obtained from crop residues animal farm wastes.

  • Biological: These are related to nitrogen uptake by micro-organisms placed in the cells of the roots of legume crops.

Chemical fertilizers are widely used in agricultural crops and require high rates of direct energy for their production, mainly in the nitrogen fertilizer industry. Ammonia is the basic source for commercial nitrogen fertilizers; it is produced by the synthesis of hydrogen with atmospheric nitrogen under high-pressure conditions. The chemical processes need natural gas both to heat steam and to react with water to obtain hydrogen at temperatures ranging between 400 and 1200oC during certain stages of production [Mudahar 1987]. Mined phosphate is the source of all phosphate fertilizers. This raw material can be applied directly after being processed (drying, grinding, etc). Most commercial phosphate fertilizers come from phosphoric acid. The latter is obtained by treatment of phosphate rock with sulfuric acid. The basic material for potash fertilizer products is potassium salt. The extraction can be performed by mining or by solar evaporation, when the raw material comes from lake beds. Average energy used for production of active constituent (kg) in most important chemical fertilizers:

Overall energy consumed by production of particular fertilizer includes production, packaging, transportation, and application. For mixed fertilizers, it is necessary to add 1.14 MJ/kg for conversion to liquid form.

Organic residues contain different degrees of nitrogen, phosphorus, and potassium, depending on the origin of the material and the method of processing and storage. In this case calculation for absorbed energy is based on percentage of the active component in a dry weight of fertilizer. Energy intensities for production of minerals like nitrogen, phosphorus, and potassium is roughly: 70, 8, and 6 MJ/kg, respectively.

Fertilizer Management

Both the fuel and the mineral fertilizers require the highest amounts of energy compared with the other inputs in crop production. Accurate fertilizer management can improve energy use, mainly if we refer to nitrogen. This nutrient has two important characteristics: the high energy content incorporated during manufacture and its ability to be quickly washed out by water. It is recommendable to increase crops profitability and reduce fertilizer losses by introducing management practices.

Fertilizing Rates

In most cases, a continual assessment of soil nutrient levels allows us to knowwhat the optimum rates to be applied are. Experimentswith different fertilizer rates lead us to make certain recomendations to the farmers to attain the greatest efficiency. From the energetic point of view, the procedure is similar to the economic evaluation.

Crop yield can be characterized as a function y = f (x), quadratic or exponential, of the nutrient supply x. The most profitable application rate of a fertilizer is the optimum energetic rate, which, by definition, occurs when the energy involved in the last increment applied equals the value of the last additional yield that resulted from an increment of fertilizer [Fox 1986]. To obtain this rate it is necessary to solve

d[(Ec / E f ) y] / dx = 1

where

- y is the crop yield (in kg . ha-1),
-
x is the fertilizer rate supply (in MJ . ha-1),
-
Ec is the gross energy intensity of the crop (in MJ . kg-1), and
-
Ef is the energy intensity of the fertilizer (in MJ . kg-1).

This procedure allows us to establish comparisons among different management practices for any crop with the same soil and weather conditions when a specific nutrient is considered as a limiting factor.

Loss Reduction

Fertilizer loss influences crop yield and create economic and environmental problems such as contamination of ground waters, aquifers, lakes and rivers. Nitro-fertilizers are the most difficult to control - they become volatile producing gases as NO2, N2, NH3. The main processes involved in nitrogen losses are Soil erosion, leaching, denitrification, and ammonification can be expected. [Soane 1995], showed that for every 100 kg/ha of nitrogen applied in the USA, 50% is consumed by harvested crop, 25% is leached and ends up in ground waters, 5% is lost by run-off to rivers/lakes, and 20% is lost in primary denitrification.

Table shows the influence of some factors in the different processes in which nitrogen is lost.

Reducing losses can be achieved by accurate fertilizer management if the following aspects are considered [Buchholz 1987]:

a. Fertilizer Location.
In many cases, fertilizers are distributed throughout the vast area application. Shortage of fertilizer can be quickly addressed in such case. Rotary spreaders distribute fertilizers more than 24 m wide. In this case the control of the fertilizer is obtained by avoiding its overlaps'-the most important factor in getting a uniform distribution. Drop-type and pneumatic equipment can be used for spreading fertilizer on top of the soil or for undersurface placement. They cover smaller bands of the ground than rotary spreaders, but provide greater uniformity of coverage. In conservation tillage systems, important amounts of nitrogen are conserved by crop residues on soil surface. Sideband applications in which nutrients are located close to, at the side of, or below the seed increase the chances that the roots of the plants absorb the fertilizer. Efficiency is increased because losses are reduced. This method is successfully used in no-tillage systems where seeding and fertilizing are carried out in one operation with combined equipment.

b. Fertilization Timing.
Majority of losses can be avoided if fertilizer is applied in several sessions, especially in humid areas where leaching is a serious problem. Fertilizer is more efficient when it is supplied just before the time of fertilizer's greatest plant consumption.

c. Crop Rotation with Legumes.
Legumes posses large capacity for increasing the nitrogen level of soil. This happens due to their roots symbionts able to trap and hold nitrogen. Consequently a reduction in fertilizer/mineral rates and lower energy in crop production are attained. For alfalfa, fixed nitrogen can be higher than 200 kg/ha; for clover, it ranges from 115 to 200 kg/ha; for vetch, 80 to 100 kg/ha; for peas, 70 to 80 kg/ha; for beans, 60 to 90 kg/ha; for soybean, 50 to 100 kg/ha, etc.

c. Chemical Biocides.

During the past 50 years, chemical biocide consumption in the world has increased substantially. Most farmers need them every year to control weeds, pests, and diseases. Biocides act faster than any non-chemical control systems. Biotechnology provides new products all the time, that when applied in low amounts, allow control of weeds, pests, and diseases more efficiently. The energy spent (embodied) in active ingredient production includes manufacturing, formulation, and packaging (shown in Table):

To establish total spent energy, it is necessary to add transportation and application for particular biocide [Green 1987]. An active ingredient requires both direct and indirect energy for its formulation. Direct energy includes fuel, electricity, and steam to synthesize the biocide’s active organic compounds. Indirect energy comprises the amount of crude oil or natural gas to produce ethylene, propylene, or methane that will be transformed into the organic products mentioned above. The active ingredient must be formulated as emulsion oil, powders, or granules. Energy for formulation is 20, 30, and 20 MJ/kg, respectively. Packing and distributing formulated biocide require additional energy, ranging from 3 to 8 MJ/kg, depending mainly on the distance: formulator to distribution. Application includes both direct energy for tractor’s diesel fuel and indirect energy used by the equipment (for example: sprayer) and the tractor during the time of application.

Biocide Management

In modern crop production it would be difficult to attain a high yields if weeds, pests, and disease were not controlled. The overall energy required in crop protection is lower than other inputs, although it is of great significance. Energy reduction is not the main factor here, because environmental and economic considerations are more important. To reduce the negative effects of weeds and parasites, different and complementary strategies, such as preventive, physical, cultural, biological, and chemical ones, must be considered [Barrett 1987].

Weed Control Strategies

Weeds compete with the crop plants for light, water, and nutrients. Weeds control in earlier stages of growth, or even before their emergence, is of prime importance. This will save money and energy, and reduce the environmental impact. For weed control, several methods must be considered.

a. Preventive Weed Control.
These practices permit farmers to avoid further problems of weed infestation. At the time of sowing, weed seeds must be separated from crop seeds by accurate cleaners. Although certified seed is more expensive than seed recovered from a previous crop or from another farm, the risk of infestation is greatly reduced with the former. Another important aspect is keeping field borders free of weeds.

b. PhysicalWeed Control.
Mechanical weed control is the oldest system used by growers. In primary cultivation, the moldboard plow is the most efficient implement for weed control. Weeds are completely buried within the soil, mainly in humid climate areas. Nevertheless, a high amount of energy is required for this type of deep tillage. On the other hand, soil layer inversion improves the conditions of weed seed germination when these seeds are located near the top of the soil. Chiseling and cultivating are less efficient in weed control than the moldboard plow because the weeds are only partially buried. To improve their control, V-sweep tools are mounted on the shanks and in many cases even a rod weeder is attached behind the implement. An interrow cultivator is efficient and easy to manage. Its energy consumption is low and allows for weed control for most of the growing season, depending of the crop type. Perennial weeds present serious problems when controlled by tillage, especially rhizomes. Some mechanical practices such as disking may disperse rhizomes within the soil. Another physical manner of weed control is burning them by propane combustion close to the crop plants. This system is expensive, requires a high amount of energy (150–200 kg/ha of propane) at the speed of only ~1 to 2 km/h, and weed control is low. Today this method does not seem appropriate for most of the crops.

c. Non-chemical (cultural) Weed Control.
Cultural practices can be classified into the following categories [
Regnier 1990]:

 - Competitive or allelopathic crops. Each crop differs in its competition with weeds according to its growth rate, spacing and the life cycle of seeds. For winter crops the activity of weeds is reduced comparatively with that of spring and summer crops. Even for the same type of seed (plant), the cultivars have a significant influence on the competitiveness against weeds.

- Allelopathic crop residues. Many mulch crops such as rye, wheat, oats, and barley contain allelochemicals, which deter weed germination.

- Intercropping. This management is often performed in the tropics. Two crops, such as soybean and corn, are cultivated interchangeably at some point during their growing.

d. Biological Weed Control.
A biological agent, normally a fungal, is released on a field to control annual weeds before weeds cause losses in crop yield. These agents are called mycoherbicides. Insects are also used as biological agents for weed control.

e. Chemical Weed Control.
Since the beginning of their use 50 years ago, chemicals are the most widely used products for weed control. Continuous research is being made, both to improve their effectiveness with new active ingredients and to develop safe application technologies. Nevertheless, environmental problems are arising as a consequence of inappropriate application of these chemicals. To reduce the quantity of active ingredients, it is necessary to act in earlier stages of weed growth. If application is delayed, the rate of herbicide could be increased 100% more in relation to the amount needed at the optimum time. To attain efficient weed control, the following aspects must be considered:

 - The best concentrations in water for a market product, range from 1% to 2% for conventional applications with sprayers.
- A flat nozzle is more accurate than a turbulence nozzle for herbicide application.
- The operating liquid pressure is generally 100 to 250 kPa.
- Travel speed must be maintained constant throughout the treatment.
- Nozzles, when operating at the same pressure, should be rejected when the flow rate per unit of time is 15% higher than the values specified by the manufacturer.
- Screen protectors against air drift allow an increase in the effectiveness of control (placement of herbicide within the desired area)..

Pest and Disease Control

As stated for weed control, pest and disease control practices follow similar trends for improvement. The term ‘integrated pest management’ is defined as “A strategy of pest containment that seeks to maximize the effectiveness of biological and cultural control factors, utilizing chemical controls only as needed and with a minimum of environmental disturbance.” This means that different strategies are involved with the objective of chemical usage reduction [Luna 1990].

a. Cultural Control.
Cultural control involves management systems in which the pest's life cycle is the primarily target. By conventional tillage, many insects are buried into the soil, breaking down their natural cycle. This can also be achieved by straw burning, but in this case, ecological disadvantages predominate over benefits. Crop rotation also allows some control of pests and diseases but its efficiency is limited for mobile insects and pathogenic spores; it is more accurate on rootworms and wireworms.

b. Biological Control.
Many species exert a natural control on insects, pathogens, and weeds. This creates trophic linkages that maintain the crop injury level below the economic threshold. Chemicals, in many cases, have a negative influence because they break down/destroy vital for many species ecosystems. For well executed biological control, knowledge of the different species and ecology is important.

c. Biotechnological Control.
In recent years, biotechnology has promoted the development of new resistance mechanisms in crops by genetic engineering. We are still in an early stage and more practical experiments are pending. Maybe in the near future this will be a powerful tool for pest and disease control.

d. Crop Propagation.

Agricultural crops can be propagated through seeds, bulbs, tubers, etc. The energy required for their production must be taken under consideration. For example, grain seed requires different energy rates, depending on whether it is produced on the farmer's own farm or purchased from a seed producer company. Values for energy costs for different seeds used in crop production are shown in Table:

e. Irrigation.

Water is essential, but unfortunately there are many areas where this element is limited. Increasing need to produce food to nourish the world population, forces people to plant and grow crops where hydraulic resources are at the far distance, hard to obtain or scarce. This objective requires infrastructures and energy for storing, pumping and transporting large amounts of water to agricultural farms. Energy assessment in irrigation systems depends on both the direct use (DE) and the indirect use (IE). The former includes the energy consumption to lift or pressurize (H) the overall rate of water required by crop considered per hectare.

Direct energy can be expressed by the following equation:

where

DE is direct-use energy (in joules per hectare),
is the water density (1000 kg/m3),
g is gravity (9.8 m/s2),
H is the total dynamic head, including friction losses (in meters),
Q overall rate of water, including losses by evaporation, run-off, etc. (m3 . ha-1),
is the pump efficiency, and

is the overall efficiency of the power device, electric or diesel.

Pump efficiency is a function of vertical height to lift (required pressure), rotation speed, and water flow. It ranges between 70% and 90%. Overall efficiency is considered for both electric- and fuel-powered devices; it ranges between 18% and 22%. For the electric motor, the generating plant, the transmission line, and the motor efficiency are included. Diesel efficiency is approximately 25% - 30%, but the energy to produce and transport fuel must also be considered [Ortiz-Canavate 1994]. Indirect energy includes raw materials, manufacturing, and transportation of the different elements. Estimation is based on the similar irrigation systems that have approximately the same expected functionality life time for particular type of crop. There are many irrigation systems, therefore it is difficult to establish the exact value for indirect energy. The following examples show relation between IE and dE: for the traveling sprinkler system IE equals about 18% of DE; for the surface irrigation systems with a run-off recovery , IE equals about 37% of DE [Fluck 1982].

Power Unit Efficiency in Pumps

In diesel engines, both torque and speed (rpm) have to be regulated to obtain the lowest specific fuel consumption. In most engines the speed is nearly 60%–75% of its maximum value and the torque is 75%–80% of its maximum. When the unit pump engine is selected, the optimum speed of the pump must be known in order to achieve the best transmission between pump and engine.

For electric-powered units, efficiency depends on the generating plant, for which thermal (coal) energy presents an average efficiency of 20%, nuclear 25%, and hydroelectric 50%. Losses in electric transmission lines are 15% and efficiency in converting electric to mechanical power can reach 90%.

Pumps’ Efficiency

Depending on the pump type and its performance, there are different efficiencies. In low- to medium-capacity centrifugal pumps, efficiency ranges from 50% to 80%. These are used by individual farmers. In high-volume propeller, mixed-flow, and turbine pumps, for which the discharge rate is higher than 500 m3/h, efficiency can be up to 90%. These kinds of pumps are normally operated to supply water to several farms.

Distribution of Water/Irrigation

Large amounts of water can be lost if infrastructures are not maintained in good condition. These losses are seepage, evaporation, and spillage. Efficiency ranges from 50% to 98%. The highest values are for drip irrigation.

Irrigation Systems

The irrigation gravity systems present the lowest efficiency, mainly because of leakages from water channels. Losses can reach up to 80%. For sprinkler stems, efficiency ranges from 50% to 80% (the lowest value refers to big gun equipment). The most efficient systems are drip and trickle irrigation, for which an efficiency of up to 90% can be obtained. These last systems allow farmers to incorporate nutrients into the water so its effectiveness is also improved.

f. Transportation.

Agriculture is basically a transportation industry. Energy is required for moving inputs to the farm from their point of origin, for moving labor, machinery, and products to and on the farm, and for moving farm products to market. Energy requirements in transport are normally expressed as energy intensity, meaning the energy needed per unit of weight and per unit of distance traveled (in MJ . t-1 . km-1). In agriculture, transportation is done mainly by trucks or tractors and trailers. In developed countries, approximately one half of the energy consumed in the food system goes to transportation, marketing, and household preparation. In general, extra energy required for transportation of agricultural commodities (even if the distance is several thousand kilometers), does not make local greenhouse production more economical [Fluck 1982].

Table lists the energy intensities for different transport modes that can be used to transport agricultural products.

Some measures to save energy in agricultural transportation could be:

 - The choice and the purchase of the most economical vehicles for the load to be carried and with the minimum fuel consumption.
 - Proper maintenance of trucks, tractors, and trailers.
 - Good driving habits.
 - Good planning to reduce trips.

Vehicle loading is an important factor for efficient energy use. Loading the vehicle up to its maximum capacity reduces energy intensiveness. This is also important in relation to energy saving in transport: the use of concentrated fertilizers and pesticides, the removal of moisture from commodities, and the processing of commodities on the farm to eliminate residues that do not have to be transported.

g. Labor.

Energy in labor is expended by agricultural workers when processes are being carried out. There are several methods to assess this input, which are based on different criteria. For primitive agricultural systems, the most accurate method is directly related to partial or total metabolic energy of the food consumed. In the mechanized agriculture of developed countries, the caloric energy of food is insufficient to be considered only.

Indirect energy involved in all the food industry processes should be considered/added. Both direct and indirect energy in this last case are higher than metabolic energy. Estimation for the muscular energy and energy sequestered in food, ranges from 1 to 93.2MJ/day, and the energy required for maintaining agricultural laborers’ activities: 510 - 1450 MJ/day.

h. Harvesting

Effective harvesting is a bigger energy saver. The efficient use of harvesting equipment is associated with the application of global position system (GPS) techniques and the timeliness of the operation. The global position system, or more accurately, the differential global position system (DGPS), uses satellite navigation with a fixed reference point located near where the machine operates. It can locate the machine in the field with a precision of a few centimeters. For cereal harvesting, the grain collected by the combine is registered by a continuous weight sensor, and consequently a yield map can be obtained. This map gives information for optimizing the inputs that have to be set next year: seed, fertilizer, and pesticide. In this way, much energy can be saved while maintaining the minimum cost in crop production. It is recommended that this method should be applied to any crop.

According to the ASAE [ASAE 1996], timeliness can be defined as the ability to perform an activity at such a time when quality and quantity of product are optimized. Energy productivity may be substantially increased by an improvement in timeliness. Yields are increased with better timeliness for different crop operations, including harvesting. Losses of timeliness can be calculated by

L(kg/ha) = KDY/Z = l Y (kg/ha)

where
K is defined as the timeliness coefficient (per day),
D is the number of days within the time span in which the operation should be accomplished,
Y is the yield per area (in kg . ha-1),
l is the coefficient of losses related to unity (adimensional), and
Z is a factor (adimensional) that is equal to 4 if the operation can be balanced evenly at approximately the optimum time and equal to 2 if the operation either commences or terminates at the optimum time.

Values of K have to be determined for each crop in a specific location. Table gives information about values of K in different places derived from crop research reports.

For example, if rice is harvested in California during D = 25 days starting at the optimum day (e.g., 20 September; therefore Z = 2), losses produced for the operation duration are

l = KD/Z = 0.009 x 25/2 = 0.113 = 11:3%

To adapt the size of machines to the amount of surface cultivated, early, medium, and late varieties of crops should be programmed in such a way that they can be planted and harvested, one after the other, at their optimum or the most near-optimum date to reduce timeliness losses.

 

Energy Balance

Let us consider as an example the sugar beet crop, which produces bioethanol (see Table).

Figure below shows the mass and the energy balance per hectare of sugar beet [Ortiz-Canavate 1994].

Considering ethanol as a main product, beet cuts as fodder for animals, and crowns and leaves for organic fertilizer as useful outputs, the balance will take a form

NEG = (115+40+13) - (32.9+15.2+ 80.7) = 168 - 128.8 = 39.2 GJ/ha

and ER = 168/128.8 = 1.3

If we consider ethanol as the main product, then productivity

EP = (5400 L/ha)/(128.8 GJ/ha) = 41.9 (L/GJ)

Therefore bioethanol derived from sugar beet can be considered as a possible biofuel source, taking into account that the energy balance of this crop is positive.

 

     

Economies of Bioenergetics

A variety of factors were found to contribute to the cost data will include both the capital and installation costs associated to the installation of actual capacity for generation, typically provided in $/W(capacity), and the production cost, which is the cost of producing electricity over the lifetime of a given project, typically provided in $/kWh. The main factors that affect these costs include:

- Feasibility Study Costs;
- Economies of Scale;
- Equipment/technology Options;
- Installation Requirements and Site Characteristics;
- Financing Terms;
- Cost of Land;
- Impact Assessment and Permitting;
- Project Renewable Resource Characteristics and Capacity Factors;
- Operating and Maintenance costs;
- Fuel Costs;
- Property Taxation and Land Lease Costs;
- Co-products and Co-benefits;
- Transmission and Grid Connection Costs; and
- Government Policy Factors

Factors that directly affect the cost of electricity are factors that have a direct impact on the capital cost of a project (and as such the installed capacity cost and generating cost of a project) or the factors that have a direct impact on the operating cost of a project (and consequently the generating cost only). Factors that indirectly affect the cost of renewable electricity are generally policy factors that lead to a reduction of the effective cost of various elements of a project. The particularly significant cost variation over time associated with some renewable electricity technologies was found to be the result of increased commercialization and maturity of markets for these technologies in recent years.

In principal, there are considered to be two generations of commercialized renewable electricity technologies if we consider technology development over the last 120 years. First generation technologies emerged from the industrial revolution at the end of the 19th century and include hydropower, biomass combustion and geothermal plants. Biomass combustion technologies generally use steam turbines to generate electricity. For smaller scale applications, internal combustion engines are used to generate electricity from biomass. Steam turbine and internal combustion engines are very mature. Hence, capital costs and electricity generating costs for these technologies have not changed significantly with reference to other conventional fossil fuel and nuclear based platforms over the years.

Therefore, unlike photovoltaics and wind turbines, the costs of biomass combustion are not on a steep technology-driven downward curve due to their technical maturity. Advanced biofuels are considered to be a part of the second generation renewable technologies. Second generation technologies are only recently starting to be broadly commercialized as a result of research, development and demonstration efforts which started in the late seventies. The initial investment in these technologies was prompted by energy security concerns linked to the oil price crises of that time period, but the continued focus on these technologies was mainly due to their potential environmental benefits. Innovations and ramp-up to commercialization for these two second generation technologies has led to a major decrease in associated installed capacity and generating costs over the past 3 decades.


Terminology

Before proceeding to the analysis of cost data for bioenergetics and the factors that influence them, several terminology clarifications are appropriate. These include the definition of capital costs, fixed costs, variable costs, installed capacity cost ICC and electricity generating cost EGC.

Capital Costs

Capital costs are costs incurred on the purchase of land and equipment and installation and construction services to be used to reach the point of producing goods, in this case renewable electricity. Capital cost also include feasibility studies, project design, permitting and legal costs incurred to reach the point of initial production. In other words, capital costs represent the total cost needed to bring a project to a commercially operable status.

Capital costs do not include labor costs except for the labor used for feasibility analysis, project design and construction. Typically, capital costs are one-time expenses, although payment may be spread out over many years depending on financing arrangements. Capital costs are generally fixed for a given unit of installed electricity generating capacity (i.e., they don’t change over the lifetime of the project), although they do vary from project to project based on equipment configurations and project site specifics. Capital costs also do not vary depending on the actual level of electricity output occurring from a project.

Operating and Maintenance Costs

Operating costs are the recurring expenses which are related to the operation of a business. It is the amount of resources used or cost incurred by an organization just to maintain existence. These costs include overhead costs, which can include the payment of rent on the office space a business occupies or lease for land on which a generating plant is sited, administrative employee wages, insurance costs, financing costs such as interest or other financing charges, taxes, equipment depreciation etc. They also include non-overhead costs like supplies, such as biomass feedstocks used to create the electricity, and in some cases employee wages.

Operating costs generally fall into two broad categories:

- Fixed costs, which are the same whether the operation is closed, or running at 100% of capacity. Fixed costs are expenses whose total does not change in proportion to the activity of a business, within the relevant time period or scale of production. Fixed costs include, but are not limited to, overheads (rent, insurance, and such) and can include direct costs such as payroll (particularly salaries).

- Variable costs, which may increase depending on whether more production is done, and how it is done. For electricity projects, the most significant variable cost is typically the cost of fuel.

Because bioenergetic projects also entail the use of devices, components and pieces of equipment to make up overall generating facilities, maintenance costs must also be considered. Maintenance costs are incurred to keep equipment operating at an optimal level of performance. These costs included those associated with routine recurring work required to keep a facility (plant, building, structure, utility system, or other real property) in such condition that it may be continuously used, at its original or designed capacity and efficiency for its intended purpose. These costs also include the corresponding administrative, managerial, and supervision costs associated with this work. In the most simple production function, total operating and maintenance cost is equal to fixed costs plus variable costs plus maintenance costs

Installed Capacity Cost ICC

The installed capacity cost for a energy project is typically represented as dollars per unit of installed power generating capacity ($/W). This cost is calculated by totaling all capital costs incurred to bring the project to the point of production and dividing this total by the total installed rated capacity of energy generating equipment. The capital costs usually includes the following:

- Project feasibility studies;
- Engineering design;
- Impact assessment and permitting;
- Equipment procurement of fabrication;
- Site preparation (including site services and access roads);
- Plant construction and installation;
- Grid connection;
- Project management; and
- Commissioning and start-up

Energy Generating Cost EGC

Each technology used to produce electricity has specific characteristics which can vary significantly from one to another. Among these characteristics: equipment cost, construction time, electrical output, lifetime and operation and maintenance requirements. Due to these differences it is very difficult to perform a comparison between different technologies by only considering one of those characteristics. Furthermore, comparison of installed capacity costs alone can be misleading as some technologies have high initial capital costs but require very little operating and maintenance expenditures over their lifetime while other technologies demonstrate the reverse phenomenon. Fossil fuel plants, for example, have some of the lowest up-front capital costs but incur significant maintenance and fuel costs for the entire life of the plant. Conversely, photovoltaic projects entail high up-front capital costs but require minimal additional expenditures over their lifetime due to almost negligible operating and maintenance requirements. In order to provide a better overall lifecycle comparison between technologies, the electricity generating cost is a more representative figure.

Levelized Cost of Power LCP

The electricity generating cost for a given project is frequently referred to as the levelized cost of power production. It is typically presented in dollars per unit of electricity produced ($/kWh). The levelized cost of power production is the average cost of power production over the life of a power plant, taking into account all capital expenses and operating and maintenance costs. It is determined by dividing the total life-cycle costs, usually in present dollar values, by the estimated amount of electricity, in kWh, the project will produce over its operating life.

Feasibility Study Cost Variability

Although feasibility studies typically do not represent a major cost relative to other capital costs associated with renewable electricity projects, they can be significant in some instances. Feasibility study requirements, and consequently cost for such studies, vary greatly from technology to technology. They can also vary significantly between different projects using the same technology. For renewable electricity projects, a significant factor affecting the cost feasibility studies is the existence and quality renewable resource data for a proposed project site. Where no data exists or where data is of limited quality for a particular site, data must be collected and analyzed to the point of establishing the viability of developing an actual electricity generation project. The cost of acquiring reliable data depends on the renewable energy resource and the technology being used to harness it. Requirements for feasibility studies are typically fairly consistent from one biomass power project to another. Furthermore, these costs are low compared to equipment and construction costs.

Capacity/Economies of Scale

All renewable electricity technologies benefit from economies of scale in various ways. Generally, the larger the installation the more power generation capacity there is to amortize the various capital costs over. This means that these costs can be more rapidly recouped with a larger capacity project, and consequently yield a lower lifecycle cost for electricity generation ($/kWh) and a lower installed capacity cost ($/kW). Furthermore, any project that has financial transaction costs can recoup these costs faster if they are spread over more kilowatt-hours with a larger project. This can also hold true with operating and maintenance costs. A larger project will almost always have smaller operations and maintenance costs per kilowatt-hour because of various cost efficiencies than can be leveraged, such as management, maintenance equipment, monitoring etc.  Significant economies of scale exist for purchase of larger steam turbines or combustion engines, so impacts on capacity costs can be significant. Impact on electricity generation cost is lower because actual power production will depend more heavily on the cost of biomass feedstocks over the lifetime of the biomass power project.

Plant Availability

Plant availability, along with the quality of the renewable resource dictate how much of the installed capacity of a plant can actually be used and consequently how much electricity can be produced from a plant assuming a constant supply of fuel. The higher the availability of generating equipment, the more power can be produced. The more power produced, the greater the potential revenues, or displacement of cost of electricity from other sources, and the more rapidly capital and operating and maintenance costs can be repaid.

Depending on the nature of the biomass feedstock for a given electricity project, equipment costs can vary significantly. For example some feedstocks may require chipping, pelletizing, drying or long term storage for their effective use in combustion equipment. Equipment for each of these activities represents a cost that may not exist in other biomass electricity projects. Furthermore, where a suitable heat load exists at a project site, an additional cost can be incurred to install heat capture and transfer equipment, the cost of which may not always be completely offset by displaced heating fuel costs. In addition to equipment cost variations, characteristics of a renewable resource can affect technology choices which also have an impact on the project capital cost per unit of installed power capacity. For biomass projects these technology variations can be significant.

The great variability of bioenergy resources combined with the broad range of technical approaches to harnessing bioenergy contributes to a great variation in biomass electricity generating costs. Process routes for converting biomass into electricity include direct combustion, gasification, anaerobic digestion and pyrolysis. Direct combustion generally is a well established and relatively low cost technology that involves burning biomass directly to produce heat to produce steam to drive a turbine for electricity generation. Initial costs of a direct wood biomass energy system are generally 50% greater than that of a fossil fuel system, but this is mainly due to more complex fuel handling and storage system requirements. Generally, the higher the plant availability, the higher the cost. Although a cost premium may be justified over the lifetime of a project, it can lead to a higher installed capacity cost. Equipment costs on an installed capacity basis can vary significantly from one biomass conversion technology to another.

Anaerobic digestion involves decomposition of waste streams such as manure or municipal solid waste in the absence of oxygen to produce a combustible gas similar to natural gas which can be used to drive an a turbine or internal combustion engine generator. Although the actual generating technologies used in such systems are well established and have relatively low costs, manure handling and digesting equipment can add a significant cost which can be offset by economies of scale in larger projects.

Pyrolysis is a thermo-chemical process used to convert solid biomass to liquid and solid fuels that can be more easily stored, transported and burned than solid wood wastes. Although not yet fully commercialized, these systems are used to convert biomass streams in remote location or in locations where electricity is not required to fuels that can be easily transported to sites where electricity generation can be done using conventional turbine technology modified to use pyrolysis product fuels in more commercially viable environments. Little cost data is available on pyrolysis systems to date but they are only expected to be competitive in applications where feedstock are free or have a negative value due to disposal liabilities.

Finally, gasification technologies convert forestry, agricultural and municipal residues into syngas (similar to natural gas, but lower in energy content), which once cleaned and conditioned, can be burned in gas turbines and gas-powered engines to produce electricity. Although more expensive than direct combustion of biomass, these systems can improve emissions performance. Each of these biomass technologies represents different capital and operating and maintenance costs, but can be the only economically competitive option depending on the biomass resource and project location.

Cost of Land

Where land is not leased, the cost of purchasing land on which electricity generating facilities will be sited can vary drastically depending on the region and several other factors. Land costs can vary according to perceived value, which generally depends on proximity to urban centers, accessibility, esthetic value, ownership or perceived value of natural resources on land. The land cost circumstances for every renewable electricity project can therefore vary significantly. This can vary drastically from one jurisdiction to another. However, land is typically only a minor cost relative to other capital costs.

Construction and Location/Installation Variables

Specific construction and installation requirements, and related capital costs can vary significantly from one renewable electricity project to another, even within applications of the same technology. Accessibility can be a major factor affecting construction and installations costs for a project. Generally, the more remote and difficult to access the project site, the higher the installation costs. Although some potential sites may be accessible by existing roads, in many cases land has to be cleared and access roads have to be specifically constructed for the purpose of reaching a development site and erecting a facility.

Construction of access roads can be costly especially since they must be able to withstand significant heavy equipment transit and hauling of large volumes of construction material, such as concrete for foundations, mobile crane equipment, steel piping, drillers, turbines, etc. The cost of roads depends on soil conditions, land cover and a variety of other factors. Furthermore, the longer the access road required, the costlier it becomes. In some cases, land leases or access fees must be paid for some parts of access roads if they cross property not owned by the project developer. Overall travel distances to sites from regions of source labour and materials can also differ substantially from project to project.

Distance to power transmission infrastructure capable of handling project power outputs and power conditioning requirements can also vary significantly from project to project. Where projects are especially remote, distance to existing transmission infrastructure and the costs associated to installing connection lines can be enough on its own to make a project uneconomic. In many cases, easement rights for lines crossing non-owned land can require an additional cost outlay. Furthermore, depending on the output voltage of a power facility, a transformer may be necessary to convert the low voltage current to 10-30 kV current suitable for most local electrical grids. The cost of such equipment can vary significantly with size and suitability to local conditions.

Materials requirements can also differ from site to site. Regional construction labour and civil and electromechanical engineering costs can also vary significantly from jurisdiction to jurisdiction. Furthermore, construction time requirements, and consequently overall labour costs, can also differ drastically from one site or jurisdiction to another. Because exact siting of a biomass power installation is less critical than for wind, hydro and geothermal projects, location related construction and installation cost variability is generally less important for this technology.

Equipment Lifetime and Decommissioning Requirements

Equipment lifetimes and retrofit/replacement schedules partially define the total amount of electricity that can be produced from a project. Equipment from different vendors can have different warranty periods, and consequently different expected lifetimes. Furthermore, different technologies have different lifetimes. Biomass electricity system turbines and wind turbines typically have shorter expected lifetimes due to their substantial moving parts and the consequent inevitable wear and breakdown of turbine components. Decommissioning and disposal costs can also vary from technology to technology. Equipment lifetime and decommissioning requirements are expected to be fairly consistent from one manufacture to another and from one technology to another. Therefore this is expected to be only a low variability factor for installed capacity and generating costs.

Impact Assessment and Permitting

Different technologies have different environmental impact assessment and permitting requirements. These costs vary widely and often include significant fees for lawyers, public affairs/lobbyists, and engineers involved in the effort to gain community approval. Environmental assessment of fish habitat impacts for small hydropower projects, air emissions impacts for biomass electricity projects and landscape visual pollution for geothermal projects are required and represent varying costs depending on the project location. Where these projects are close to populated areas, community opposition can come into play. Impact assessment and permitting requirements are expected to be fairly consistent from one jurisdiction to another and from one technology to another. Some slight variability can be expected based on the scale of the installation and the nature of the biomass stream to be used as project fuel. However, the cost associated to these activities are low relative to the overall equipment and construction costs for biomass power installation


Factors that Have a Direct Impact on Net Cost of Generating Electricity

Generally, there are numerous factors that dictate the levelized cost of electricity from renewables, all of which can vary significantly from one project to another. The following provides a summary of the factors that affect the cost of renewable electricity by affecting operating and maintenance costs.

Quality of Renewable Energy Resource and Capacity Factors

For all electricity generating technologies, the availability of fuel is essential to produce electricity. With renewable technologies the quality and characteristics of the renewable energy resource at or close to project site define the amount of fuel available for electricity generation on an annual basis and when it can be used. The amount of fuel available has a huge impact on the net cost of generating electricity for all technologies, but the added factor of when or how often the fuel is available can have a particularly significant impact on costs for some renewable technologies as well.

Actual costs per kWh for renewables depend on the number of kWh of electricity actually produced. The capacity factor of a power plant is the ratio of the actual output of a power plant over a period of time and its output if it had operated at full capacity over that time period. This is calculated by totaling the electricity the plant produced and dividing it by how much electricity it would have produced at full capacity. This is a particularly important issue when considering photovoltaics, wind power and some small-scale hydropower projects. In these cases, the plant may be available to produce electricity, but its fuel, wind, sunlight or water, may not be available or enough of the fuel may not be available to allow the plant to operate at full capacity.

Geothermal and biomass generation projects generally deal with resources that are continuously available, assuming a project is appropriately designed, and hence have capacity factors approaching 100%. As long as a viable fuel source is available, such projects will only be limited by the capacity and availability factors their power equipment is rated for and will generally not be affected by temporal factors. That being said, for geothermal projects, the heat content of a geothermal reservoir will gradually decrease/decline over time, but this should be minimized for the planned life of the project if an appropriate water re-injection strategy is employed. Similarly, if a steady stream of biomass feedstock is not secured from the duration of a biomass generation project, the capacity factor issue may come into play, if production rate is reduced or interrupted. Consistency of availability of biomass fuel can have a significant impact on the cost of biomass power generation.

Operations and Maintenance

Aside from the requirement to replace some of the supporting power conditioning components over their lifetime, operating and maintenance costs are essentially can result from special attention and extra maintenance requirements. Operations and maintenance costs are generally fairly consistent from one jurisdiction to another. Some relative cost variability can occur based on scale of the biomass power installation.

Fuel Costs

For biomass projects, the cost of fuel defines economic competitiveness. Factors affecting biomass fuel costs, such as transportation distance and harvesting, preparation and storage requirements, can have drastic variability impacts on generating costs. Cost for biomass feedstocks can range from free, or even negative values in cases that involve waste streams with high disposal costs, to significantly higher when feedstocks must be grown, harvested, processed or transported to end-use sites. Types of biomass feedstock used for electricity generation include:

- Agricultural residues which are generated after each harvesting cycle of commodity crops. A portion of the remaining stalks and biomass material left on the ground can be collected and used for electricity generation purposes. Wheat straw and corn stover generally make up the majority of available crop residues.

- Energy crops are produced solely or primarily for use as feedstocks in electricity generation processes. Energy crops includes hybrid poplar, hybrid willow, and switchgrass, which are typically grown on idled or in pasture lands.

- Forestry residues are the biomass material remaining in forests that have been harvested for timber. Timber harvesting operations do not extract all biomass material, because only timber of certain quality is usable for processing into end products by facilities. Therefore, the residual material after a timber harvest is potentially available for electricity generation purposes. Forestry residues are composed of logging residues, rough rotten salvageable dead wood, and excess small pole trees.

- Urban wood waste/mill residues are waste woods from manufacturing operations that would otherwise be landfilled. The urban wood waste/mill residue category includes primary mill residues and urban wood such as pallets, construction waste, and demolition debris, which are not otherwise used. These streams can be particularly economical since they generally exist close to urban centers with established transmission infrastructure and represent a negative disposal cost.

- Landfill gas is produced from organic waste disposed of in landfills. The waste is covered and compressed mechanically and by the pressure of higher levels. As conditions become anaerobic the organic waste is broken down and landfill gas is produced. This gas builds up and can be used to drive an electric turbine.

- Agricultural manure and biological solids are streams of biomass that can be converted into biogas which can in turn be used to drive a steam turbine or an internal combustion engine to produce electricity. Manure can be collected from dairy farms, feedlots, pig farms and poultry farms. Waste biological solids are produced at waste water treatment facilities and food processing plants. Conversion of these wastes into combustible biogas occurs in anaerobic digesters, which present several key advantages beyond production of electricity including a reduction of waste volume, destruction of parasites and harmful organisms, and creation of high value fertilizer streams.

The characteristics and economics of harnessing each of these feedstock streams for power generation vary significantly, not only from stream to stream, but also from project to project. The cost of each fuel is defined by production, collection/harvesting, processing, transportation, storage, and in some cases, fuel handling requirements. Production costs can be especially high when dealing with dedicated energy crops and can vary drastically from one project to another. Variations stem from differences in the cost of agricultural land, soil conditions and climate and annual crop yields. Processing costs can also vary depending on the biomass stream. For example forestry residues may require chipping to be usable in combustion equipment and manure and biosolids require anaerobic digesters for production of biogas.

Where biomass feedstocks are by-products of other processes, such as forestry residues, manure and biosolids streams, crop residues and landfill gas, project economics can be significantly improved as long as electricity generation projects can be sited close to these streams and still have easy grid access. If not sited close enough, transportation costs alone can render projects uneconomical. Energy density of fuels can also affect the net transportation cost per delivered kWh of electricity. The amount of biomass available within a practical transporting distance generally determines the viable size of a biomass electricity generating project. The following figures can provide some context of the costs associated with some biomass streams.

- For forestry-produced biomass, the cost can range from US$0.5 to 3 per million Btu, with economically successful projects paying less than $1.5 per million Btu

- Urban wood waste and mill residues are often available at $1 per million Btu or less. However, the cost of collecting urban wood waste and mill residues can range from $0-8 per wet ton for mill residues and from $10-14 per ton for urban residues.

- Burnable municipal solid waste (MSW) is usually landfilled for a fee. Thus, it has a negative fuel price. However, plant operators must process MSW to eliminate toxics and generally need to install emissions control equipment, both of which can drive up costs of power generation.

- Studies have shown that transporting giant round bales of switchgrass costs $4.50 to $13.5 per dry tonne ($0.29 to $0.87 per million Btu) for distances of less than 50 miles

- Costs of landfill gas are less variable: these plants can typically produce electricity at 6 to 8 cents per kWh. Larger landfills are often required to install gas recovery systems - making the marginal cost of the energy recovery system the appropriate consideration for determining electricity production costs. Costs of energy recovery systems alone are typically about 5 cents per kWh.

Electricity Generating Costs and Installed Capacity Costs for Biomass Electricity Facilities

Source Capacity Cost (US$/kWh)* Capacity Cost (US$/kW)*
USDA Forest Products Laboratory 0.06 – 0.11 2,000
Lahmeyer International 0.051 – 0.083 1,300 – 1,800
International Energy Agency 0.035 – 0.155  
Energy Information Administration 0.035 – 0.12 1300 - 1550

Transmission Costs

Transmission and market access constraints can significantly affect the cost of renewable electricity, especially with intermittent technologies such as wind and solar. Significant connections fees and annual transmission fees are required for photovotaic projects in many jurisdictions, regardless of the size of the system. Wind can be especially challenging because of its inherent unpredictability. Deviations from schedule can be penalized in certain jurisdictions without regard to whether they increase or decrease system costs. Furthermore, interconnection procedures are not standardized, and utilities have on occasion imposed such difficult and burdensome requirement on wind plants for connection to transmission lines that wind companies have chosen to build their own lines instead. These issues can contribute to significant variations in the cost of wind electricity from one project to another or one jurisdiction to another. Such issues are less significant with hydropower, geothermal and biomass projects because they can provide baseload power and are typically fairly large scale. Because biomass power projects are typically large scale, transmission related costs are typically small relative to other operating costs. As such, variation in these costs have minimal variability impacts on overall generating cost.

Financing Costs

Financing terms are a critical factor for all renewable electricity generation technologies. Different project developer categories will have access to different finance options, which translates to different financing costs. For example, a typical 50 MW wind farm that could deliver power at 5 cents/kWh, if financed by a wind developer through financial institutions, could generate electricity at 3.5 cents/kWh if the wind developer had access to the financing terms available to investor-owned utilities when they own wind projects . The main reason for this is that utility project developers have access to lower interest financing through access to funds from bond-style investments from investors.

When financing projects through financial institutions or private investors, interest rates are significantly higher. Utilities usually have access to financing at interest rates of roughly 7.5% compared to 9.5% for a developer and longer debt payment periods (20 years compared to 12 for developers). Utilities also don’t have a debt service coverage ratio (DSCR) requirement. The DSCR is a mechanism by which a lender reduces risk of default on a loan be requiring that a wind project generate enough cash each year to exceed loan repayments. Typically, this results in a smaller loan than would be most advantageous to the developer. Financing costs can be especially high for small photovoltaic installations.

In order to offset the higher interest rates that are usually required for renewable projects compared to traditional gas or other utility generation projects, several economic instruments can be employed. These include low-cost government loans, loan guarantee programs, and interest-rate buy-downs. Financing costs for biomass power projects are expected to only vary slightly from one jurisdiction to another.

Co-products and Co-benefits

Because biomass generation produces electricity by combustion, the possibility exists to use heat (or steam) not captured by the generator for process or space heating applications. This is commonly referred to as co-generation or combined heat and power (CHP). The key economic driver for developing a CHP project is the presence of a heat load onsite or within a close distance to the biomass generation project. If heat can be produced at a cost that is competitive with heating alternatives, typically from fossil fuel, and a steady heat requirement exists, a net cost saving, or profit from the sale of heat, can be credited to the project and serve to offset the cost of electricity production. The magnitude of the cost saving differs from project to project, from negligible to significant depending on how much heat can be economically used and the cost of fuel being displaced by the CHP system.

Other renewables generally do not have co-product opportunities, although some co-benefits may exist. For example, emission credits from displaced greenhouse gas or criteria air contaminant emissions reductions can translate to an increased value for renewable electricity projects that can offset costs and accelerate investment payback periods. Emission credit opportunities vary significantly from jurisdiction to jurisdiction, as does the value for these credits. Hydropower can provide further co-benefits such as facilitating irrigation, providing flood control, providing water supply and facilitating navigation. The cost impacts of such co-benefits are, however, difficult to quantify. The presence of a market for co-product heat from biomass power installations can have a significant impact in terms of creating a new revenue stream or offsetting operating costs.

Land Leases and Property Taxes

As with the cost of purchasing land, land leases can vary drastically from one jurisdiction to another. Lease rates vary with the perceived value for land. This value typically varies with proximity to urban centers, accessibility, esthetic value, ownership and perceived value of natural resources on land. The circumstances for every renewable electricity project can therefore vary significantly. As an example, land lease costs for small hydropower projects have been known to range from roughly $1,500 per MW of capacity to alleged offers as high as $15,000 per MW. Some are fixed payments and some vary with the amount of electricity produced.

Rates of taxation of renewable electricity projects also vary drastically from one jurisdiction to another, most notably at the municipal level. In Canada for example, municipalities in all provinces levy property taxes to raise additional revenues to cover the cost of local government services, with the intent to allocate these costs across all taxpayers, based on wealth as measured by the assessed value of property owned. There are two fundamental activities related to property taxes – assessment and taxation. Property assessment is simply the process of assigning a dollar value to a property for taxation purposes. This value is then used to calculate the amount of taxes that will be charged to the owner of a property. Taxation is the process of applying a local tax rate to a property’s assessed value to determine the taxes payable by the owner of a property.

Value attributed to renewable electricity projects differs from province to province and tax rates are different for every municipality. This means that renewable power projects are taxed differently in every municipality. This can be illustrated by the fact that the annual municipal rate of taxation for a 20 MW wind farm in Canada can range from almost US$ 400,000 in certain parts of Alberta to just US$ 50,000 in certain parts of Ontario. Land lease and property tax expenses are expected to be small relative to overall biomass power operating costs. As such, relative variability in these expenses from jurisdiction to jurisdiction will only slightly contribute to overall variability of biomass power generating costs.


Factors that Have an Indirect Impact the Cost of Electricity

Factors that have an indirect impact on the cost of renewable electricity mainly refer to the various government policies and economic instruments available for off-setting the increased cost of renewable electricity generation. These policies and economic instruments include: capital grants, consumer grants and rebates, corporate tax incentives, production tax credits, property tax incentives, sales tax rebates, third party finance and low interest loans, emission reduction credits and research and development incentives. These factors are seen as indirect because they do not immediately impact the initial capital outlay or reduce operating expenses and are generally not included in cost analysis data developed by groups such as the Energy Information Agency or public utilities. They do, however, allow a project developer to recoup a portion of these costs after they are incurred through rebates or tax incentives. These recouped costs can have several after investment impacts of the economics of a project, which include:

- Reduced taxation and increased net profit
- Increased revenues
- Reduced debt financing requirements
- Accelerated repayment of debt and reduced financing charges

All of these impacts translate to reduced investment payback periods, and over the lifetime of the project, reduced levelized electricity generating costs.

Capital Grants

With capital grants, a percentage of the investment cost in renewable electricity technology and equipment purchase and installation is covered by government-financed schemes directed towards commercial electricity suppliers. In North America, several states and provinces in the United States and Canada offer a variety of grant programs to encourage the use and development of renewable electricity technologies. Most programs offer support for a broad range of renewable electricity technologies, while some focus on promoting one particular type of renewable electricity such as wind technology or photovoltaics. These grants are typically primarily available to the commercial, industrial, utility, education, and government sectors. Programs vary in the amount offered--from $500 to $1,000,000 and some do not set any limits. Capital grants can help reduce initial capital investment for biomass power projects. However, due to the relatively small size of grants typically available for generally large biomass power developments, the impacts of grants are low over the lifetime of a project.

Consumer Grants/Rebates

Similar to capital grants, consumer grants and rebates allow for a percentage of the investment costs in renewable electricity equipment purchase and installation to be covered by government-financed schemes directed towards end-users of electricity (residents and businesses). Such programs are offered both at the state level and also at the local municipal level or directly from utility providers and are usually targeted at small scale installations of photovoltaics and in some cases small wind turbines. Due to the industrial scale of typical biomass power installations, consumer grants and rebates are not relevant.

Corporate Tax Incentives

Tax Credits

Corporate tax incentives allow corporations to receive credits or deductions ranging from 10% to 35% against the cost of renewable electricity project planning, equipment or installation to promote their increased use. In some cases, the incentive decreases over time. These tax credits exists in both the US and Canada. In most cases, there is no maximum limit imposed on the amount of the deductible or credit. Increased depreciation rates for biomass power equipment can greatly reduce the tax burden on biomass projects in the first years of their existence and allow for more rapid payback periods for initial investment and earlier debt retirement. Renewable project planning expense clauses in tax codes can also contribute to significantly lowered taxation. Consequently power production costs can vary drastically between regions with and without corporate tax incentives.

In Canada, the Canadian Renewable and Conservation Expense (CRCE) category of expenditure is intended to promote the development of conservation and renewable energy projects in the same way that is currently done for investments in other types of resource activities. Under CRCE, eligible expenditures are 100% deductible in the year they are incurred or can be carried forward indefinitely for deduction in later years. These credits can also be transferred to investors using flow-through shares. Eligible expenses typically include engineering and design, site clearing, feasibility studies, contract negotiations and regulatory approvals. For the wind industry, CRCE also includes the capital cost of "test wind turbines," which can constitute up to 20 per cent of the generating capacity in a wind farm.

In the US, the permanent extension of the standard investment credit (Section 1916), provides a 10% investment credit for most solar and geothermal technologies. In addition, the Energy Tax Act is a program of tax credits for households and businesses that purchase renewable energy equipment. Through this program, residential energy income tax credits for solar and wind energy equipment expenditures were set at 30% of the first $2 000 invested and 20% of the next $8 000.

The most important electricity sector incentive available in the US is 10% business energy tax credit for investments in various renewable energy technologies including solar, wind, and geothermal. This credit is in addition to the standard 10% investment tax credit previously mentioned. Public utility property was specifically excluded from eligibility for the tax credits that were to expire at the end of 1982.

Special Depreciation Rules

Shortened or “accelerated” depreciation tax rules exist in all three North American Countries. In Canada, the federal Income Tax Act provides an accelerated capital cost allowance (30% capital cost allowance rate computed on a declining balance basis) for certain types of renewable energy equipment used to generate electricity or to produce thermal energy for direct use in an industrial process. A range of renewable energy conversion and energy efficiency equipment are eligible for inclusion, such as certain co-generation systems, small-scale hydropower installations, wind energy conversion equipment, certain photovoltaic and active solar heating equipment, and equipment used in certain landfill gas applications.

In the US, a five-year accelerated depreciation for renewable energy property (from a 150% to 200% declining balance method) is available. This accelerated depreciation applies to "small power production facilities", which includes facilities that produce electricity at a capacity of 80 megawatts or less. Public utility property is also eligible for the accelerated depreciation.

In Mexico, investments in environmentally friendly technology, including renewable energy technology can benefit from accelerated depreciation. Under the guidelines of this accelerate depreciation program, investors are thus allowed to deduct 100% of the investment after one year of operation, as long as the equipment operates for at least five years following the tax deduction declaration.

Production Tax Credits

In Canada and the US, private entities generating electricity from renewables that are normally subject to taxation are eligible for a federal production tax credit for the electricity they produce. Production tax credits are normally set as a price per kWh ($/kWh). Basing payments on performance rather than capital investments is seen as a more effective mechanism for ensuring quality projects are developed. Production tax credits help to offset the cost premium associated to biomass power production compared to traditional sources of electricity. As with other tax incentives, production tax credits can lead to more rapid payback periods and offset overall operating costs. Consequently net power production costs can vary significantly between regions with and without production tax credits.

In Canada, the Wind Power Production Incentive (WPPI) was designed to provide financial support for the installation of 1,000 megawatts of new capacity between April 2002 and March 2007. The incentive was intended to cover approximately half of the current cost of the premium for wind electricity in Canada compared to conventional sources. As of June 2006 almost 1000 MW had been supported by WPPI, signifying that the majority of financial resources designated to the program had been deployed to projects.

As the program’s success became evident and the targets began to appear in reach, interest groups began pressuring the federal government to extend WPPI. Consequently, Budget 2005 provided $200 million over 5 years and a total of $920 million over 15 years to expand the Wind Power Production Incentive target to 4,000 MW. Under the new tranche of the incentive and as with the original terms of the program, an incentive payment of 1 cent per kilowatt-hour of production for the first 10 years of operation would be made to eligible projects commissioned before April 1, 2010. The eligible production per project would be determined by Natural Resources Canada.

In addition to WPPI, in Budget 2005, the federal government announced a Renewable Power Production Incentive (RPPI) to stimulate the installation of up to 1,500 MW of new renewable electricity generating capacity, other than wind (small hydro, biomass and geothermal). RPPI’s application to solar energy was never fully formalized. Similarly to WPPI, an incentive payment of 1 cent per kWh of production would be awarded for the first 10 years of operation of eligible renewable energy projects commissioned after March 31, 2006 and before April 1, 2011. Budget 2005 provided $97 million over five years and a total of $886 million over 15 years for the RPPI.

Both the RPPI and WPPI programs were suspended until further evaluation in early 2006. On January 19th, 2007, a replacement program, entitled the ecoENERGY for Renewable Power program and similar to the original programs, was announced by the federal government that essentially combined both the RPPI and WPPI programs into a smaller funding envelope.

In the US, the Renewable Electricity Production Credit (REPC), also commonly referred to as the Production Tax Credit (PCT), is a per kilowatt-hour ($/kWh) tax credit for electricity generated by qualified energy resources. Enacted as part of the Energy Policy Act of 1992, the credit expired at the end of 2001, and was subsequently extended in March 2002 as part of the Job Creation and Worker Assistance Act of 2002. The tax credit then expired again at the end of 2003 and was not renewed until October 4, 2004, when it was extended through to December 31, 2005. Subsequently, the Energy Policy Act of 2005 modified the credit and extended it through to December 31, 2007. Finally, in December 2006, the credit was extended for yet another year, through to December 31, 2008.

Eligible electricity generation technologies under the REPC presently include geothermal energy, biomass energy facilities, including open-loop biomass systems (facilities that use agricultural livestock waste nutrients), small irrigation power, landfill gas, municipal solid waste combustion and wind energy. The Energy Policy Act of 2005 (EPAct 2005) further expanded the credit to certain hydropower facilities, but removed solar facilities from the list of eligible projects.

The original REPC provided a tax credit of 1.5 cents/kWh, adjusted annually for inflation, for wind, closed-loop biomass and geothermal. The inflation adjusted credit amount for projects in 2007 is roughly 2 cents/kWh. Electricity from open-loop biomass, small irrigation hydroelectric, landfill gas, municipal solid waste resources, and hydropower currently receive 1.0 cent/kWh. The duration of the credit is generally 10 years. However, open-loop biomass, geothermal, small irrigation hydro, landfill gas, and municipal solid waste combustion facilities placed into service after are eligible for the credit for only a five-year period.

Property Tax Exemptions

The majority of the property tax provisions for renewable energy follow a simple model that provides the added value of the renewable device is not included in the valuation of the property for taxation purposes. Property taxes are collected locally, so some states allow the local authorities the option of providing a property tax incentive for renewable energy devices. In the US, six states have such provisions: Connecticut, Iowa, Maryland, New Hampshire, Vermont, and Virginia. Property tax incentives can also take the form of exemptions to owners from paying all or a portion of their taxes on properties using renewable energies, therefore reducing their tax payments. This is, however, less common

Sales Tax Rebates

Sales tax incentives typically provide an exemption from the state or provincial sales tax for the cost of renewable energy equipment. Several provinces and states in North America have enacted such measures, mainly for solar technologies.

Personal Income Tax Incentives

Many states offer personal income tax credits or deductions to cover the expense of purchasing and installing renewable energy equipment. Some states offer personal income tax credits up to a certain percentage or predetermined dollar amount for the cost or installation or renewable energy equipment. Allowable credit may be limited to a certain number of years following the purchase or installation or renewable energy equipment. Eligible technologies may include photovoltaic energy systems, geothermal energy, wind energy, biomass, hydroelectric, and alternative fuel technologies.

Loan Programs and Third Party Finance

Loan programs offer financing for the purchase of renewable energy equipment. Low-interest or no-interest loans for energy efficiency are a very common strategy for demand-side management by utilities. However several state governments also offer loans to assist in the purchase of renewable energy equipment. A broad range of renewable energy technologies are eligible. In many states, loans are available to residential, commercial, industrial, transportation, public, and nonprofit sectors. Repayment schedules vary; while most are determined on an individual project basis, some offer a 7-10 year loan term.

As an example in the US, the Oregon Department of Energy makes low-interest loans for projects that produce electricity from renewable resources, that conserve energy resources or that use recycled materials to create products. The Small Scale Energy Loan Program (SELP) is a self-supporting loan program funded by the sale of Oregon general obligation bonds. Borrowers can use loan funds to pay most direct energy project costs and related project costs such as engineering and design, permit fees, loan fees and project management costs. Most Oregonians, Oregon businesses, non-profit organizations, state agencies, schools, cities, counties, special districts, state public corporations and federal agencies are eligible.

In Canada for example, the government established two complementary funds to stimulate investment in innovative municipal infrastructure projects and environmental practices, including renewable electricity development, for Canadian municipal governments and their public and private sector partners. The government is essentially providing CAN$ 250 million to encourage projects and studies in communities. These funds include the Green Municipal Investment Fund (GMIF) which has a total budget of CAN$ 200 million. GMIF supports the implementation of innovative environmental projects. Through GMIF, a municipal government can borrow at preferred interest rates of 1.5% below the Bank of Canada bond rate. Project partners are also eligible for loans at attractive rates. Where favorable interest rates are available through loan and 3rd party finance programs, lifetime financing costs can be greatly reduced for biomass power projects.

Emissions Credits

Several jurisdiction offer government regulated or voluntary incentives programs to reduce emissions such as sulfur dioxide (SO2) or carbon dioxide (CO2). Through typical emissions programs, utilities or industries may receive emissions credits or allowance for each tonne of SO2 or CO2 avoided through internal efficiency or renewable electricity projects or purchase such credits or allowances from independent renewable electricity projects that have been credited for their projects. This creates a new value stream for renewable electricity project developers, as long as project emission reductions are recognized by the allowance or credit program authority and a customer for credits or allowances exists.

Although emissions credits do not directly affect the cost of producing electricity from renewable resources, they do create a new revenue stream for the renewable electricity producers and can allow them to price electricity more competitively relative to traditional power sources. Furthermore, the revenues from emissions reductions can reduce payback periods and increases the profitability of a renewable electricity project. Where emissions credits are available, significant additional revenue streams for biomass power projects may exist, which can offset operating expenses.

Government R&D Support Programs

Several jurisdictions have research support program and schemes aimed at the technological advancement of renewable electricity technologies. These include grant programs or foundations for supporting pure research, demonstration activities or commercialization activities related to renewable electricity technologies. These initiatives can also include publicly funded projects such as education schemes or demonstration sites to create awareness about the opportunities and benefits of renewable electricity installations. Contributions from such programs can lead to reduced research and development cost amortization periods for technologies entering the market and consequently lower initial technology costs to renewable electricity project developers.

An example of such a foundation in Canada is Sustainable Development Technology Canada (SDTC). The objective of this foundation is to stimulate the development and demonstration of Canadian technologies related to climate change, clean air, water quality and soil through partial funding of eligible projects. Eligible recipients are partnerships that include the private sector and academic and non-governmental organizations. Eligible projects are aimed at advancing the development and demonstration of new sustainable technologies, many of which are renewable electricity technologies.

Similarly in the US, a bill passed in 1999, provides funding for research and development specifically targeted at advanced photovoltaic devices. Research areas covered under the bill include thin films, high-performance devices, silicon materials, characterization techniques, and other innovative concepts.


THERMODYNAMIC DATA FOR BIOENERGETICS

Definitions

Air-Drying - process of partial drying of a sample to bring its moisture content near to equilibrium with the atmosphere in which further reduction, division, and characterization of the sample are to take place.

Air-Dry Loss - decrease in sample mass due to air-drying. This decrease is presumed to be moisture.

Ash - residue remaining after ignition of a sample determined by a definite prescribed procedure.

Enthalpy - H, is defined by the equation: H = U + PV, where U is the internal energy of the system, P is the pressure, and V is the volume.

Gross Heat of Combustion - heat produced by combustion of one unit of substance at constant volume in an oxygen bomb calorimeter under specified conditions. The conditions are: initial oxygen pressure of 2.0-4.0 MPa (20-40 atm), final temperature of 20°-35°C (68-95°F), products in the form of ash, liquid water, gaseous CO2 and N2, and dilute aqueous HCl and H2S04. It is assumed that if significant quantities of metallic elements are combusted, they are converted to their oxides. In the case of materials such as coal, wood, or refuse, if small or trace amounts of metallic elements are present, they are unchanged during combustion and are part of the ash. In accurate studies, the observed heat is corrected for side reactions and to a standard state in which all gases are at unit fugacity. For most of the data reported here, the precision of the measurements does not warrant such refinement.

Gross Heat of Reaction - specific isothermal gross heat of reaction at the specified temperature and at constant volume, qv(gross), is equal to -DU/M, where DU is the molar change in internal energy of the process, and M is the molecular weight. Usually, the values of qv (or DU) have not been converted to the standard state (-DU°/M). Some of the data are of such low precision, because of sample variability or measurement method, that this correction is impractical. The numerical values for qv(gross) are given in J.g-1 , cal.g-1, and Btu.lb-1.

Heat of Fusion Lf - specific latent heat of fusion (DHfus/M) at a pressure of 101325 Pa (I atm). The value is the heat absorbed (in J, cal, or Btu) when one unit mass of the substance goes from the solid state to the liquid state. For a pure compound, the melting occurs at a single temperature; for the complex materials considered here, the melting process may take place over a temperature range.

Heat of Sublimation Ls - specific latent heat of sublimation (DHsub/M). The value is the heat absorbed when one unit mass of the substance goes from the solid state to the gaseous state.

Heat of Transition Lt - specific latent heat of transition (DHtrs/M) at a pressure of 101325 Pa (1 atm). The value is the heat absorbed when one unit mass of the substance goes from one solid phase to another solid phase. For a pure compound, the transition occurs at a single temperature; for the complex materials considered here, the transition process may take place over a temperature range.

Heat of Vaporization Lv - specific latent heat of vaporization (DHvap/M). The value is the heat absorbed when one unit mass of the substance goes from the liquid state to the gaseous state. If measured calorimetrically, the value will be for a definite temperature and pressure. If derived from the vapor pressure equation through the relation d(lnP)/d(l/T) = -DHvap/R, the value may be referred to a definite temperature and pressure, depending upon the form of the equation. With the simple form lnP = A-B/T, the value refers to the midpoint of the temperature range over which the equation is valid. The value thus obtained is for one mole of gaseous species; the average molecular weight must be obtained to calculate the specific heat of vaporization: Lv = DHvap/M.

Internal Energy - when heat, q, is added or removed, and work, w, is done on or by the system, its internal energy, U, is modified according to the equation: U = q + w .

Net Heat of Combustion - heat produced by combustion of one unit of substance at atmospheric pressure under conditions such that all water in the products remains in the form of vapor. The net heat of combustion is calculated from the gross heat of combustion at 20°C (68°F) by subtracting 572 cal.g-l (1030 Btu.lb-l) of water derived from one unit mass of sample, including both the water originally present as moisture and that formed by combustion. This subtracted amount is not equal to the latent heat of vaporization of water (586 cal.g-l at 20°C) because the calculation also reduces the data from the gross value at constant volume to the net value at constant pressure. The appropriate factor for this reduction is 572 cal.g-l .

Net Heat of of Reaction - specific isothermal net heat of reaction at the specified temperature and at constant volume. qv(net) is equal to -DU/M, where DU is the molar internal energy of the process, and M is the molecular weight. This value differs from qv(gross) in that water formed is in the gaseous state. .

Residual Moisture - moisture content remaining in a sample after it has been airdried and milled down, if necessary, to an analysis sample.

Specific Heat Cp - change in enthalpy with temperature at constant pressure (1 atm unless otherwise specified) for one unit mass of substance. Cp = [d(H/M)/dT]p. At constant volume Cv = [d(U/M)/dT]v. Numerical values for C are given in J.g-l.K-l, cal.g-l .K-l, and Btu.lb-l .°F-l .

Sublimation Pressure - saturated equilibrium pressure over the solid substance at a given temperature. Values are expressed in pascals (Pa = N.m-l) and in Torr (Torr = 133.3224 Pa). The conventional atmosphere is taken as 101325 Pa. One bar is 100,000 Pa.

Temperature - absolute temperature, T, is based upon the International Practical Temperature Scale. Values are given in kelvins (symbol K). The Celsius ("Centigrade") scale (symbol °C) is used to indicate the temperature or temperature range for many reported measurements. It is defined as t(°C) = T(K) - 273.15. The Fahrenheit scale, provided as a convenience for many measurements, is defined as t(°F) = 1.8t(°C) + 32. Unless specifically indicated otherwise, all temperatures T involved in equations are absolute temperature (T, K).

Vapor Pressure - saturated equilibrium pressure over the liquid substance at a given temperature. Values are expressed in pascals (Pa = N-m-l) and in Torr (Torr 133,3224 Pa). The conventional atmosphere is taken as 101325 Pa.

Volatile Fraction VCM - the sample is placed in a covered crucible at 600°C for 6 minutes followed by heating at 950°C for 6 minutes. The loss in weight is the volatile fraction.

Volatile Matter - Those products exclusive of moisture given off by the sample as a gas or vapor determined by definite prescribed procedures. In ASTM D 3175-77, Standard Test Method for Volatile Matter in the Analysis of Coal and Coke, the weighed sample is placed in a covered platinum crucible at 950°C for exactly 7 minutes. The loss in weight is the volatile fraction.


A FORMULA FOR THE EMPIRICAL ESTIMATION OF THE HEATS OF COMBUSTION OF CARBONACEOUS MATERIALS

In modeling biomass reactions and reactors it is necessary to have values for the heats of formation and combustion of the various materials considered. A collection of representative data for biomass and wastes appears in the main body of this publication. In some cases, the composition of carbonaceous materials is known or can be estimated, while the heats have not been measured. In 1978, the Institute of Gas Technology developed a formula for predicting the higher heating values (heat of combustion) (HHV, dry basis) of coal (IGT, 1978)

higher heating value: HHV = DHc = 146.58 C + 568.78 H - 51.53 (O + N) - 6.58 A + 29.45 S Btu/lb

where C, H, 0, N, S, and A are the weight' percents of carbon, hydrogen, oxygen, nitrogen, sulfur, and ash respectively.

This equation was derived by correlating the thermal data with the composition on more than 700 samples of coal. In the Survey of Biomass Gasification (Reed, 1979) Graboski and Bain used this formula, as well as two others, on 15 samples of biomass and 5 samples of char and found average etrors from the measured values of 1.7% and 2.1% respectively. The error of actual measurements of composition and heats of combustion probably exceeds this, so that this suggests that the method can be used for all biomass solids.
Reed (1985) has extended the IGT equation to a wide variety of carbonaceous materials. The equation in the modified SI form is:

HHV = 0.341 C + 1.322 H - 0.12 (O + N) - 0.0153 A + 0.0686 S kJ/g

Note that in general the last two terms will be very small compared to the first three. The equation is also useful in the molecular form (on a dry, ash-free, sulfur-free basis) to estimate the heat of combustion for biomass in which the formulas are given:

DHc = 4.092 nC + 1.322 nH - 1.916 y(N + O) kJ/mole

where ni is the number of moles of each element in the formula
The heat of formation can be calculated from the heat of combustion from using the equation:

DHf = DHc - nC [DHc(C)] - nH [DHc(H2)/2]

where DHc(C) and DHc(H2) are the heats of combustion of carbon and hydrogen.

The above equations were used to calculate thermal data for the biomass-related materials shown in table. This table includes representative samples of biomass, charcoals, pyrolysis oils, and tars taken from the literature but not included in this handbook. The average absolute error for each of these materials was 1.696, 1.6%, 2.5%, and 2.5% respectively. Thus, it seems that the above equations form a reliable basis for predicting biomass thermochemical data where measured heats are not available, and can form a supplement to the representative heats of combustion shown in this publication.


Table: Calculated and Measured Heats of Combustion for Various Biomass Materials Using an Empirical Formula

Name

Reference

Composition
Dry, ash-free, Wt%

 Heat of Combustion

Error
(Meas/Calc)

C

H

O

Calculated
HHV
kJ/g

Measured
HHV
kJ/g

Biomass Components

Cellulose (Avicel)

Mok

43.3

6.3

50.4

NA

17.14

NA

Lignin (Indulin)

Mok

66.8

5.5

27.7

NA

26.77

NA

Biomass

Pine Sawdust

Diebold

51.3

6.0

42.7

20.21

20.40

-0.009

Maple

Tillman

51.5

6.1

42.4

20.28

20.59

-0.015

Douglas Fir

Tillman

52.8

6.4

40.9

21.22

21.56

-0.016

Paper

Reed 1981

46.4

6.2

47.4

18.82

18.41

0.022

Maritime Pine

Bourgeois

52.6

6.2

41.2

20.59

21.23

-0.031

Chestnut & Oak

Bourgeois

50.1

5.6

44.3

19.20

19.27

-0.004

Typical biomass

Reed 1985

52.2

6.1

41.7

NA

20.89

NA

Primary Oils

R 35CS

Diebold

54.5

5.7

39.8

20.31

21.44

-0.055

R 40CS

Diebold

57.6

5.9

36.5

22.88

23.11

-0.010

R 40PS

Diebold

57.1

5.6

37.2

22.27

22.53

-0.011

Chars

Temp. of formation
°C

 

 

 

 

 

 

 

Torrefied Pine

280

Bourgeois

60.8

5.7

33.5

23.90

24.30

-0.017

Torr. Chestnut & Oak

275

Bourgeois

57.8

5.3

36.9

22.70

22.36

0.015

Charcoal

 

Tillman

84.8

3.3

11.9

32.81

31.85

0.029

Fir Bark Char

 

Reed 1981

63.6

5.1

31.3

24.49

24.75

-0.011

Grass Straw Char

 

Reed 1981

68.5

5.0

26.5

25.93

26.82

-0.035

Rice Hull Char

 

Reed 1981

71.6

5.2

23.3

28.18

28.50

-0.011

Redwood Charcoal

 

Reed 1981

77.7

3.4

18.9

29.62

28.75

0.029

Oak Charcoal

549

Reed 1981

78.6

2.6

18.9

28.02

27.96

0.002

Oak Charcoal

571

Reed 1981

80.1

2.8

17.0

29.32

29.07

0.008

Redwood Charcoal

641

Reed 1981

82.5

3.7

13.8

31.88

31.37

0.016

FP Chars

Run 53

941

Diebold

87.7

3.8

8.4

34.40

33.98

0.012

Run 54

625

Diebold

83.2

3.7

13.1

34.09

31.72

0.070

Run 59

625

Diebold

84.1

3.8

12.1

33.63

32.25

0.041

Run X

625

Diebold

92.6

1.9

5.5

33.42

33.47

-0.002

Secondary Tars

Run 55

650

Diebold

82.2

5.3

12.5

32.44

33.59

-0.035

Run 56

730

Diebold

85.4

5.0

9.6

34.08

34.60

-0.015

Run 59

825

Diebold

79.3

5.9

14.8

33.92

33.09

0.024

 


SYMBOLS

Primary Symbols

T - thermodynamic temperature (absolute temperature)

K - Kelvin temperature

t - Celsius temperature

R - molar gas constant

k - Boltzmann constant

q , Q - heat

w , W -  work

U , (E) - internal energy

H - enthalpy: H = U + pVz

S - entropy

A -  Helmholtz energy: A = U - TS

J - Massieu function: J = -A/T

G - Gibbs energy: G = H - TS (The Gibbs energy is frequently called free energy, Gibbs free energy, or Gibbs function. The commonly encountered term free energy in American work on thermodynamics almost invariably refers to Gibbs energy. This usage of the term free energy and the symbol F are being discouraged by the IUPAC because of confusion with the Helmholtz energy and the common European usage of F for the latter.)

Y - Planck function: Y = G/T

Z - compressibility factor: Z = pV/nRT

Cp  - heat capacity

cp  - specific heat capacity (heat capacity divided by mass)

g , (k) - heat capacity ratio: Cp /Cv

m - Joule-Thomson coefficient

l , k - thermal conductivity

a - thermal diffusivity: a = l/r.Cp

h - coefficient of heat transfer

a - cubic expansion coefficient: u = (dV/dT)p/V

k - isothermal compressibility: = (dV/dp)T/V

mB - chemical potential of substance B

lB - absolute activity of substance B: lB = exp(mB/RT)

f , (p*) - fugacity

m - osmotic pressure

I - ionic strength:  I = ½ Σimi zi2  or  I = ½ Σici zi2

aB - activity, relative activity of substance B

fB - activity coefficient, mole fraction basis

gB - activity coefficient, molality basis

yB - activity coefficient, concentration basis

F - osmotic coefficient

 

Selected Symbols for Other Quantities in Thermodynamics

A , S - area

V - volume

t - time

m - mass

r - density (mass divided by volume)

p - pressure

Ar - relative atomic mass (also called "atomic weight")

Mr - relative molecular mass (also called "molecular weight")

L , NA - Avogadro constant

N - number of molecules

n , (n) - amount of substance

xB , yB - mole fraction of substance B:  xB = nB/Σini

wB - mass fraction of substance B

FB - volume fraction of substance B

mB - molality of solute substance B (amount of B divided by the mass of solvent)

cB [B]- concentration of substance B (amount of B divided by the volume of the solution)

rB - mass concentration of substance B (mass of B divided by the volume of the solution)

nB - stoichiometric coefficient of substance B (negative for reactants, positive for products).

the general equation for a chemical reaction:   ΣnBB = 0
example for the reaction H
2O → H2 + ½ O2 :      H2 + ½ O2 - H2O = 0

z - extent of reaction: (dz = dnB/nB)

K - equilibrium constant

a - degree of dissociation

zB - charge number of an ion B (positive for cations, negative for anions)

Units of Measurement

Base Units

Quantity

Name of Unit

Symbol

length

meter

m

mass

kilogram

kg

time

second

s

temperature

kelvin

K

electric current

ampere

A

luminous intensity

candela

cd

amount of substance

mole

mol

plane angle

radian

rad

solid angle

steradian

sr

SI Derived Units (Partial Listing)

Quantity

Name of Unit

Symbol

Definition

Other Definitions

force

newton

N

m.kg.s-2

 

pressure

pascal

Pa

m-1.kg.s-2

N.m-2

energy

joule

J

m2.kg.s-2

N.m

power

watt

W

m2.kg.s-3

J.s-1

electric charge

coulomb

C

A.s

 

electric potential difference

volt

V

m2.kg.s-3.A-1

W.A-1

electric resistance

ohm

W

m2.kg.s-3.A-2

V.A-1

electric conductance

siemens

S

m-2.kg-1.s3.A2

A.V-1

electric capacitance

farad

F

m-2.kg-1.s4.A2

C.V-1

magnetic flux

weber

Wb

m2.kg.s-2.A-1

V.s

inductance

henry

H

m2.kg.s-2.A-2

Wb.A-1

magnetic flux density

tesla

T

kg.s-2.A-1

Wb.m-2

luminous flux

lumen

Irn

cd.sr

 

illumination

lux

Ix

m-2.cd.sr

 

frequency

hertz

Hz

s-1

 

Other Units Exactly Defined in Terms of SI Units (Partial Listing)

Quantity

Name of Unit

Symbol

Definition

Other

length

inch

in.

2.54x10-2 m

 

mass

pound (av.)

lb

0.453 592 37 kg

 

force

kilogram force

kg f

9.806 65 N

 

pressure

atmosphere

atm

101 325 N.m-2

 

pressure

torr

Torr

101 325/760 N.m-2

 

pressure

millimeter of mercury

mmHg

13.5951 x 980.665 x 10-2 N.m-2

 

energy

kilowatt-hour

kWh

3.6 x 106 J

 

energy

thermochemical calorie

calth

4.184 J

used in this publication

energy

thermochernical Btu

Btuth

1054.35 J

1 Btuth = (4.1840/1.8) x 453.59237 J

energy

IT calorie

calIT

4.1868 J

IT refers to International Steam Tables

energy

IT British thermal unit

BtuIT

1055.056 J

1 BtuIT = (4.1868/1.8) x 453.59237 J

temperature (thermodynamic)

degree Rankine

°R

5/9 K

T(°R) = l.8T(K)
T(
°R) = t(°F) + 459.671
T(
°R) = t(°C) + 491.67

temperature

degree Celsius

°C

K

 t(°C) = T(K) - 273.151

temperature

degree Fahrenheit

°F

5/9 K

t(°F) = 1.8t(°C) + 321

volume

liter

l

10-3 m3

 

Energy Conversion Factors

1 calth = 4.1840 J
1 calIT = 4.1868 J
1 Btuth = 1054.35 J
1 BtuIT = 1055.056 J

1 calth/g = 1.8 Btuth/lb
1 calIT/g = 1.8 BtuIT/lb
1.8 Btuth/lb = 2.326 J/g

1 Btuth/(lb.°F) = 1 calth/(g.K)

Temperature Conversion Factors

1.8(°C) + 32 = °F
273.15 +
°C = K
 

[(459.67) + °F]/1.8 = K
1.8 K  = 459.67 +
°F

1.8 K = °R
°R = 459.67 + °F

Physical Constants

Gas Constant

R = 82.0568 (26) cm3.atm.rnol-1 K-1

R = 8.31441 (26) J.rnol-1 K-1

R = 1.987 19 (6) calth.rnol-1 K-1

Molar Gas Volume

Vm = 0.02241383 (70) m3.rnol-1 (at To = 273.15 K and po = 1 atm)

Heat of Combustion of Waste and Biomass Materials

Name

Reference

Composition Wt%

 Heat of Combustion  kJ/g

VCM

ash

carbon

qV(gross)

qV(net)

Agricultural Residues

ALFALFA, SEED, STRAW

Jenkins 1985

72.60

7.25

20.15

18.45

17.36

BARLEY STRAW

Jenkins 1985

68.80

10.30

20.90

17.31

16.24

BEAN STRAW

Jenkins 1985

75.30

5.93

18.77

17.46

16.32

CORN COBS

Jenkins 1985

80.10

1.36

18.54

18.77

17.58

CORN STOVER

Jenkins 1985

75.17

5.58

19.25

17.65

16.52

COTTON STALKS

Jenkins 1985

65.40

17.30

17.30

15.83

14.79

PEANUT HULLS

Jenkins 1985

73.02

5.89

21.09

18.64

17.53

RICE STRAW

Jenkins 1985

69.33

13.42

17.25

16.28

15.34

RICE STRAW WEATHERED

Jenkins 1985

62.31

24.36

13.33

14.56

13.76

SUGARCANE BAGASSE

Jenkins 1985

73.78

11.27

14.95

17.33

16.24

WALNUT SHELLS

Jenkins 1985

78.28

0.56

21.16

20.18

19.02

WHEAT DUST

Jenkins 1985

69.85

13.68

16.47

16.20

15.16

WHEAT STRAW

Jenkins 1985

71.30

8.90

19.80

17.51

16.49

Animals

CATTLE

Stroud

 

 

 

22.79

39.74

CILIATE Tetrahymena pyriforrnis

Slobodkin

 

 

 

24.84

 

CLADOCERA Leptodora kindtu

Slobodkin

 

 

 

23.45

 

COPEPOD Calanus helgolandicus

Slobodkin

 

 

 

23.07

 

LEATHER

Kaiser 1966

57.12

21.16

14.26

18.20

 

SHEEP BLOOD

Paladines

 

 

 

24.57

 

SHEEP CARCASS

Paladines

 

 

 

32.54

 

SHEEP VISCERA

Paladines

 

 

 

33.51

 

Biomass-Derived Materials

CELLULOSE red oak

Murphey

 

 

 

 17.02

 

CELLULOSE from wood pulp

Jessup 1950

 

 

 

 17.45

 

CELLULOSE 99.81% pure

Colbert 1981

 

 

 

 17.34

 

CELLULOSE DIACETATE

Tavernier 1957

 

0.04

 

18.60

 

CHARCOAL WOOD

Spiers

10

1

89

34.72

 

COTTON

Mansson

 

 

 

17.18

 

DEXTRIN

Merill

 

 

 

17.19

 

LIGNIN HARDWOOD

Rydholm

 

 

 

24.68

 

LIGNIN SOFTWOOD

Rydholm

 

 

 

26.36

 

MANURE PIG

Backhurst

 

 

 

17.90

 

STARCH

Merill

 

 

 

17.57

 

SULFITE LIQUOR SPENT

Hulden

 

 

 

18.80

 

Foods

BEANS DRY

Merill

 

 

 

16.32

 

CABBAGE Brassica olerucea

Merill

 

 

 

0.88

 

COCONUT

Merill

 

 

 

11.34

 

CORN (MAIZE), GREEN

Merill

 

 

 

4.65

 

COWPEAS Vigna sinesis

Merill

 

 

 

16.73

 

EGG ALBUMIN

Merill

 

 

 

23.89

 

EGG YOLK

Merill

 

 

 

24.43

 

FAT ANIMAL

Merill

 

 

 

39.75

 

FAT BARLEY

Merill

 

 

 

37.95

 

FAT BEEF

Merill

 

 

 

39.75

 

FAT BUTTER

Merill

 

 

 

38.78

 

FAT FRIED

Kaiser

97.64

 0.00

2.36

38.30

 

FAT LARD

Merill

 

 

 

40.12

 

FAT MUTTON

Merill

 

 

 

39.00

 

FAT OAT

Merill

 

 

 

37.95

 

FAT PORK

Merill

 

 

 

39.75

 

FAT WOOL

Paladines

 

 

 

40.75

 

FLOUR SOY BEAN

Merill

 

 

 

14.56

 

FLOUR WHEAT

Abramova

 

 

 

17.40

 

FOOD WASTES VEGETABLE

Kaiser

17.10

1.06

3.55

19.23

 

HOMINY from corn

Merill

 

 

 

16.67

 

MEAL CORN

Merill

 

 

 

15.99

 

MEAT COOKED SCRAPS

Kaiser

56.34

3.11

1.81

28.94

 

OATS

Merill

 

 

 

19.08

 

PEANUTS

Merill

 

 

 

12.72

 

POTATO WHITE

Yamada

 

0.8

 

3.54

 

RICE

Merill

 

 

 

16.12

 

WALNUTS

Merill

 

 

 

13.88

 

WHEAT

Merill

 

 

 

7.36

 

Fossil Materials

COAL ANTHRACITE

Poole

1.3

 

94.39

34.61

 

COAL BITUMINOUS

Kirklin

33.4

2.79

85.09

33.80

 

COAL SEMI-BITUMINOUS

Poole

17.5

6.80

89.79

33.40

 

COKE

Poole

1.17

6.08

92.75

32.07

 

COKE BREEZE

Poole

4.92

12.05

94.79

33.63

 

FUEL aviation gasoline

LeTourneau

 

 

 

47.02

 

FUEL COED-1 COAL DERIVED

Hazlet

 

 

 

 

42.52

FUEL JP-9 RAMJET

Smith 1978

 

 

 

44.63

42.21

GASOLINE

LeTourneau

 

 

 

46.46

 

KEROSINE

Lenoir

 

 

 

46.39

 

LIGNITE

Poole

50.6

10.12

63.30

25.65

 

NAPHTHA

Lenoir

 

 

86.30

43.36

 

NAPHTHA JET

Lenoir

 

 

86..05

46.12

 

OIL FUEL

Lenoir

 

 

86.9

40.84

 

PEAT organic soil

Davis

50.92

16.61

23.79

19.14

 

Paper

BROWN PAPER

Kaiser 1966

83.92

1.01

9.24

17.92

 

CORRUGATED BOX

Kaiser 1966

77.47

5.06

12.27

17.28

 

FOOD CARTONS

Kaiser 1966

75.59

6.50

11.80

17.98

 

JUNK MAIL

Kaiser 1966

73.32

13.09

 9.03

14.83

 

MAGAZINE

Kaiser 1966

66.39

22.47

7.03

12.74

 

NEWSPRINT

Kaiser 1966

81.12

1.48

11.48

19.72

 

PLASTIC COATED PAPER

Kaiser 1966

84.20

2.64

8.45

17.91

 

WAXED MILK CARTONS

Kaiser 1966

90.92

1.17

4.46

27.28

 

Plant Materials (Non-Woody)

ALGAE

Paine

 

 

 

13.59

 

ARCHANGEL Stachys sylvatica

Pauca-comanescu

 

 

 

17.18

 

SAGEBRUSH Artemisia tridentata

Van Epps

 

6.7

 

19.65

 

BRACKEN FERN Pteridium aquilinurn

Susott

 

9.24

 

 20.03

 

STARWORT Stellaria nemorum

Pauca-comanescu

 

 

 

15.01

 

CATTAILS

Jenkins 1985

71.57

 7.90

20.53

17.81

16.31

CHEATGRASS Bromus tectorum

Susott

 

 

 

19.36

 

CLOVEROOT Geum urbanum

Pauca-comanescu

 

 

 

17.24

 

COCKS-FOOT GRASS Dactylis pozygama

Papp

 

12.4

 

17.74

 

GRASS LAWN CLIPPINGS

Kaiser 1966

18.64

1.42

4.50

19.32

 

IRISH SHAMROCK Oxalis acetoselza

Pauca-comanescu

 

 

 

18.09

 

MOSSES ALPINE TUNDRA;

Bliss

 

 

 

18.45

 

MOUNTAIN RUSH Carex montana

Papp

 

 

 

17.66

 

ANTS FLOWER GARDEN

Kaiser 1966

35.64

2.34

8.08

18.67

 

SAW-PALMETTO Serenoa repens

Susott

 

5.37

 

21.27

 

SHRUBS, EVERGREEN CUTTINGS

Kaiser 1966

25.18

0.81

5.01

20.31

 

SUDAN GRASS

Jenkins 1985

72.75

 8.65

18.60

17.39

16.31

Polymers and Plastics

BUTENE-1-POLYSULFONE

Ivin

 

 

 

24.05

 

CELLULOID

Roth 1915

 

 

 

1767

 

DICYANDIAMIDE

Franz

 

 

 

15.62

 

DURETHAN

Franz

 

 

 

26.03

 

MELINEX

Andruzzi

 

 

 

22.92

 

2,5-METHYLOLMELAMINE

Franz

 

 

 

16,15

 

NYLON-6

Franz

 

 

 

31.69

 

PHENOL-FORMALDEHYDE RESIN

Franz

 

 

 

31.60

 

POLYACENAPHTHYLENE

Joshi

 

 

 

39.27

 

POLY-iso-BUTENE

Joshi

 

 

 

46.77

 

POLY-1,1-DICHLOROETHYLENE

Sinke

 

 

 

10.52

 

POLY-1,1-DIFLUOROETHYLENE

Good 1962

 

 

 

14.76

 

POLY-2,6-DIMETHYLPHENYLENE ETHER

Joshi

 

 

 

30.99

 

POLYETHYLENE

Splitstone

 

 

 

46.26

 

P0LY-a-METHYL STYRENE

Joshi

 

 

 

42.30

 

POLYPROPYLENE

Parks 1963

 

 

 

46.11

 

POLYSTYRENE

Franz

 

 

 

41.46

 

POLYUREA

Franz

 

 

 

24.91

 

POLYVINYL CHLORIDE

Sinke

 

 

 

18.30

 

TEFLON

Domalski 1967

 

 

 

10.37

 

Polypeptides and Proteins

CASEIN, MILK

Merill

 

 

 

23.70

 

GELATINE

Roth 1915

 

 

 

21.55

 

GLUTEN

Ponomarev

 

 

 

24.25

 

VITELLIN

Merill

 

 

 

24.10

 

WOOL

Passler

 

 

 

23.00

 

Refuse

REFUSE

Jensen

 

 

 

18.50

 

REFUSE-DERIVED FUEL

Kirklin

 

 

 

21.52

 

REFUSE, MUNICIPAL

Wisely

 

 

 

10.86

 

Rubber Materials

DISCARDED TIRES

Collins

 

 

 

40.00

 

RUBBER

Jessup

 

 

 

45.24

 

SBR (styrene-butadiene rubber)

Collins

 

 

 

40.00

 

Vegetable Oils

BARLEY OIL

Merill

 

 

 

37.95

 

CASTOR OIL

Goeting

 

 

 

37.27

 

COCONUT OIL

Merill

 

 

 

37.95

 

CORN OIL

Goeting

 

 

 

39.50

 

COTTONSEED OIL

Goeting

 

 

 

39.46

 

GROUND NUT SEED OIL

Kornan

 

 

 

39.79

 

LINSEED OIL

Kornan

 

 

 

39.68

 

OLIVE OIL

Merill

 

 

 

39.62

 

RAPESEED OIL

Kornan

 

 

 

40.64

 

RYE OIL

Merill

 

 

 

38.49

 

SESAME OIL

Goeting

 

 

 

39.34

 

SOYBEAN OIL

Goeting

 

 

 

39.62

 

SUNFLOWER OIL

Goeting

 

 

 

39.57

 

WHEAT OIL

Merill

 

 

 

37.95

 

Woody and Tree Materials

ALDER Alnus rubru

Chang 1955

 

 

 

18.47

 

ASH Fraxinus excelsior

Gottlieb

 

 

 

19.77

 

ASPEN Populus tremuloides

Chang 1955

 

 

 

19.60

 

BEECH Fagus silvatiea

Gottlieb

 

 

 

20.04

 

BEEFWOOD Casuarina equisetifolia

Jenkins 1985

78.94

1.40

19.66

19.44

18.26

BIRCH Betula alba

Gottlieb

 

 

 

19.96

 

BLACKGUM Nyssa sylvatica

Gower

 

 

 

19.67

 

BOXELDER Acer negundo

Geyer

 

 

 

18.55

 

CHAPARRAL

Jenkins 1985

75.19

6.13

18.68

 18.61

17.58

CHERRY genus Prunus

Gottlieb

 

 

 

18.28

 

COTTONWOOD Populus deltoides

Geyer

 

 

 

19.64

 

ELM Ulrnus arnericana

Chang 1955

 

 

 

16.08

 

EUCALYPTUS

Jenkins 1985

81.42

0.76

17.82

19.42

18.23

FIR Pinus silvestri

Gottlieb

 

 

 

 

21.07

FIR, WHITE

Jenkins 1985

83.17

0.25

16.58

19.95

18.74

HICKORY genus Carya

Parr

 

 

 

17.62

 

LARCH Larix occidentalis

Susott

 

0.19

 

19.83

 

LEAVES, TREE

Kaiser 1966

66.92

3.82

19.29

20.62

 

LOCUST, BLACK

Jenkins 1985

80.94

0.80

18.26

19.71

18.55

MADRONE Arbutus rnenzeisii

Jenkins 1985

82.99

0.57

16.44

19.41

18.20

MANZANITA Arctostaphylos

Jenkins 1985

81.29

0.82

17.89

19.30

18.09

MAPLE genus, Acer

Kaiser

76.10

4.30

19.60

19.05

 

MAPLE  Acer tataricurn

Papp

 

 

 

19.28

 

OAK Quercus petraea

Papp

 

 

 

19.86

 

OAK, TAN

Jenkins 1985

80.93

1.67

17.40

18.93

17.73

OAK, WHITE

Jenkins 1985

81.28

1.52

17.20

19.42

18.33

PINE Pinus strobus

Kaiser

 

 

 

21.03

 

PINE Pinus ponderosa

Jenkins 1985

82.54

0.29

17.17

20.98

18.80

POPLAR genus Populus

Jenkins 1985

82.32

1.33

16.35

19.38

18.19

REDWOOD

Jenkins 1985

79.72

0.36

19.92

20.72

19.51

REDWOOD, MILL WASTES

Jenkins 1985

81.19

0.18

18.63

20.98

 

WILLOW Salix nigra

Geyer

 

 

 

16.66

 

explosives

AMATOL 80/20 AN/TNT

Cox

 

 

 

5.17

 

DBX (AN) 21% (RDX) 21% (TNT) 40% aluminum 18%

Cox

 

 

 

14.13

 

PB-RDX (RDX) 90%, polystyrene 8.5%, dioctyl phthalate 1.5%

US. Army

 

 

 

12.66

 

PENTOLITE 50/50 PETN/TNT

Cox

 

 

 

11.60

 

POLYVINYL NITRATE

US. Army

 

 

 

12.38

 

 

 

term

EXPLANATION

1st generation biofuels  1st generation biofuels include mature technologies for the production of bioethanol from sugar and starch crops, biodiesel and renewable diesel from oil crops and animal fats, and biomethane from the anaerobic digestion of wet biomass.
2nd generation biofuels  2nd generation biofuels are novel biofuels or biofuels based on novel feedstocks. They generally use biochemical and thermochemical routes that are at the demonstration stage, and convert lignocellulosic biomass (i.e. fibrous biomass such as straw, wood, and grass) to biofuels (e.g. ethanol, butanol, syndiesel).
3rd generation biofuels  3rd generation biofuels generally include advanced biofuels production routes which are at the early stage of research and development or are significantly further from commercialisation (e.g. biofuels from algae, hydrogen from biomass).
Abiotic Having an absence of life or living organisms.
Aerobic Life or biological processes that can occur only in the presence of oxygen.
Agricultural residues  Agricultural residues include arable crop residues (such as straw, stem, stalk, leaves, husk, shell, peel, etc.), forest litter, grass and animal manures, slurries and bedding (e.g. poultry litter).
Anaerobic digestion  Decomposition of biological wastes by micro-organisms, usually under wet conditions, in the absence of air (oxygen), to produce biogas.
Animal residues  Agricultural by-products originating from livestock operations. It includes among others solid excreta of animals.
Best available control technology (BACT) That combination of production processes, methods, systems, and techniques that will result in the lowest achievable level of emissions of air pollutants from a given facility. BACT is an emission limitation determined on a case- by-case basis by the permitting authority, taking into account energy, environmental, economic and other costs of control. BACT may include fuel cleaning or treatment, or innovative fuel combustion techniques. Applies in attainment areas.
Best management practices A practice or combination of practices that is determined by a designated agency to be the most effective, practical means of reducing the amount of pollution generated by nonpoint sources to a level compatible with water quality goals.
Bagasse  Fibre left over after the juice has been squeezed out of sugar-cane stalks. It is commonly used as a source of heat supply in the production of bioethanol.
Baghouse A chamber containing fabric filter bags that remove particles from furnace stack exhaust gases. Used to eliminate particles greater than 20 microns in diameter.
Bark  The outermost sheath of tree trunks, branches, and roots of woody plants. It overlays the wood and consists of inner bark (living tissue) and outer bark (dead tissue). Bark is usually a by-product (residue) from conventional wood processing.
Barrel of oil equivalent A unit of energy equal to the amount of energy contained in a barrel of crude oil. Approximately 5.78 million Btu or 1,700 kWh. A barrel is a liquid measure equal to 42 gallons.
Baseload capacity The power output that generating equipment can continuously produce.
BIG/CC Biomass integrated gasification and combined cycle.
Bioaccumulants Substances in contaminated air, water, or food that increase in concentration in living organisms exposed to them because the substances are very slowly metabolized or excreted.
Biobutanol  Alcohol with a 4 carbon structure and the molecular formula C4H9OH produced from biomass. Biobutanol can easily be added to conventional petrol and can be blended up to higher concentrations than bioethanol for use in standard vehicle engines. Biobutanol can also be used as a blended additive to diesel fuel to reduce soot emissions.
Biochemical conversion process The use of living organisms or their products to convert organic material to fuels.
Biochemical oxygen demand (BOD) A standard means of estimating the degree of pollution of water supplies, especially those which receive contamination from sewage and industrial waste. BOD is the amount of oxygen needed by bacteria and other microorganisms to decompose organic matter in water. The greater the BOD, the greater the degree of pollution. Biochemical oxygen demand is a process that occurs over a period of time and is commonly measured for a five-day period, referred to as BOD5.
Biodiesel Biodiesel refers to a diesel-type fuel produced by transesterification of vegetable oils or animal fats. Biodiesel can be blended (with some restrictions on the level of blending) with conventional diesel for use in unmodified diesel-engine vehicles. Its full name is FAME (Fatty Acid Methyl Ester) biodiesel.
Bioenergy  Renewable energy produced from the conversion of organic matter. Organic matter may either be used directly as a fuel or processed into liquids and gases.
Bioethanol  Alcohol with a 2 carbon structure and the molecular formula C2H5OH, produced from biomass. Bioethanol can be blended with conventional gasoline or diesel for use in petroleum-engine vehicles.
Biofuel  Fuel produced directly or indirectly from biomass. The term biofuel applies to any solid, liquid, or gaseous fuel produced from organic (once-living) matter. The word biofuel covers a wide range of products, some of which are commercially available today, and some of which are still in the research and development phase.
Biogas A combustible gas derived from decomposing biological waste under anaerobic conditions. Biogas normally consists of 50-60% methane, 25-50% carbon dioxide, and other possible elements such as nitrogen, hydrogen or oxygen. See also Landfill Gas.
Biomass Organic matter available on a renewable basis. Biomass includes forest and mill residues, agricultural crops and wastes, wood and wood wastes, animal wastes, livestock operation residues, aquatic plants, fast-growing trees and plants, and municipal and industrial wastes.
Biomass feed system Electromechanical system (e.g. conveyors, pumps) to feed the biomass feedstock into the boiler of a biomass-based plant.
Biomethanol Simplest possible alcohol with the molecular formula CH3OH. Biomethanol can be blended into gasoline, but the substance is more volatile than bioethanol.
Bioreactor A bioreactor is a vessel in which a biochemical process occurs. This usually involves organisms or biochemically active substances derived from such organisms.
Biochar Biochar is charcoal created by pyrolysis of biomass.
Bio-SNG Bio Synthetic Natural Gas is syngas (produced from gasification of biomass) that has been upgraded to meet the quality standard of natural gas. Bio-SNG is often called simply SNG.
Biotechnology Technology that use living organisms to produce products such as medicines, to improve plants or animals, or to produce microorganisms for bioremediation.
Black liquor Black liquor is a by-product of the kraft process during the production of paper pulp. It is an aqueous solution of lignin residues, hemicelluloses, and the inorganic chemicals used in the process.
Boiler Any device used to burn biomass fuel to heat water for generating steam.
Bone dry Having zero percent moisture content. Biomass heated in an oven at a constant temperature of 212 degrees F or above until its weight stabilizes is considered bone dry or oven dry.
Bottom ash Noncombustable ash that is left after solid fuel has been burned.
Briquette Densified solid biofuel in the shape of cubiform or cylindrical units, produced by compressing biomass. The raw material for briquettes can be biomass of various origins (e.g. woody, herbaceous, fruit). Biofuel briquettes are usually manufactured in a piston press. The total moisture content of the biofuel briquette is usually less than 15 % of mass.
British thermal unit (Btu) A unit of heat energy equal to the heat needed to raise the temperature of one pound of water from 60 degrees F to 61 degrees F at one atmosphere pressure.
BTL Biomass-to-liquid is a (multi-step) process to produce liquid biofuels from biomass. The first step is gasification, while the second step may, for example, be Fischer Tropsch.
Bulk density Mass of a portion of a solid fuel divided by the volume of the container which is filled by that portion under specific conditions.
By-product A by-product, or co-product, is a substance, other than the principal product, generated as a consequence of producing the main product. For example, a by-product of biodiesel production is glycerine. Every bioenergy conversion chain generates co-products. These may add substantial economic value to the overall process. Examples include animal feed, food additives, specialty chemicals, charcoal, and fertilisers.
Calorific Value (Q) Amount of heat released during the complete combustion of a given amount of a combustible.
Capacity The maximum power that a machine or system can produce or carry safely. The maximum instantaneous output of a resource under specified conditions. The capacity of energy generating equipment is generally expressed in kilowatts (for devices) or megawatts (for plants).
Capacity factor (1) The ratio of the average load on a generating resource to its capacity rating during a specified period of time. (2) The amount of energy that the system produces at a particular site as a percentage of the total amount that it would produce if it operated at rated capacity during the entire year.
Capacity Price The electricity price based on the cost associated with providing the capability to deliver energy, primarily the capital cost of facilities.
Capital cost The total investment needed to complete a project and bring it to a commercially operable status. Cost of construtction of a new plant (including equipment purchase, design, engineering), and expenditures for the purchase of acquistion of new facilities.
Catalyst  A catalyst is a substance that increases the rate of a chemical reaction, without being consumed or produced by the reaction. Enzymes are catalysts for many biochemical reactions.
Cellulose Polysaccharide (long chain of simple sugar molecules) with the formula (C6H10O5)n. Cellulose is the fibrous substance which is contained in leaves and stalks of plants.
Cellulosic ethanol Cellulosic ethanol is ethanol fuel produced from lignocellulosic material such as wood. Cellulosic ethanol is chemically identical to ethanol from other sources, such as corn or sugar, and is available in a great diversity of biomass including waste from urban, agricultural, and forestry sources.
cfm Cubic feet per minute
Char The remains of solid biomass that has been incompletely combusted, such as charcoal resulting from wood that is incompletely burned.
Charcoal Solid residue derived from carbonisation distillation, pyrolysis, and torrefaction of fuelwood.
Chips  Woody material cut into short, thin wafers. Chips are used as a raw material for pulping and fibreboard or as biomass fuel.
Circulating fluidised bed (CFB) A type of furnace in which the emission of sulphur compounds is lowered by the addition of crushed limestone in the fluidised bed thus obviating the need for much of the expensive stack gas clean-up equipment. The particles are collected and recirculated, after passing through a conventional bed, and cooled by boiler internals.
CHP Combined Heat and Power
CO2 Carbon dioxide.
Cogeneration The simultaneous production of electricity and useful thermal energy from a common fuel source. Surplus heat from an electric generating plant can be used for industrial processes, or space and water heating purposes (topping cycle). Reject heat from industrial processes can be used to power an electric generator (bottoming cycle). Combined Heat and Power (CHP)
Coliform bacteria Bacteria whose presence in waste water is an indicator of pollution and of potentially dangerous contamination.
Combined cycle Two or more energy generation processes in series or in parallel, configured to optimise the energy output of the system.
Combined Cycle Power Plant The combination of a Brayton-Joule Cycle (gas turbine) and a Rankine Cycle (steam turbine) in an electric generation plant. The waste heat from the gas turbine provides the heat energy required for the steam cycle. This is also called combined cycle gas turbine.
Combustion (of biomass) The transformation of biomass fuel into heat, chemicals, and gases through chemical combination of hydrogen and carbon in the fuel with oxygen.
Combustion gases The gases released from a combustion process.
Combustion air The air fed to a fire to provide oxygen for combustion of fuel. It may be preheated before injection into a furnace.
Compressed Natural Gas (CNG) CNG is made by compressing natural gas to less than 1% of its volume at standard atmospheric pressure. It is used in traditional gasoline internal combustion engine cars that have been converted into bi-fuel vehicles (gasoline/CNG).
Condenser A heat-transfer device that reduces a fluid from a vapor phase to a liquid phase.
Conservation Efficiency of energy use, production, transmission, or distribution that results in a decrease of energy consumption while providing the same level of service.
Conveyor A mechanical apparatus for carrying bulk material from place to place; for example, an endless moving belt or a chain of receptacles.
Cyclone separator A device used to remove particulate matter suspended in exhaust gases.
Density Ratio of mass to volume. It must always be stated whether the density refers to the density of individual particles or to the bulk density of the material and whether the mass of water in the material is included.
Dimethyl ether (DME) Liquid biofuel with the molecular formula CH3OCH3. DME is produced by the dehydration of methanol and can be used as a fuel in diesel engines, petrol engines, and gas turbines. It works particularly well in diesel engines due to its high cetane number.
Discount rate A rate used to convert future costs or benefits to their present value.
Discounting A method of converting future dollars into present values, accounting for interest costs or forgone investment income. Used to convert a future payment into a value that is equivalent to a payment now.
Distribution The transfer of electricity from the transmission network to the consumer.
District heating or cooling a system for distributing hot water, steam, or chilled water generated in a centralised location for residential and commercial heating or cooling requirements.
Digester An airtight vessel or enclosure in which bacteria decompose biomass in wet conditions to produce biogas.
Downdraft gasifier A gasifier in which the product gases pass through a combustion zone at the bottom of the gasifier.
Dry matter Material after removal of moisture under specific conditions.
Dry matter content Fraction of dry matter in the total material on mass basis.
Dry Ton 2,000 pounds of material dried to a constant weight.
E85 Mix of 85% ethanol and 15% petrol. E85 is a common bioethanol blend used in flex-fuel vehicles. Other blends exist such as E5 and E100. The number always refers to the percentage of ethanol blended in the petrol.
EC European Commission.
Effluent The liquid or gas discharged from a process or chemical reactor, usually containing residues from that process.
EJ Exajoules (1EJ = 1018J).
Emissions Waste substances released into the air or water.
Energy The ability to do work.
Energy crops Crops grown specifically for their fuel value. These include food crops such as corn and sugar-cane, and non-food crops such as poplar trees and switchgrass.
Energy density Ratio of net energy content and bulk volume.
Energy Price The electricity price based on the variable costs associated with the production of electric energy (kilowatt-hours).
Engine A device that converts the energy of a fuel into mechanical power. The combination of an engine and an alternator converts heat from combustion (e.g. of biomass) into power.
Enzyme A protein or protein-based molecule that speeds up chemical reactions occurring in living things. Enzymes act as catalysts for a single reaction, converting a specific set of reactants into specific products.
Ethyl-tertio-butyl-ether (ETBE) Organic compound with the formula C6H14O. ETBE is commonly used as an oxygenate gasoline additive in the production of gasoline from crude oil.
EU European Union.
Externality A cost or benefit not accounted for in the price of goods or services. Often ‘externality’ refers to the cost of pollution and other environmental impacts.
FAME Biodiesel Fatty Acid Methyl Ester Biodiesel.
Feed-in tariff Subsidy mechanism by which the regional or national electricity companies are obligated to buy the electricity generated from renewable resources by decentralised producers at fixed prices (the feed-in tariffs) set by the government, The higher price helps overcome the cost disadvantages of renewable energy sources.
Feedstock Any material which is converted to another form or product. A feedstock is any biomass resource destined for conversion to energy or biofuel. For example, corn is a feedstock for ethanol production, soybean oil may be a feedstock for biodiesel and cellulosic biomass has the potential to be a significant feedstock source for biofuels.
Fermentation Conversion of carbon-containing compounds by micro-organisms for production of fuels and chemicals such as alcohols, acids or energy-rich gases. It is a biochemical reaction that breaks down complex organic molecules (such as carbohydrates) into simpler materials (such as ethanol, carbon dioxide, and water). Bacteria or yeasts can ferment sugars to bioethanol.
Fine A very small particle of material such as very fine sander dust or very small pieces of bark.
Firewood Cut and split oven-ready fuelwood used in household wood burning appliances such as stoves, fireplaces and central heating systems. Firewood usually has a uniform length, typically in the range 150 mm to 500 mm.
Firm power (firm energy) Power which is guaranteed by the supplier to be available at all times during a period covered by a commitment. That portion of a customer’s energy load for which service is assured by the utility provider.
Fischer Tropsch (FT) Process Catalysed chemical reaction in which syngas from gasification is converted into a liquid biofuel of various kinds.
Flex-fuel vehicle (FFV) Vehicles that can use either biofuels and/or petroleum interchangeably.
Flow rate The amount of water or gas that moves through an area (usually pipe) in a given period of time.
Fluidized-bed boiler A large, refractory-lined vessel with an air distribution member or plate in the bottom, a hot gas outlet in or near the top, and some provisions for introducing fuel. The fluidized bed is formed by blowing air up through a layer of inert particles (such as sand or limestone) at a rate that causes the particles to go into suspension and continuous motion. The super-hot bed material increased combustion efficiency by its direct dontact with the fuel.
Fluidised-bed combustion (FBC) Fluidised-bed combustion is a technology that improves the chemical reactions and heat transfer of boilers in power plants, and hence its overall efficiency, as compared to traditional fixed-beds. FBC plants are more flexible than conventional plants because they can be fired on coal and biomass, among other fuels. FBC also reduces the amount of sulphur emitted in the form of SOX emissions.
Fly ash Small ash particles carried in suspension in combustion products.
Forest residues Material not harvested or removed from logging sites in commercial hardwood and softwood stands as well as material resulting from forest management operations such as pre-commercial thinnings and removal of dead and dying trees.
Fossil fuel Solid, liquid, or gaseous fuels formed in the ground after millions of years by chemical and physical  changes in plant and animal residues under high temperature and pressure. Oil, natural gas, and coal are fossil fuels.
Fuel Any material that can be burned and converted to energy.
Fuel cell A device that converts the energy of a fuel directly to electricity and heat, without combustion.
Fuel handling system A system for unloading fuel from vans or trucks, transporting the feedstock to a storage location (e.g., pile, silo), and conveying it from storage to the boiler or other energy conversion equipment.
Fuelwood Wood fuel where the original composition of the wood is preserved.
Furnace An enclosed chamber or container used to burn biomass in a controlled manner to produce heat for space or process heating.
Gas engine A piston engine that uses gaseous fuel or gasoline. Fuel and air are mixed before they enter cylinders; ignition occurs with a spark.
Gas turbine A turbine that converts the energy of hot compressed gases (produced by burning fuel in compressed air) into mechanical power. Often fired by natural gas or fuel oil.
Gasification A thermochemical process at elevated temperature and reducing conditions to convert a solid fuel to a gaseous form (CO, H2, CH4, etc.), with char, water, and condensibles as minor products.
Gasifier A device for converting solid fuel into gaseous fuel. In biomass systems, the process is referred to as pyrolytic distillation.
Generator A machine used for converting rotating mechanical energy to electrical energy.
Gha Gigahectares (1Gha = 109ha)
GHG Greenhouse gas. Gases that trap the heat of the sun in the Earth's atmosphere, producing the greenhouse effect. The two major greenhouse gases are water vapour and carbon dioxide. Other greenhouse gases include methane, ozone, chlorofluorocarbons, and nitrous oxide.
GIS Geographic Information System. An information system for capturing, storing, analysing, managing, and presenting data which are spatially referenced (linked to location).
GJ Gigajoule (1GJ = 109J)
GJe Gigajoule electrical.
GJth Gigajoule thermal.
GMO Genetically Modified Organism.
Greenhouse effect The effect of certain gases in the Earth's atmosphere in trapping heat from the sun.
Grid An electric utility system for distributing power.
Grid connection Joining a plant that generates electric power to a utility system so that electricity can flow in either direction between the utility system and the plant.
GW Gigawatt. A measure of electrical power equal to one billion watts (1,000,000 kW). A large coal or nuclear power station typically has a capacity of about 1 GW.
Gross heating value (GHV) The maximum potential energy in the fuel as received. It reflects the displacement of fiber by water present in the fuel. Expressed as: GHV = HHV (1 - MC / 100).
Hammermill A device consisting of a rotating head with free-swinging hammers which reduce chips or hogged fuel to a predetermined particle size through a perforated screen.
Heat Rate The amount of fuel energy required by a power plant to produce one kilowatt-hour of electrical output. A measure of generating station thermal efficiency, generally expressed in Btu per net kWh. It is computed by dividing the total Btu content of fuel burned for electric generation by the resulting net kWh generation.
Heating value Amount of heat released during the complete combustion of a given amount of a combustible
Hectare (Ha) Common metric unit of area, equal to 2.47 acres. 1 hectare equals 10,000 square meters. 100 hectares = 1 square kilometre. Abbreviated as ha.
Herbaceous biomass Biomass from plants that has a non-woody stem and which dies back at the end of the growing season.
Higher heating value (HHV) Amount of heat released during the complete combustion of a given amount of a combustible (initially at 25°C) and the cooling of the combustion products back to 25°C. Thus, the HHV includes the latent heat of vaporisation of the water contained in the combustion products. For wood, the range is 7,600 to 9,600 Btu/lb.
Horsepower (hp) electrical horsepower: A unit for measuring the rate of mechanical energy output. The term is usually applied to engines or electric motors to describe maximum output.
1 hp = 745.7 Watts = 0.746 kW = 2,545 Btu/hr.
Hydraulic load Amount of liquid going into a system.
Hydrocarbon Any chemical compound containing hydrogen and carbon.
Hydrogen Simplest molecule conceivable, with a molecular formula of H2. Gaseous fuel that can be produced from fossil fuels, biomass and electricity.
Hydrogenation Process which typically constitutes the addition of pairs of hydrogen atoms to a molecule. Biodiesel manufactured from the hydrogenation of vegetable oil and animal fat can be blended in any proportion with petroleum-based diesel.
Hydrolysis Hydrolysis is a chemical reaction that releases sugars, which are normally linked together in complex chains. In bioethanol production, hydrolysis reactions are used to break down the cellulose and hemicellulose in the biomass.
IEA International Energy Agency.
Incinerator Any device used to burn solid or liquid residues or wastes as a method of disposal. In some incinerators, provisions are made for recovering the heat produced.
Inclined grate A type of furnace in which fuel enters at the top part of a grate, passes over the upper drying section where moisture is removed, and descends into the lower burning section. Ash is removed at the lower part of the grate.
Indirect liquefaction Conversion of biomass to a liquid fuel through a synthesis gas intermediate step.
Induction generator A variable speed multi-pole electric generator.
Infiltration Leakage of ground water or surface run-off into a manure collection system.
Influent Waste water going into the anaerobic digester.
Interconnection A connection or link between power systems that enables them to draw on one another’s reserve in time of need.
Interruptible load Loads that can be curtailed at the supplier’s discretion or in accordance with a contractual agreement.
Investment tax credit A specified percentage of the dollar amount of certain new investments that a company can deduct as a credit against its income tax bill.
Investor-owned utility (IOU) A private power company owned by and responsible to its shareholders and regulated by a public service commission.
IPCC Intergovernmental Panel on Climate Change.
Jatropha Jatropha curcas is a non-edible evergreen shrub found in Asia, Africa and the West Indies. Its seeds contain a high proportion of oil which can be used for making biodiesel.
Joule Metric unit of energy, equivalent to the work done by a force of one Newton applied over a distance of one metre (= 1 kg.m2/s2). One joule (J) = 0.239 calories (1 calorie = 4.187 J).
kW Kilowatt. A measure of electrical power equal to 1,000 watts. 1 kW = 3.413 Btu/hr = 1.341 horsepower.
kWh Kilowatt hour. A measure of energy equivalent to the expenditure of one kilowatt for one hour. For example, 1 kWh will light a 100-watt light bulb for 10 hours. 1 kWh = 3.413 Btu.
kWe Kilowatt electrical.
kWth Kilowatt thermal.
Kyoto Protocol UN-led international agreement aimed at reducing GHG emissions.
Landfill gas Biogas generated by decomposition of organic material at landfill disposal sites. Landfill gas is approximately 50% methane. See also Biogas.
Leachates Liquids percolated through waste piles. Leachate can include various minerals, organic matter, or other contaminants and can contaminate surface water or ground water.
Life cycle Assessment (LCA) Investigation and valuation of the environmental impacts of a given product or service caused or necessitated by its existence. The term 'lifecycle' refers to the notion that a fair, holistic assessment requires the assessment of raw material production, manufacture, distribution, use and disposal including all intervening transportation steps necessary or caused by the product's existence.
Life-cycle costing A method of comparing costs of equipment or buildings based on original costs plus all operating and maintenance costs over the useful life of the equipment. Future costs are discounted.
Load (1) The amount of electrical power required at a given point on a system. (2) The average demand on electrical equipment or on an electric system.
Load factor Load factor is the ratio of average demand to maximum demand or to capacity.
Lower Heating Value (LHV) or Net heating value (NHV) Amount of heat released during the complete combustion of a given amount of a combustible (initially at 25°C) and the cooling of the combustion products down to 150°C. Thus, the LHV excludes the latent heat of vaporisation of the water contained in the combustion products. Expressed as NVH = (HHV x (1- MC / 100)) - (LH2O x MC / 100)
Lowest achievable emissions rate (LAER) Lowest achievable emissions rate (LAER): Used to describe air emissions control technology. A rate of emissions defined by the permitting agency.
Lignin Structural constituent of wood and (to a lesser extent) other plant tissues, which encrusts the cell walls and cements the cells together.
LNG Liquefied natural gas.
Log wood Cut fuelwood, with most of the material having a length of 500 mm and more.
LPG Liquefied Petroleum Gas.
Management plan A plan guiding overall management of an area administered by a federal or state agency. A management plan usually includes objectives, goals, standards and guidelines, management actions, and monitoring plans.
Mesophilic An optimum temperature for bacterial growth in an enclosed digester (25 to 40 oC).
Methane Methane is a combustible chemical compound with the molecular formula CH4. It is the principal component of natural gas.
Methanogen A methane-producing organism.
Mill/kWh A common method of pricing electricity. Tenths of a cent per kilowatt hour.
Miscanthus Miscanthus or elephant grass, is a genus of about 15 species of perennial grasses native to subtropical and tropical regions of Africa and southern Asia. The rapid growth, low mineral content and high biomass yield of Miscanthus makes it a favoured choice as a bioethanol feedstock.
Mitigation Steps taken to avoid or minimize negative environmental impacts. Mitigation can include: avoiding the impact by not taking a certain action; minimizing impacts by limiting the degree or magnitude of the action; rectifying the impact by repairing or restoring the affected environment; reducing the impact by protective steps required with the action; and compensating for the impact by replacing or providing substitute resources.
MJ Megajoule (1MJ = 106J).
MMBtu One million British thermal units.
Moisture content (MC) The quantity of water contained in a material (e.g. wood) on a volumetric or mass basis. The weight of the water contained in biomass, usually expressed as a percentage of weight, either oven-dry or as received.
Monoculture The cultivation of a single species crop.
MSW Municipal Solid Waste
MTBE Methyl tert-butyl ether. MTBE is used as an oxygenate additive to raise the octane number of gasoline.
MW Megawatt. A measure of electrical power equal to one million watts (1,000 kW).
MWe Megawatt electrical.
MWth Megawatt thermal.
N2 Nitrogen.
N2O Nitrous oxide or laughing gas. Powerful greenhouse gas that can be emitted from soils with intensive (nitrogen) fertilisation.
Net present value The sum of the costs and benefits of a project or activity. Future benefits and costs are discounted to account for interest costs.
Nitrogen fixation The transformation of atmospheric nitrogen into nitrogen compounds that can be used by growing plants.
Nitrogen Oxides (NOx) Nitrogen oxides are a product of photochemical reactions of nitric oxide in ambient air, and are one type of emission produced from fuel combustion.
Nonutility Generator (NUG) An all encompassing terms for independent power producers.
O2 Oxygen.
Octane number Measure of the resistance of gasoline and other fuels to detonation (engine knocking) in sparkignition internal combustion engines. The octane rating of a fuel is indicated on the pump. The higher the number, the slower the fuel burns. Bioethanol typically adds two to three octane numbers when blended with ordinary petroleum, making it a cost-effective octane-enhancer.
Opacity The degree to which smoke or particles emitted into the air reduce the transmission of light and obscure the view of an object in the background.
Organic Derived from living organisms.
Organic compounds Chemical compounds based on carbon chains or rings and also containing hydrogen, with or without oxygen, nitrogen, and other elements.
Organic matter Matter that comes from a once-living organism.
Organic Rankine Cycle (ORC) A Rankine Cycle is a closed circuit steam cycle to convert heat into mechanical energy in an engine. An organic Rankine Cycle uses an organic fluid with a high molecular mass instead of steam, allowing heat recovery from low temperature sources such as industrial waste heat, geothermal heat, solar ponds, etc.
Oven dry ton (ODT) An amount of biomass that weighs 2,000 pounds at zero percent moisture content.
Particulate A small, discrete mass of solid or liquid matter that remains individually dispersed in gas or liquid emissions. Particulates take the form of aerosol, dust, fume, mist, smoke, or spray. Each of these forms has different properties.
Particulate emissions Fine liquid or solid particles discharged with exhaust gases. Usually measured as grains per cubic foot or pounds per million Btu input.
Pellet Densified biofuel made from pulverised biomass with or without pressing aids usually with a cylindrical form, random length typically 5 to 30 mm, and broken ends. The raw material for biofuel pellets can be woody biomass, herbaceous biomass, fruit biomass, or biomass blends and mixtures. They are usually manufactured using a die. The total moisture content of biofuel pellets is usually less than 10% of mass.
pH A measure of acidity or alkalinity. A pH of 7 represents neutrality. Acid substances have lower pH. Basic substances have higher pH.
Photosynthesis Process by which chlorophyll-containing cells in green plants convert incident light to chemical energy, capturing carbon dioxide in the form of carbohydrates.
Pilot scale The size of a system between the small laboratory model size (bench scale) and a full-size system.
Pound Pound mass (sometimes abbreviated lb(m)). A unit of mass equal to 0.454 kilograms.
Power conversion factors (Rate of flow of energy) Watts=3.413 BTU/hr.
Kw=1,000 watts=1.341 horsepower=3413 BTU/hr.
Horsepower=745.7 watts.
Present value The worth of future receipts or costs expressed in current value. To obtain present value, an interest rate is used to discount future receipts or costs.
Process heat Heat used in an industrial process rather than for space heating or other housekeeping purposes.
Producer gas The mixture of gases produced by the gasification of organic material such as biomass at relatively low temperatures (700-1000°C). Producer gas is composed of carbon monoxide (CO), hydrogen (H), carbon dioxide (CO2), Nitrogen (N2) and typically a range of hydrocarbons such as methane (CH4). Producer gas can be burned as a fuel gas in a boiler for heat or in an internal combustion gas engine for electricity generation or combined heat and power (CHP). It can also be upgraded to Syngas for the production of biofuels.
Psi Pounds force of pressure per square inch.
Psig Pounds force of pressure per square inch gauge (excluding atmospheric pressure).
Public utility commission State agency that regulate investor-owned utilities operating in the state.
Pyrolysis The thermal decomposition of biomass at high temperatures (greater than 400°F, or 200°C) in the absence of air. The end product of pyrolysis is a mixture of solids (char), liquids (oxygenated oils), and gases (methane, carbon monoxide and carbon dioxide) with proportions determined by operating temperature, pressure, oxygen content, and other conditions.
Quad One quadrillion Btu (1015 Btu). An energy equivalent to approximately 172 million barrels of oil.
Rate schedule A price list showing how the electric bill of a particular type of customer will be calculated by an electric utility company.
Recirculation Returning a fraction of the effluent outflow to the inlet to dilute incoming wastewater.
Refractory Lining A lining, usually of ceramic, capable of resisting and maintaining high temperatures.
Renewable diesel Hydrotreated biodiesel produced by the hydrogenation of vegetable oils or animal fats. Its fuel characteristics are similar to fossil diesel.
Renewable energy resource An energy resource replenished continuously or that is replaced after use through natural means. Renewable energy resources include bioenergy, solar energy, wind energy, geothermal power, and hydropower.
Reforming Chemical process used in the petrochemical industry to improve the octane rating of hydrocarbons, but is also a useful source of other chemical compounds such as aromatic compounds and hydrogen. Steam reforming of natural gas or syngas sometimes referred to as steam methane reforming (SMR) is the most common method of producing commercial bulk hydrogen. At high temperatures (700 – 1100°C) and in the presence of a metal-based catalyst (nickel), steam reacts with methane to yield carbon monoxide and hydrogen.
CH4 + H2O = CO + 3 H2
Additional hydrogen can be recovered by a lower-temperature gas-shift reaction with the carbon monoxide produced.
CO + H2O = CO2 + H2.
Refuse-derived fuel (RDF) Fuel prepared from municipal solid waste. Non-combustible materials such as rocks, glass, and metals are removed, and the remaining combustible portion of the solid waste is chopped or shredded. RDF facilities process typically between 100 and 3,000 tonnes of MSW per day.
Residues By-product of agricultural cultivation (e.g. bagasse), farming activities (e.g. manure) or forestry industry (tree thinnings).
Return on investment (ROI) The interest rate at which the net present value of a project is zero.
RME Rape methyl ester. Esterified rape-oil commonly used as biodiesel.
Saturated steam Steam at the temperature that corresponds to its boiling temperature at the same pressure.
Sawdust Fine particles created when sawing wood.
SCF Standard cubic foot.
SCFM Standard cubic foot per minute.
Short rotation crop Woody biomass grown as a raw material and/or for its fuel value in short rotation forestry.
Slow pyrolysis Thermal conversion of biomass to fuel by slow heating to less than 500 °C in the absence of oxygen.
Sludge Sludge is formed in the aeration basin during biological waste water treatment or biological treatment process and separated by sedimentation. Sludges can be converted into biogas via anaerobic digestion.
SNG Synthetic natural gas. Gas mixture that contains varying amounts of carbon monoxide and hydrogen generated by the gasification of a carbon-containing fuel to a gaseous product with a heating value.
Solid biofuel Solid fuels (e.g. pellets, wood charcoal) produced directly or indirectly from biomass.
Spreader stoker furnace A furnace in which fuel is automatically or mechanically spread. Part of the fuel is burned in suspension. Large pieces fall on a grate.
Steam turbine A device for converting energy of high-pressure steam (produced in a boiler) into mechanical power which can then be used to generate electricity.
Stirling engine Closed-cycle regenerative heat engine with a gaseous working fluid. The working fluid, the gas which pushes on the piston, is permanently contained within the engine's system.
Stoichiometric condition That condition at which the proportion of the air-to-fuel is such that all combustible products will be completely burned with no oxygen remaining in the combustion air.
Sunk cost A cost already incurred and therefore not considered in making a current investment decision.
Surplus electricity Electricity produced by cogeneration equipment in excess of the needs of an associated factory or business.
Suspended solids Waste particles suspended in water.
Switchgrass Perennial energy crop. Switchgrass is native to the USA and known for its hardiness and rapid growth. It is often cited as a potentially abundant 2nd generation feedstock for ethanol.
Syndiesel Synthetic diesel produced through Fischer Tropsch synthesis from lignocellulosic biomass (e.g., wood). Its fuel characteristics are similar to fossil diesel.
Syngas Syngas (from the contraction of synthesis gas) is a mixture of mainly carbon monoxide (CO) and hydrogen (H2), which is the product of high temperature steam or oxygen gasification of organic material such as biomass. Following clean-up to remove any impurities such as tars, syngas can be used to produce organic molecules such as synthetic natural gas (mainly CH4) or liquid biofuels such as synthetic diesel (via Fischer Tropsch synthesis).
Therm A unit of energy equal to 100,000 Btus; used primarily for natural gas. It is approximately the energy equivalent of burning 100 cubic feet (often referred to as 1 Ccf) of natural gas.
Torrefaction Mild pre-treatment of biomass at a temperature between 200-300°C. During torrefaction of the biomass, its properties are changed to obtain a better fuel quality for combustion and gasification applications.
Transesterification Process of exchanging the alkoxy group of an ester compound with another alcohol. Biodiesel is typically manufactured from vegetable oils or animal fats by catalytically reacting these with methanol or ethanol via transesterification.
Transmission The process of long-distance transport of electrical energy, generally accomplished by raising the electric current to high voltages.
Traveling grate A type of furnace in which assembled links of grates are joined together in a perpetual belt arrangement. Fuel is fed in at one end and ash is discharged at the other.
Tri-generation Tri-generation is the simultaneous production of mechanical power (often converted to electricity), heat and cooling from a single heat source such as fuel.
Turbine A machine for converting the heat energy in steam or high temperature gas into mechanical energy. In a turbine, a high velocity flow of steam or gas passes through successive rows of radial blades fastened to a central shaft.
Turnkey system A system which is built, engineered, and installed to the point of readiness for operation by the owner.
Ultimate analysis A description of a fuel’s elemental composition as a percentage of the dry fuel weight.
VOC Volatile organic compounds are air pollutants found, for example, in engine exhaust.
Volatiles Substances that are readily vaporized.
Waste streams Unused solid or liquid by- products of a process.
Water-cooled vibrating grate A boiler grate made up of a tuyere grate surface mounted on a grid of water tubes interconnected with the boiler circulation system for positive cooling. The structure is supported by flexing plates allowing the grid and grate to move in a vibrating action. Ashes are automatically discharged.
Watt The common base unit of power in the metric system. One watt equals one joule per second, or the power developed in a circuit by a current of one ampere flowing through a potential difference of one volt. 1 Watt = 3.413 Btu/hr.
Wheeling The process of transferring electrical energy between buyer and seller by way of an intermediate utility or utilities.
Wood chips Chipped woody biomass in the form of pieces with a defined particle size produced by mechanical treatment with sharp tools such as knives. Wood chips have a sub-rectangular shape with a typical length 5-50 mm and a low thickness compared to other dimensions.
Wood fuel All types of biofuels derived directly or indirectly from trees and shrubs grown on forest and nonforest lands, from silvicultural activities (thinning, pruning, etc.), and from industrial activities (harvesting, logging or primary and secondary forest industries).
Woody biomass Biomass from trees, bushes and shrubs.
Yeast Yeast is any of various single-cell fungi capable of fermenting carbohydrates. Bioethanol is produced by fermenting sugars with yeast.

 

References

[1] Wikipedia Fotosynteza

[2] Jeremy Mark Berg, John L Tymoczko, Lubert Stryer, Neil D Clarke, Zofia Szweykowska-Kulińska: Biochemia Warszawa: Wydawnictwo Naukowe PWN, 2007, s. 327. ISBN 978-83-01-14379-4.

[3] Stefan Bringezu, Helmut Schütz, Meghan O´Brien, Lea Kauppi, Robert W. Howarth, Jeff McNeely: Towards to sustainable production and use of resources: Assessing Biofuels UNEP United Nations Environment Programme 2009, s.16. ISBN 978-92-807-3052-4.

[4] Bardi U. 2004 Price trends over a complete Hubbert cycle: the case of the American whaling industry in the 19th century

[5]Jean Laherrere: Fossil fuels future production, Romania Oil&Gas Congress 2005 Bucharest, s.40

[6] European Commission Directorate-General for Research, Information and Communication Unit: Biofuels in the European Union - A vision for 2030 and beyond, Office for Official Publications of the European Communities, 2006 ISBN 92-79-01748-9

[7] |> Frank Rosillo-Calle, Luc Pelkmans, Arnaldo Walter, A GLOBAL OVERVIEW OF VEGETABLE OILS, WITH REFERENCE TO BIODIESEL, IEA Bioenergy 2009

[8] |> Global Oil & Gas Study Topic Paper #8 Biomass, The National Petroleum Council (NPC) 2007

[9] |> RENEWABLES GLOBAL STATUS REPORT 2009 Update, Renewable Energy Policy Network for the 21st Century, 2009

[10] |> Bogner, J., M. Abdelrafie Ahmed, C. Diaz, A. Faaij, Q. Gao, S. Hashimoto, K. Mareckova, R. Pipatti, T. Zhang, Waste Management, In Climate Change 2007: Mitigation. Contribution of Working Group III to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change [B. Metz, O.R. Davidson, P.R. Bosch, R. Dave, L.A. Meyer (eds)], Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA.

[11] |> IEA Bioenergy (2009) Energy from Waste: Summary and Conclusions from the IEA Bioenergy ExCo56 Workshop

[12] |> Faaij Andre, Spitzer J., Kwant K., Potential Contribution of Bioenergy to the World's Future Energy Demand, IEA Bioenergy

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